公开(公告)号：US20160194277A1

公开(公告)日：2016-07-07

申请号：US14890053

申请日：2014-05-19

申请人： COVESTRO DEUTSCHLAND AG

发明人： Thorsten Dreier ,  Stefan Wershofen ,  Anton Vidal ,  Robert Haak

IPC分类号： C07C269/04 ,  C07C65/21 ,  C07C51/41 ,  B01J31/22

CPC分类号： C07C269/04 ,  B01J31/2208 ,  B01J2231/34 ,  B01J2531/26 ,  C07C51/418 ,  C07C65/21 ,  C07C271/26 ,  C07C271/24 ,  C07C271/12

摘要： The present invention relates to metallic zinc cluster compounds which are suitable as catalysts in the reaction of amines with dialkyl carbonates to produce carbamates. The invention is also directed towards a method for the alkoxycarbonylation of amines. The cluster compound has a general formula which may be written as [M(O2C—R)2]x.[MO]y.[H2O]z, wherein M is Zn, R is an unsubstituted or substituted aromatic, cycloaliphatic, linear aliphatic, or other organic rest, x is 1, y is ≧x is 1, y is ≧0.03 to ≦26.0 and z is >0.00 to ≦17.0.

摘要翻译： 本发明涉及在胺与碳酸二烷基酯反应生成氨基甲酸酯时适合作为催化剂的金属锌簇化合物。 本发明还涉及胺的烷氧羰基化方法。 簇化合物具有可以写为[M（O 2 C-R）2] x。[MO] y。[H 2 O] z的通式，其中M是Zn，R是未取代或取代的芳族，脂环族，直链脂族 或其它有机残基，x为1，y为≧x为1，y为≥0.03〜＆lt; nlE; 26.0，z为> 0.00〜＆lt; lE; 17.0。

公开(公告)号：US09988344B2

公开(公告)日：2018-06-05

申请号：US14890053

申请日：2014-05-19

申请人： Covestro Deutschland AG

发明人： Thorsten Dreier ,  Stefan Wershofen ,  Anton Vidal ,  Robert Haak

IPC分类号： C07F3/00 ,  C07C269/04 ,  B01J31/22 ,  C07C51/41 ,  C07C65/21

CPC分类号： C07C269/04 ,  B01J31/2208 ,  B01J2231/34 ,  B01J2531/26 ,  C07C51/418 ,  C07C65/21 ,  C07C271/26 ,  C07C271/24 ,  C07C271/12

摘要： The present invention relates to metallic zinc cluster compounds which are suitable as catalysts in the reaction of amines with dialkyl carbonates to produce carbamates. The invention is also directed towards a method for the alkoxycarbonylation of amines. The cluster compound has a general formula which may be written as [M(O2C—R)2]x.[MO]y.[H2O]z, wherein M is Zn, R is an unsubstituted or substituted aromatic, cycloaliphatic, linear aliphatic, or other organic rest, x is 1, y is ≥x is 1, y is ≥0.03 to ≤26.0 and z is >0.00 to ≤17.0.