Process for esterification of cellulose using as the catalyst the
combination of sulfuric acid, phosphoric acid and a hindered aliphatic
alcohol
    1.
    发明授权
    Process for esterification of cellulose using as the catalyst the combination of sulfuric acid, phosphoric acid and a hindered aliphatic alcohol 失效
    使用硫酸,磷酸和受阻脂肪醇的组合作为催化剂的纤维素的酯化方法

    公开(公告)号:US4480090A

    公开(公告)日:1984-10-30

    申请号:US544187

    申请日:1983-10-21

    IPC分类号: C08B3/02

    CPC分类号: C08B3/02

    摘要: The present invention relates to a method of preparing lower fatty acid esters of cellulose which comprises esterifying at a temperature of between about 75.degree. C. and about 110.degree. C. a cellulose compound having esterifiable hydroxyl groups with an esterifying bath comprising an organic acid anhydride, a diluent, and a catalyst comprising from 0.2 to 2.0 parts phosphoric acid, from 0.1 to 1.2 parts sulfuric acid, and from 0.05 to 0.6 parts of a hindered aliphatic alcohol by weight per 100 parts of the cellulose to be esterified.

    摘要翻译: 本发明涉及一种制备纤维素的低级脂肪酸酯的方法,其包括在约75℃至约110℃的温度下酯化具有可酯化羟基的纤维素化合物与含有机酸酐的酯化浴 ,稀释剂和催化剂,其包含0.2至2.0份磷酸,0.1至1.2份硫酸和0.05至0.6份受阻脂肪醇,每100份待酯化的纤维素。