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公开(公告)号：US06689552B2
公开(公告)日：2004-02-10
申请号：US10011561
申请日：2001-11-05
申请人： Cuong Ly , Edgar Draber , Matthias Feigl , Günter Helling , Thomas Kaluschke , Michael Missfeldt , Maria Nietgen , Heinz-Horst Teitscheid , Ralf Weimann , Heinz Wiesen
发明人： Cuong Ly , Edgar Draber , Matthias Feigl , Günter Helling , Thomas Kaluschke , Michael Missfeldt , Maria Nietgen , Heinz-Horst Teitscheid , Ralf Weimann , Heinz Wiesen
IPC分类号： G03C108
CPC分类号： G03C7/39204 , G03C1/127 , G03C1/16 , G03C7/3022 , G03C7/346 , G03C7/36 , G03C7/3835 , G03C7/3926 , G03C2001/03517
摘要： A color photographic silver halide material which can be developed to form a negative, at least 95 mol % of the silver halides of which consist of AgCl, and which contains at least one light-sensitive silver halide emulsion layer, the silver halide of which contains at least one compound of formulae (I), (II) and (III): [IrClnF6-n]2−M2+ (I) wherein n denotes 0 or an integer from 1 to 6 and M2+ denotes 1 or 2 cations with a total number of 2 positive charges, [Fe(CN)6]m−Mm+ (II) wherein m denotes 2 or 3 and Mm+ denotes 1 to 3 cations with a total number of m positive charges, wherein o denotes 0, 1 or 2 and R denotes an alkyl, aryl or aralkyl, is distinguished under scanning exposure and on analogue exposure by sharp contrast which is independent of exposure time and by a stable latent image.
摘要翻译： 可以显影的彩色照相卤化银材料，其形成负极，至少95mol％的由AgCl组成的卤化银，并且其含有至少一种感光卤化银乳剂层，其卤化银含有 至少一种式（I），（II）和（III）的化合物：其中n表示0或1至6的整数，M 2+表示1或2个阳离子，总数为2个正电荷，其中 m表示2或3，M
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公开(公告)号：US6063557A
公开(公告)日：2000-05-16
申请号：US145445
申请日：1998-09-02
申请人： Cuong Ly , Maria Nietgen , Michael Missfeldt , Heinz-Horst Teitscheid , Edgar Draber , Markus Geiger
发明人： Cuong Ly , Maria Nietgen , Michael Missfeldt , Heinz-Horst Teitscheid , Edgar Draber , Markus Geiger
CPC分类号： G03C7/30535 , G03C1/09 , G03C1/16 , G03C7/3835 , G03C7/3022
摘要： A color photographic silver halide material in which at least one of the blue-sensitive silver halide emulsions is doped with mercury and is spectrally sensitised with a sensitising dye of formula (I) ##STR1## wherein X.sub.1 and X.sub.2, independently of each other, denote O, S, Se, NR,R denotes alkyl or carboxyalkyl,R.sub.1 and R.sub.2 or R.sub.2 and R.sub.3 denote the remaining members for the completion of a phenanthro- or anthraazole ring, and the remaining R.sub.1 or R.sub.3 radical denotes a hydrogen atom,R.sub.4 and R.sub.5, independently of each other, denote a hydrogen atom, alkyl or aryl, orR.sub.4 and R.sub.5 jointly denote the remaining members of an unsubstituted or substituted benzazole, naphthazole, phenanthro- or anthraazole,S.sub.1 and S.sub.2, independently of each other, denote alkyl, sulphoallyl or carboxyalkyl, andM.sup.+ denotes a cation which is possibly necessary for charge equalisation,is distinguished by an improved latent image stability.
