Pollen suppressant comprising a fused pyridazine
    6.
    发明授权
    Pollen suppressant comprising a fused pyridazine 失效
    含有稠合哒嗪的花粉抑制剂

    公开(公告)号:US4756740A

    公开(公告)日:1988-07-12

    申请号:US863082

    申请日:1986-05-14

    摘要: Pollen suppressants of the formula ##STR1## wherein Z represents a divalent organic radical of the formula --CH.dbd.CH--CH.dbd.CH--, --CH.dbd.CH--CH.dbd.N--, --CH.dbd.CH--N.dbd.CH--, --CH.dbd.CH--NH--, --CH.dbd.CH--O--, or --CH.dbd.CH--S-- or said radical in which an H of Z is replaced with a halogen atom with the proviso that no more than three H of Z are replaced by fluorine; a C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkanoyl, cyano, nitro, hydroxy, or trihalomethyl group; or a group of the formula --NR.sup.1 R.sup.2 wherein R.sup.1 and R.sup.2 independently represent a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group; Y is Y.sup.1 R.sup.3 or NR.sup.4 R.sup.5 wherein Y.sup.1 is oxygen or sulfur; R.sup.3 hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxyalkyl, cyclohexylmethyl, halogenated C.sub.1 -C.sub.4 alkyl, phenyl, or benzyl; and R.sup.4 and R.sup.5 are independently selected from the group consisting of hydrogen, C.sub.1 -C.sub.4 alkyl, or C.sub.1 -C.sub.4 alkyl substituted with carboxyl or C.sub.1 -C.sub.4 alkoxycarbonyl; and R represents C.sub.1 -C.sub.4 alkyl, phenyl, naphthyl, or phenyl or naphthyl substituted with one to three substituents selected from the group consisting of halogen, trihalomethyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkyl, and cyano, are disclosed along with methods of producing these compounds and of using them to produce hybrid seeds in self-fertilizing plants.

    摘要翻译: 其中Z表示式-CH = CH-CH = CH-,-CH = CH-CH = N - , - CH = CH-N = CH-,-CH = CH-的二价有机基团的花粉抑制剂 = CH-NH-,-CH = CH-O-或-CH = CH-S-或其中Z的H被卤素原子替代的所述基团,条件是不超过三个Z的Z被替换 由氟; C 1 -C 4烷基,C 1 -C 4烷氧基,C 1 -C 4烷酰基,氰基,硝基,羟基或三卤代甲基; 或式-NR1R2的基团,其中R1和R2独立地表示氢原子或C1-C4烷基; Y是Y 1 R 3或NR 4 R 5,其中Y 1是氧或硫; R 3氢,C 1 -C 4烷基,C 1 -C 4烷氧基烷基,环己基甲基,卤代C 1 -C 4烷基,苯基或苄基; 并且R 4和R 5独立地选自氢,C 1 -C 4烷基或被羧基或C 1 -C 4烷氧基羰基取代的C 1 -C 4烷基; 苯基,萘基或被一至三个选自卤素,三卤代甲基,C 1 -C 4烷氧基,C 1 -C 4烷基和氰基的取代基取代的苯基或萘基与方法 生产这些化合物并使用它们在自体施肥植物中产生杂种种子。

    Pollen suppressant comprising a fused pyridazinone
    7.
    发明授权
    Pollen suppressant comprising a fused pyridazinone 失效
    含有熔融哒嗪酮的花粉抑制剂

