摘要:
The invention relates to ultrafine suspensions of bisphenol, sodium hydroxide and water for the production of polycarbonates by the two-phase interfacial process. According to the invention, these suspensions are prepared by cooling bisphenolate concentrations near the solubility limit in aqueous sodium hydroxide with intensive mixing at relatively high temperatures and precipitating bisphenolate or more bisphenolate in the form of fine droplets during the cooling process. The ultrafine suspensions provide for a high volume/time yield in the interfacial reaction.
摘要:
The invention relates to a process for the production of polycarbonates by the two-phase interfacial method in which deviations between measured and estimated variables are continuously minimized by means of a suitably selected observer or filter system on the basis of a process model with an empirical Mark-Houwink relation adapted to the process. The variables estimated by the observer/filter are converted into control variables which are used to set input streams of the production process. Product quality is kept constant, changes in load or set values are quickly intercepted and even disturbances not readily accessible to measurement are taken into account by the process control.
摘要:
The present invention relates to the use of cyclic carbonates as demoulding agents for thermoplastic polycarbonates, and to the incorporation of these cyclic carbonates into the thermoplastic polycarbonates.
摘要:
Substituted succinic acid amides, in particular substituted succinic acid amides containing differing derivative groups, are prepared by reacting unsaturated carboxamides with carbon monoxide and with a nucleophilic component containing at least one mobile hydrogen atom, in the presence of cobalt compounds and, if appropriate, in the presence of one or more tertiary nitrogen bases, under an elevated pressure and at an elevated temperature.
摘要:
The present invention relates to a process for the preparation of polycarbonates in which an oil-in-water emulsion is maintained throughout by employing special reaction conditions.
摘要:
The present invention relates to a process for the preparation of polycarbonates in which an oil-in-water emulsion is maintained throughout by carrying out the reaction under special conditions.