摘要翻译： 一种彩色照相卤化银材料，其中至少一种感蓝卤化银乳剂用汞掺杂，并用式（I）的敏化染料进行光谱增感，其中X1和X2彼此独立地表示O，S ，Se，NR，R表示烷基或羧基烷基，R 1和R 2或R 2和R 3表示用于完成菲或蒽并噻唑环的剩余成员，其余的R 1或R 3基团表示氢原子，R 4和R 5，独立地 表示氢原子，烷基或芳基，或者R4和R5共同表示未取代或取代的苯并唑，萘并噻唑，菲咯啉或蒽醌的剩余成员，S1和S2彼此独立地表示烷基，磺基烯丙基或 羧基烷基和M +表示电荷平衡可能需要的阳离子，其特征在于改进的潜像稳定性。
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公开(公告)号：US06171776B2
公开(公告)日：2001-01-09
申请号：US09209404
申请日：1998-12-10
IPC分类号： G03C129
摘要： A colour photographic silver halide material in which at least one of the blue-sensitive silver halide emulsions is spectrally sensitised with a mixture of at least one seansitising dye of the formula (I) and at least one sensitising dye of the formula (II): in which R1 means an optionally substituted thienyl, pyrroly, indolyl, furamyl or phenyl, in which R5, R6, R7, mean H or R5 and R6 together or R6 and R7 together mean the remaining members of a fused benzo ring and the residual substituent means H and R2, R3, R4, R8, R9, R10 and M have the meaning stated in the description, is distinguished by elevated sensitivity and improved latent image stabilitity.
摘要翻译： 一种彩色照相卤化银材料，其中至少一种感蓝卤化银乳剂用式（I）的至少一种海藻染料和至少一种式（II）的敏化染料的混合物进行光谱增感： 其中R 1表示任选取代的噻吩基，吡咯基，吲哚基，呋喃基或苯基，其中R 5，R 6，R 7，平均H或R 5和R 6一起或R 6和R 7一起表示稠合的苯并环的剩余成员，残基取代基表示H 和R2，R3，R4，R8，R9，R10和M具有描述中所述的含义，其特征在于提高的灵敏度和改善的潜像稳定性。
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公开(公告)号：US06890707B2
公开(公告)日：2005-05-10
申请号：US10612809
申请日：2003-07-02
申请人： Ralf Weimann , Markus Geiger , Cuong Ly , Klaus Sinzger , Beate Weber , Heinz Wiesen
发明人： Ralf Weimann , Markus Geiger , Cuong Ly , Klaus Sinzger , Beate Weber , Heinz Wiesen
IPC分类号： G03C5/08 , G03C1/035 , G03C1/09 , G03C5/04 , G03C7/00 , G03C7/30 , G03C7/34 , G03C7/392 , G03C1/08 , G03C7/25 , G03C7/32
CPC分类号： G03C7/346 , G03C1/09 , G03C5/04 , G03C7/30 , G03C7/3022 , G03C7/39204 , G03C2001/03517 , G03C2001/093 , G03C2200/19
摘要： A print material having a support, at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler and at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, characterised in that the silver halide crystals of the red-sensitive layer have a chloride content of at least 95 mol %, contain 20 to 500 nmol of iridium per mol of silver halide and the cyan coupler is of the formula in which R1 means a hydrogen atom or an alkyl group, R2 means an alkyl, aryl or hetaryl group, R3 means an alkyl or aryl group, R4 means an alkyl, alkenyl, alkoxy, aryloxy, acyloxy, acylamino, sulfonyloxy, sulfamoylamino, sulfonamido, ureido, hydroxycarbonyl, hydroxycarbonylamino, carbamoyl, alkylthio, arylthio, alkylamino or arylamino group or a hydrogen atom and Z means a hydrogen atom or a group eliminable under the conditions of chromogenic development, is distinguished in that it is equally ideally suitable for analogue and scanning exposure and exhibits very good latent image stability.