    公开(公告)号:US4729782A

    公开(公告)日:1988-03-08

    申请号:US717666

    申请日:1985-03-29

    摘要: Pollen suppressants of the formula ##STR1## wherein Z represents a divalent organic radical of the formula --CH.dbd.CH--CH.dbd.CH--, --CH.dbd.CH--CH.dbd.N--, --CH.dbd.CH--N.dbd.CH--, --CH.dbd.CH--NH--, --CH.dbd.CH--O, or --CH.dbd.CH--S-- or said radical in which an H of Z is replaced with a halogen atom with the proviso that no more than three H of Z are replaced by fluorine; a C.sub.1 -C.sub.4 alkyl, C.sub.1 C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkanoyl, cyano, nitro, hydroxy, or trihalomethyl group; or a group of the formula --NR.sup.1 R.sup.2 wherein R.sup.1 and R.sup.2 independently represent a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group; Y is Y.sup.1 R.sup.3 or NR.sup.4 R.sup.5 wherein Y.sup.1 is oxygen or sulfur; R.sup.3 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.2 -C.sub.4 alkenyl, C.sub.2 -C.sub.4 alkynyl, C.sub.1 -C.sub.4 alkoxyalkyl, cyclohexylmethyl, halogenated C.sub.1 -C.sub.4 alkyl, phenyl, or benzyl; and R.sup.4 and R.sup.5 are independently selected from the group consisting of hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.2 -C.sub.4 alkenyl, C.sub.2 -C.sub.4 alkynyl, or C.sub.1 -C.sub.4 alkyl substituted with carboxyl or C.sub.1 -C.sub.4 alkoxycarbonyl; and R represents C.sub.1 -C.sub.4 alkyl, phenyl, naphthyl, or phenyl or naphthyl substituted with one to three substituents selected from the group consisting of halogen, trihalomethyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkyl, and cyano, are disclosed along with methods of producing these compounds and of using them to produce hybrid seed in self-fertilizing plants.

    摘要翻译: 其中Z表示式-CH = CH-CH = CH-,-CH = CH-CH = N - , - CH = CH-N = CH-,-CH = CH-的二价有机基团的花粉抑制剂 = CH-NH-,-CH = CH-O或-CH = CH-S-或其中Z的H被卤素原子替代的所述基团,条件是不超过三个Z的Z被 氟; C 1 -C 4烷基,C 1 -C 4烷氧基,C 1 -C 4烷酰基,氰基,硝基,羟基或三卤代甲基; 或式-NR1R2的基团,其中R1和R2独立地表示氢原子或C1-C4烷基; Y是Y 1 R 3或NR 4 R 5,其中Y 1是氧或硫; R 3是氢,C 1 -C 4烷基,C 2 -C 4烯基,C 2 -C 4炔基,C 1 -C 4烷氧基烷基,环己基甲基,卤代C 1 -C 4烷基,苯基或苄基; 并且R 4和R 5独立地选自氢,C 1 -C 4烷基,C 2 -C 4烯基,C 2 -C 4炔基或被羧基或C 1 -C 4烷氧基羰基取代的C 1 -C 4烷基; 苯基,萘基或被一至三个选自卤素,三卤代甲基,C 1 -C 4烷氧基,C 1 -C 4烷基和氰基的取代基取代的苯基或萘基与方法 生产这些化合物并使用它们在自体施肥植物中产生杂种种子。

    Pollen suppressant comprising a fused pyridazine
    8.
    发明授权
    Pollen suppressant comprising a fused pyridazine 失效
    含有稠合哒嗪的花粉抑制剂

    公开(公告)号:US4604134A

    公开(公告)日:1986-08-05

    申请号:US532020

    申请日:1983-09-14

    摘要: Pollen suppressants of the formula ##STR1## wherein Z represents a divalent organic radical of the formula --CH.dbd.CH--CH.dbd.CH--, --CH.dbd.CH--CH.dbd.N--, --CH.dbd.CH--N.dbd.CH--, --CH.dbd.CH--NH--, --CH.dbd.CH--O--, or --CH.dbd.CH--S-- or said radical in which an H of Z is replaced with a halogen atom with the proviso that no more than three H or Z are replaced by fluorine; a C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkanoyl, cyano, nitro, hydroxy, or trihalomethyl group; or a group of the formula --NR.sup.1 R.sup.2 wherein R.sup.1 and R.sup.2 independently represent a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group; Y is Y.sup.1 R.sup.3 or NR.sup.4 R.sup.5 wherein Y.sup.1 is oxygen or sulfur; R.sup.3 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxyalkyl, cyclohexylmethyl, halogenated C.sub.1 -C.sub.4 alkyl, phenyl, or benzyl; and R.sup.4 and R.sup.5 are independently selected from the group consisting of hydrogen, C.sub.1 -C.sub.4 alkyl, or C.sub.1 -C.sub.4 alkyl substituted with carboxyl or C.sub.1 -C.sub.4 alkoxycarbonyl; and R represents C.sub.1 -C.sub.4 alkyl, phenyl, naphthyl, or phenyl or naphthyl substituted with one to three substituents selected from the group consisting of halogen, trihalomethyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkyl, and cyano, are disclosed along with methods of producing these compounds and of using them to produce hybrid seeds in self-fertilizing plants.

