公开(公告)号：US20140163249A1

公开(公告)日：2014-06-12

申请号：US13708811

申请日：2012-12-07

申请人： Cong-Yan Chen ,  Alexander E. Kuperman ,  William James Cannella ,  Theodorus Ludovicus Michaael Maesen

发明人： Cong-Yan Chen ,  Alexander E. Kuperman ,  William James Cannella ,  Theodorus Ludovicus Michaael Maesen

IPC分类号： C07C29/149 ,  C11C3/12 ,  C10G3/00

CPC分类号： C07C29/149 ,  C10G3/46 ,  C10G3/50 ,  C10G45/58 ,  C10G50/02 ,  C10G69/14 ,  C10G2300/1022 ,  C10G2400/10 ,  C11C3/00 ,  C11C3/123 ,  Y02P30/20 ,  C07C31/125

摘要： A hydroconversion process comprises contacting a feedstock comprising renewable materials under hydroprocessing conditions with a promoted catalyst selected from a self-supported catalyst, a supported catalyst and combinations thereof, wherein the reaction conditions can be tailored to directly convert the renewable feedstock to the desired product(s) including fatty alcohols, esters, normal paraffins, or combinations thereof. The catalyst comprising at least a Group VIB metal selected from molybdenum and tungsten, a Group VIII metal selected from cobalt and nickel to convert the feedstock into any of fatty alcohols, esters, and normal paraffins. In some embodiments, the process further comprising additional steps to generate various desirable products, including α-olefins (or PAO, by dehydrating the fatty alcohol products), lubricants and bright stocks (from the oligomerizing of the PAO), and Group 3 lubricants (from co-oligomerizing of the PAO with some short chain olefins).

摘要翻译： 加氢转化方法包括在加氢处理条件下将包含可再生材料的原料与选自自支撑催化剂，负载型催化剂及其组合的促进催化剂接触，其中反应条件可以被定制以将可再生原料直接转化为所需产物（ s），包括脂肪醇，酯，正链烷烃或其组合。 所述催化剂至少包含选自钼和钨的第VIB族金属，选自钴和镍的第Ⅷ族金属，以将原料转化成任何脂肪醇，酯和正链烷烃。 在一些实施方案中，该方法还包括产生各种所需产物的其它步骤，包括α-烯烃（或PAO，通过脱脂脂肪醇产物），润滑剂和光亮油料（来自PAO的低聚）和第3组润滑剂 来自PAO与一些短链烯烃的共低聚）。