摘要翻译： 具有载体的印刷材料，至少一种含有至少一种青色成色剂的感红卤化银乳剂层，至少一种包含至少一种品红成色剂的至少一种感光卤化银乳剂层和至少一种感蓝卤化银乳剂 含有至少一种黄色成色剂的层，其特征在于，红色敏感层的卤化银晶体的氯化物含量为至少95摩尔％，每摩尔卤化银含有20-500nmol的铱，青色成色剂为 其中R 1表示氢原子或烷基的式R 2是指烷基，芳基或杂芳基，R 3表示 烷基或芳基，R 4表示烷基，烯基，烷氧基，芳氧基，酰氧基，酰氨基，磺酰氧基，氨磺酰氨基，亚磺酰氨基，脲基，羟基羰基，羟基羰基氨基，氨基甲酰基，烷硫基，芳硫基，烷基氨基或芳基氨基 基团或氢原子，Z表示氢原子或取代基 在显色发展的条件下，其特征在于它同样理想地适用于模拟和扫描曝光，并且表现出非常好的潜像稳定性。
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公开(公告)号：US06783924B2
公开(公告)日：2004-08-31
申请号：US10612560
申请日：2003-07-02
申请人： Ralf Weimann , Markus Geiger , Cuong Ly , Klaus Sinzger , Beate Weber , Heinz Wiesen
发明人： Ralf Weimann , Markus Geiger , Cuong Ly , Klaus Sinzger , Beate Weber , Heinz Wiesen
IPC分类号： G03C108
CPC分类号： G03C1/18 , G03C1/127 , G03C5/04 , G03C7/30 , G03C7/3006 , G03C7/346 , G03C7/3926 , G03C7/39276 , G03C2200/19
摘要： A color photographic silver halide material comprising a substrate, at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler and at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, characterised in that the silver halide crystals of the red-sensitive layer have a chloride content of at least 95 mol %, the cyan coupler corresponding to formula wherein R1 represents a hydrogen atom or an alkyl group, R2 represents an alkyl, aryl or hetaryl group R3 represents an alkyl or aryl group, R4 represents an alkyl, alkenyl, alkoxy, aryloxy, acyloxy, acylamino, sulphonyloxy, sulphamoylamino, sulphonamido, ureido, hydroxycarbonyl, hydroxycarbonylamino, carbamoyl, alkylthio, arylthio, alkylamino or arylamino group or a hydrogen atom and Z represents a hydrogen atom or a group which may be split off under the conditions of chromogenic development and the red-sensitive layer contains at least one compound of formula wherein R5 represents H, CH3 or OCH3, R6 represents H, OH, CH3, OCH3, NHCO—R7, COOR7, SO2NH2, NHCONH2 or NHCONH—CH3 and R7 represents C1 to C4 alkyl, is distinguished by very good stability in storage simultaneously with very good latent image stability.
摘要翻译： 一种彩色照相卤化银材料，其包含基材，至少一种含有至少一种青色成色剂的感红卤化银乳剂层，至少一种包含至少一种品红色成色剂的至少一种感绿卤化银乳剂层和至少一种蓝色敏感性 含有至少一种黄色成色剂的卤化银乳剂层，其特征在于，所述红色感光层的卤化银晶体的氯化物含量为至少95摩尔％，对应于其中的青色成色剂R 1表示氢原子或 烷基，R 2表示烷基，芳基或杂芳基R 3表示烷基或芳基，R 4表示烷基，烯基，烷氧基，芳氧基，酰氧基，酰氨基，磺酰氧基，氨磺酰氨基，磺酰氨基，脲基 ，羟基羰基，羟基羰基氨基，氨基甲酰基，烷硫基，芳硫基，烷基氨基或芳基氨基或氢原子，Z表示氢原子或可以在条件o f显色发育和红敏层含有至少一种糠醛的化合物，R 5表示H，CH 3或OCH 3，R 6表示H，OH，CH 3，OCH 3，NHCO-R 7，COOR 7， SO 2 NH 2，NHCONH 2或NHCONH-CH 3和R 7表示C 1至C 4烷基，其特征在于非常好的保存稳定性，同时具有非常好的潜像稳定性。
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公开(公告)号：US06806042B2
公开(公告)日：2004-10-19
申请号：US10612132
申请日：2003-07-02
申请人： Ralf Weimann , Markus Geiger , Cuong Ly , Klaus Sinzger , Beate Weber , Heinz Wiesen
发明人： Ralf Weimann , Markus Geiger , Cuong Ly , Klaus Sinzger , Beate Weber , Heinz Wiesen
IPC分类号： G03C108