    摘要翻译: 其中Z表示式-CH = CH-CH = CH-,-CH = CH-CH = N - , - CH = CH-N = CH-,-CH = CH-的二价有机基团的花粉抑制剂 = CH-NH-,-CH = CH-O-或-CH = CH-S-或其中Z的H被卤素原子替代的所述基团,条件是不超过三个H或Z被替换 由氟; C 1 -C 4烷基,C 1 -C 4烷氧基,C 1 -C 4烷酰基,氰基,硝基,羟基或三卤代甲基; 或式-NR1R2的基团,其中R1和R2独立地表示氢原子或C1-C4烷基; Y是Y 1 R 3或NR 4 R 5,其中Y 1是氧或硫; R3是氢,C1-C4烷基,C1-C4烷氧基烷基,环己基甲基,卤代C1-C4烷基,苯基或苄基; 并且R 4和R 5独立地选自氢,C 1 -C 4烷基或被羧基或C 1 -C 4烷氧基羰基取代的C 1 -C 4烷基; 苯基,萘基或被一至三个选自卤素,三卤代甲基,C 1 -C 4烷氧基,C 1 -C 4烷基和氰基的取代基取代的苯基或萘基与方法 生产这些化合物并使用它们在自体施肥植物中产生杂种种子。

    Pollen suppressant comprising a pyridazolylamine
    10.
    发明授权
    Pollen suppressant comprising a pyridazolylamine 失效
    含有哒唑胺的花粉抑制剂

    公开(公告)号:US4561881A

    公开(公告)日:1985-12-31

    申请号:US532094

    申请日:1983-09-14

    摘要: A pollen suppressant of the formula ##STR1## wherein R.sup.1 and R.sup.4 independently represent C.sub.1 -C.sub.4 alkyl, phenyl, naphthyl, or phenyl or naphthyl substituted with one to three substituents selected from the group consisting of halogen, trihalomethyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkyl, and cyano; R.sup.2 is ##STR2## where R.sup.5 is a C.sub.1 -C.sub.12 alkyl group, optionally substituted with one or more halogen atoms, or an aryl group selected from the group consisting of 6-membered rings containing 0-3 nitrogens and fused bicyclic 10-membered rings containing 6 atoms in each ring and 0-3 nitrogens per ring with the remaining atoms in the ring or rings of said aryl group being carbon atoms, said aryl group being optionally substituted with a C.sub.1 -C.sub.4 alkyl group or an electron-withdrawing group, R.sup.3 is hydrogen, a halogen a C.sub.1 -C.sub.4 alkyl group, a carboxy group or an agronomically acceptable alkali metal salt thereof, or a group of the formula --COOR.sup.6 or --CONR.sup.6 R.sup.7 where R.sup.6 is a C.sub.1 -C.sub.4 alkyl group and R.sup.7 is R.sup.6 or hydrogen, is disclosed along with methods of producing these compounds and of using them to produce hybrid seeds in self-fertilizing plants.

    摘要翻译: 其中R1和R4独立地表示C1-C4烷基,苯基,萘基或被一至三个选自卤素,三卤代甲基,C1-C4烷氧基,C1-C4烷基的取代基取代的苯基或萘基的花粉抑制剂 -C4烷基和氰基; R 2是,其中R 5是任选被一个或多个卤素原子取代的C 1 -C 12烷基,或选自含有0-3个氮的6元环和稠合的双环10元环的芳基 每个环中含有6个原子,每个环有0-3个氮原子,所述芳基的环或其中的剩余原子是碳原子,所述芳基任选被C 1 -C 4烷基或吸电子基团取代, R 3是氢,卤素,C 1 -C 4烷基,羧基或其农业上可接受的碱金属盐,或式-COOR 6或-CONR 6 R 7的基团,其中R 6是C 1 -C 4烷基,且R 7是R 6或 氢以及生产这些化合物的方法以及使用它们在自体施肥植物中产生杂种种子。