公开(公告)号：US20160200869A1

公开(公告)日：2016-07-14

申请号：US14911336

申请日：2014-07-10

Applicant: DSM IP ASSETS B.V.

Inventor： Wilhelmus Petrus Johannes APPEL ,  Carel Frederik Constantijn FITIÉ ,  Atze Jan NIJENHUIS ,  Beert Jacobus KEESTRA ,  Josien KRIJGSMAN ,  Michel Henri Chrétien Joseph VAN HOUTEM ,  Henricus Marie JANSSEN

IPC: C08G69/40

CPC classification number: C08G69/28 ,  C07C231/02 ,  C08G69/40 ,  C08G69/44 ,  C07C233/78 ,  C07C233/80

Abstract: Process for the production of a thermoplastic polymer comprising segments of a diamide, the process comprising: 1) a first step of preparing a reaction mixture comprising a diamine H2N—Y—NH2 Form. (I), and a diester of a dicarboxylic acid Form. (II) 2) a second step of heating the reaction mixture to a temperature at least 5° C. above the crystallization temperature of the diester and a least 5° C. below the melting temperature of the formed amide (formula III) in the presence of an alkaline or earth alkaline alkoxy catalyst Form. (III) wherein X and Y are the same or different and are an aliphatic group comprising 2-12 carbon atoms or an aromatic group comprising 6-20 carbon atoms, R1 and R2 are the same or different and are an aliphatic group comprising 2-15 carbon atoms and wherein R equals R1 or R2 and are the same or different. 3) optionally a third step of quenching the catalyst of the reaction mixture obtained in the second step by adding an acid to the reaction mixture and 4) a fourth step of adding further components to the reaction mixture obtained in the second step, or if the third step has been applied to the reaction mixture obtained in the third step, and so producing the thermoplastic polymer comprising the segments of the diamide.

Abstract translation: 制备包含二酰胺链段的热塑性聚合物的方法，该方法包括：1）制备包含二胺H 2 N -Y-NH 2形式的反应混合物的第一步骤。 （I）和二羧酸形式的二酯。 （II）2）将反应混合物加热至高于二酯的结晶温度至少5℃的温度并且在所形成的酰胺（式III）的熔融温度以下的至少5℃的第二步骤 存在碱性或碱性碱性烷氧基催化剂形式。 （III）其中X和Y相同或不同，是包含2-12个碳原子的脂族基团或包含6-20个碳原子的芳族基团，R 1和R 2相同或不同，是包含2- 15个碳原子，其中R等于R1或R2并且相同或不同。 3）任选的第三步骤，通过向反应混合物中加入酸来淬灭第二步获得的反应混合物的催化剂; 4）第四步骤，向第二步获得的反应混合物中加入其他组分，或者如果 已经将第三步骤应用于在第三步骤中获得的反应混合物，因此制备包含二酰胺链段的热塑性聚合物。