CPC分类号： G03C7/346 , G03C5/04 , G03C7/30 , G03C7/3022 , G03C7/3882 , G03C7/3885 , G03C2001/03517 , G03C2200/19
摘要： A print material having a support, at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler and at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, characterised in that the red-sensitive layer contains at least one oil former, the cyan coupler is of the formula in which R1 means a hydrogen atom or an alkyl group, R2 means an alkyl, aryl or hetaryl group, R3 means an alkyl or aryl group, R4 means an alkyl, alkenyl, alkoxy, aryloxy, acyloxy, acylamino, sulfonyloxy, sulfamoylamino, sulfonamido, ureido, hydroxycarbonyl, hydroxycarbonylamino, carbamoyl, alkylthio, arylthio, alkylamino or arylamino group or a hydrogen atom and Z means a hydrogen atom or a group eliminable under the conditions of chromogenic development, and the ratio by weight of oil former to cyan coupler is less than 1:1, is distinguished by excellent colour reproduction.
摘要翻译： 具有载体的印刷材料，至少一种含有至少一种青色成色剂的感红卤化银乳剂层，至少一种包含至少一种品红成色剂的至少一种感光卤化银乳剂层和至少一种感蓝卤化银乳剂 该层包含至少一个黄色成色剂，其特征在于该红色敏感层含有至少一种成油剂，青色成色剂是式（1）表示氢原子或烷基，R 2表示烷基 ，芳基或杂芳基，R 3表示烷基或芳基，R 4表示烷基，烯基，烷氧基，芳氧基，酰氧基，酰氨基，磺酰氧基，氨磺酰氨基，亚磺酰氨基，脲基，羟基羰基，羟基羰基氨基，氨基甲酰基， ，芳硫基，烷基氨基或芳基氨基或氢原子，Z表示氢原子或在显色条件下可消除的基团，成油剂与青色成色剂的重量比小于1：1，由ex 细胞色彩再现。
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公开(公告)号：US6159675A
公开(公告)日：2000-12-12
申请号：US318040
申请日：1999-05-25
申请人： Cuong Ly , Matthias Feigl , Markus Geiger
发明人： Cuong Ly , Matthias Feigl , Markus Geiger
CPC分类号： G03C7/3926 , G03C7/301 , G03C7/3835
摘要： A colour photographic material having a support and at least one silver halide emulsion layer containing couplers, which layer contains as couplers a 2-equivalent magenta coupler and both at least one compound of the formula (III) and at least one compound of the formula (IV): ##STR1## in which R.sub.4 to R.sub.9 and n have the meaning stated in the description, is distinguished by reduced pressure sensitivity.
摘要翻译： 一种具有载体的彩色照相材料和含有成色剂的至少一种卤化银乳剂层，该层含有作为成色剂的2-当量品红成色剂和至少一种式（III）的化合物和至少一种式（III）的化合物 IV）：其中R4至R9和n具有说明书中所述的含义，其特征在于降低的压力敏感性。
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公开(公告)号：US06284447B1
公开(公告)日：2001-09-04
申请号：US09545378
申请日：2000-04-07
申请人： Cuong Ly , Dieter Rockser , Edgar Draber , Markus Geiger , Jürgen Heinecke , Randolph Trommer
发明人： Cuong Ly , Dieter Rockser , Edgar Draber , Markus Geiger , Jürgen Heinecke , Randolph Trommer
IPC分类号： G03C108
CPC分类号： G03C7/396 , G03C7/39268
摘要： A color photographic silver halide material which is developed as a negative, at least 90 mol % of the silver halides of which consist of AgCl, and which contains a compound of formula (I) or formula (II) in a light-insensitive layer which is further from the support than is each light—light sensitive layer, is distinguished by its improved color reproduction.
