公开(公告)号：US20110003726A1

公开(公告)日：2011-01-06

申请号：US12496510

申请日：2009-07-01

申请人： Curtis Bay Campbell ,  Eugene Edward Spala ,  Willie Horn, JR.

发明人： Curtis Bay Campbell ,  Eugene Edward Spala ,  Willie Horn, JR.

IPC分类号： C10M129/76 ,  C07C69/88

CPC分类号： C10M129/70 ,  C10M129/54 ,  C10M159/22 ,  C10M167/00 ,  C10M2203/1025 ,  C10M2207/026 ,  C10M2207/028 ,  C10M2207/262 ,  C10M2215/086 ,  C10M2223/045 ,  C10N2220/028 ,  C10N2230/08 ,  C10N2230/52 ,  C10N2240/10 ,  C10N2260/00 ,  C10N2270/00 ,  C10N2270/02

摘要： The present invention is directed to a method for preparing an unsulfurized, carboxylate-containing additive for lubricating oils and the product produced by said method, wherein said method comprises a) neutralization of a mixture of at least two alkyl phenols using an alkaline earth base in the presence of a promoter, to produce a mixture of alkyl phenates, wherein the mixture of at least two alkyl phenols comprises at least a first alkyl phenol wherein the alkyl group is derived from an isomerized alpha olefin and a second alkyl phenol wherein the alkyl group is derived from a branched chain olefin; (b) carboxylation of the mixture of alkyl phenates obtained in step (a) using carbon dioxide under carboxylation conditions sufficient to convert at least 20 mole % of the starting alkyl phenols to alkyl salicylate; and (c) removal of at least about 10% of the starting mixture of at least two alkyl phenols from the product produced in step (b) to produce said additive.

摘要翻译： 本发明涉及一种制备用于润滑油的未硫化的含羧酸盐的添加剂和通过所述方法制备的产品的方法，其中所述方法包括：a）使用碱土金属碱将至少两种烷基酚的混合物中和 促进剂的存在以产生烷基酚盐的混合物，其中至少两种烷基酚的混合物包含至少第一烷基苯酚，其中烷基衍生自异构化的α-烯烃和第二烷基苯酚，其中烷基 衍生自支链烯烃; （b）在足以将至少20摩尔％的起始烷基酚转化为水杨酸烷基酯的羧化条件下使用二氧化碳使步骤（a）中获得的烷基酚盐的混合物羧化; 和（c）从步骤（b）中产生的产物中除去至少约10％的至少两种烷基酚的起始混合物以产生所述添加剂。

公开(公告)号：US08399388B2

公开(公告)日：2013-03-19

申请号：US12496510

申请日：2009-07-01

申请人： Curtis Bay Campbell ,  Eugene Edward Spala ,  Willie Horn, Jr.

发明人： Curtis Bay Campbell ,  Eugene Edward Spala ,  Willie Horn, Jr.

IPC分类号： C10M129/76 ,  C10M169/00

CPC分类号： C10M129/70 ,  C10M129/54 ,  C10M159/22 ,  C10M167/00 ,  C10M2203/1025 ,  C10M2207/026 ,  C10M2207/028 ,  C10M2207/262 ,  C10M2215/086 ,  C10M2223/045 ,  C10N2220/028 ,  C10N2230/08 ,  C10N2230/52 ,  C10N2240/10 ,  C10N2260/00 ,  C10N2270/00 ,  C10N2270/02

摘要： The present invention is directed to a method for preparing an unsulfurized, carboxylate-containing additive for lubricating oils and the product produced by said method, wherein said method comprises a) neutralization of a mixture of at least two alkyl phenols using an alkaline earth base in the presence of a promoter, to produce a mixture of alkyl phenates, wherein the mixture of at least two alkyl phenols comprises at least a first alkyl phenol wherein the alkyl group is derived from an isomerized alpha olefin and a second alkyl phenol wherein the alkyl group is derived from a branched chain olefin; (b) carboxylation of the mixture of alkyl phenates obtained in step (a) using carbon dioxide under carboxylation conditions sufficient to convert at least 20 mole % of the starting alkyl phenols to alkyl salicylate; and (c) removal of at least about 10% of the starting mixture of at least two alkyl phenols from the product produced in step (b) to produce said additive.

摘要翻译： 本发明涉及一种制备用于润滑油的未硫化的含羧酸盐的添加剂和通过所述方法制备的产品的方法，其中所述方法包括：a）使用碱土金属碱将至少两种烷基酚的混合物中和 促进剂的存在以产生烷基酚盐的混合物，其中至少两种烷基酚的混合物包含至少第一烷基苯酚，其中烷基衍生自异构化的α-烯烃和第二烷基苯酚，其中烷基 衍生自支链烯烃; （b）在足以将至少20摩尔％的起始烷基酚转化为水杨酸烷基酯的羧化条件下使用二氧化碳使步骤（a）中获得的烷基酚盐的混合物羧化; 和（c）从步骤（b）中产生的产物中除去至少约10％的至少两种烷基酚的起始混合物以产生所述添加剂。

公开(公告)号：US20130157916A1

公开(公告)日：2013-06-20

申请号：US13768003

申请日：2013-02-15

申请人： Curtis Bay Campbell ,  Eugene Edward Spala ,  Willie Horn, JR.

发明人： Curtis Bay Campbell ,  Eugene Edward Spala ,  Willie Horn, JR.

IPC分类号： C10M129/70

CPC分类号： C10M129/70 ,  C10M129/54 ,  C10M159/22 ,  C10M167/00 ,  C10M2203/1025 ,  C10M2207/026 ,  C10M2207/028 ,  C10M2207/262 ,  C10M2215/086 ,  C10M2223/045 ,  C10N2220/028 ,  C10N2230/08 ,  C10N2230/52 ,  C10N2240/10 ,  C10N2260/00 ,  C10N2270/00 ,  C10N2270/02

摘要： The present invention is directed to a method for preparing an unsulfurized, carboxylate-containing additive for lubricating oils and the product produced by said method, wherein said method comprises a) neutralization of a mixture of at least two alkyl phenols using an alkaline earth base in the presence of a promoter, to produce a mixture of alkyl phenates, wherein the mixture of at least two alkyl phenols comprises at least a first alkyl phenol wherein the alkyl group is derived from an isomerized alpha olefin and a second alkyl phenol wherein the alkyl group is derived from a branched chain olefin; (b) carboxylation of the mixture of alkyl phenates obtained in step (a) using carbon dioxide under carboxylation conditions sufficient to convert at least 20 mole % of the starting alkyl phenols to alkyl salicylate; and (c) removal of at least about 10% of the starting mixture of at least two alkyl phenols from the product produced in step (b) to produce said additive.

摘要翻译： 本发明涉及一种制备用于润滑油的未硫化的含羧酸盐的添加剂和通过所述方法制备的产品的方法，其中所述方法包括：a）使用碱土金属碱将至少两种烷基酚的混合物中和 促进剂的存在以产生烷基酚盐的混合物，其中至少两种烷基酚的混合物包含至少第一烷基苯酚，其中烷基衍生自异构化的α-烯烃和第二烷基苯酚，其中烷基 衍生自支链烯烃; （b）在足以将至少20摩尔％的起始烷基酚转化为水杨酸烷基酯的羧化条件下使用二氧化碳使步骤（a）中获得的烷基酚盐的混合物羧化; 和（c）从步骤（b）中产生的产物中除去至少约10％的至少两种烷基酚的起始混合物以产生所述添加剂。