摘要翻译： 显色为负的彩色照相卤化银材料，其至少90mol％的银卤化银由AgCl组成，并且在不透光层中含有式（I）或式（II）的化合物，其中 比每个光敏层更远离支撑，通过其改进的颜色再现来区分。
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公开(公告)号：US6077657A
公开(公告)日：2000-06-20
申请号：US343620
申请日：1999-06-30
申请人： Cuong Ly , Matthias Feigl , Markus Geiger
发明人： Cuong Ly , Matthias Feigl , Markus Geiger
CPC分类号： G03C7/301 , G03C7/30529 , G03C7/3835 , G03C7/39236 , G03C7/3926
摘要： A color photographic silver halide material having a support and at least one silver halide emulsion layer containing couplers, which layer contains as couplers a 2-equivalent magenta coupler and both at least one compound of the formula (III) and at least one compound of the formula (IV): ##STR1## in which R.sub.4 means H, alkoxy or alkylmercapto,R.sub.5 means alkyl, halogen or R.sub.4,R.sub.7 means OH, NHCHO, NHCONH-alkyl, CO-alkyl, COOH, COO-alkyl, CONH.sub.2, SO.sub.3 H, SO.sub.2 NH-alkyl, CH.sub.2 CH.sub.2 COOH andR.sub.7 means H, alkyl, halogen, OH or alkoxyis distinguished by improved pressure sensitivity.
摘要翻译： 具有载体的彩色照相卤化银材料和含有成色剂的至少一种卤化银乳剂层，该层包含作为成色剂的2-当量品红成色剂和至少一种式（III）的化合物和至少一种式 式（IV）：其中R4表示H，烷氧基或烷基巯基，R5表示烷基，卤素或R4，R7表示OH，NHCHO，NHCONH-烷基，CO-烷基，COOH，COO-烷基，CONH2，SO3H，SO2NH-烷基 ，CH 2 CH 2 COOH和R 7表示H，烷基，卤素，OH或烷氧基通过改进的压力敏感性来区分。
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公开(公告)号：US6045989A
公开(公告)日：2000-04-04
申请号：US122128
申请日：1998-07-24
申请人： Cuong Ly , Ralf Weimann
发明人： Cuong Ly , Ralf Weimann
CPC分类号： G03C7/3835 , G03C1/035 , G03C1/08 , G03C1/30 , G03C1/34 , G03C2001/03517 , G03C2001/092 , G03C7/00 , G03C7/3212
摘要： A color photographic silver halide material having a support and at least one light-sensitive silver halide emulsion layer, the silver halide of which consists of at least 95 mole % of AgCl, and which contains a magenta coupler of formula (I) whereinR denotes H or a group which is split off under the conditions of chromogenic development,R.sub.1 denotes alkyl, which is optionally substituted, andR.sub.2 denotes R.sub.1 or aryl,wherein the sum of all the C atoms of the R.sub.1 and R.sub.2 radicals in a coupler molecule is at least 12, and wherein the silver halide contains mercury, is distinguished by improved latent image stability.
摘要翻译： 具有支持体和至少一种感光卤化银乳剂层的彩色照相卤化银材料，其卤化银由至少95摩尔％的AgCl组成，并且含有式（I）的品红成色剂，其中R表示 H或在显色发展条件下分离的基团，R 1表示任选被取代的烷基，R 2表示R 1或芳基，其中偶联分子中R 1和R 2基团的所有C原子的总和为 至少12，并且其中卤化银含有汞，其特征在于改进的潜像稳定性。
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