公开(公告)号：US20190144365A1

公开(公告)日：2019-05-16

申请号：US16300269

申请日：2017-05-11

Applicant: DSM IP ASSETS B.V.

Inventor： Matthias BELLER ,  Werner BONRATH ,  Johannes Gerardus DE VRIES ,  Yuting FAN ,  Sandra HÜBNER ,  Laurent LEFORT ,  Jonathan Alan MEDLOCK ,  Pim PUYLAERT ,  Richard VAN HECK

IPC: C07C29/149 ,  B01J31/18 ,  B01J31/22 ,  B01J31/24

CPC classification number: C07C29/149 ,  B01J31/0212 ,  B01J31/1805 ,  B01J31/181 ,  B01J31/226 ,  B01J31/24 ,  B01J31/2404 ,  B01J2231/643 ,  B01J2531/0258 ,  B01J2531/821 ,  B01J2531/825 ,  B01J2531/842 ,  B01J2531/845 ,  C07C31/125 ,  C07C33/14 ,  C07C33/22 ,  C07C33/32 ,  C07C2601/16 ,  C07C31/20

Abstract: The present invention relates to a selective reduction of esters to their corresponding alcohols.

公开(公告)号：US20190300462A1

公开(公告)日：2019-10-03

申请号：US16300944

申请日：2017-05-11

Applicant: DSM IP ASSETS B.V.

Inventor： Matthias BELLER ,  Werner BONRATH ,  Johannes Gerardus DE VRIES ,  Yuting FAN ,  Sandra HÜBNER ,  Laurent LEFORT ,  Jonathan Alan MEDLOCK ,  Pim PUYLAERT ,  Richard VAN HECK

IPC: C07C29/145 ,  B01J31/24 ,  B01J31/22 ,  C07D307/83

Abstract: The present invention relates to a selective reduction of specific aldehydes and ketones to their corresponding alcohols.

公开(公告)号：US20160221913A1

公开(公告)日：2016-08-04

申请号：US14760885

申请日：2014-01-16

Applicant: DSM IP ASSETS B.V.

Inventor： Rudy Francois Maria Jozef PARTON ,  Michele Catherine Christianne JANSSEN ,  Barthel ENGENDAHL ,  Johannes Gerardus DE VRIES

IPC: C07C51/373 ,  C07C51/42 ,  C07C51/12

CPC classification number: C07C51/373 ,  C07C51/09 ,  C07C51/12 ,  C07C51/14 ,  C07C51/42 ,  C07C51/44 ,  C07C51/48 ,  C07D307/32 ,  C07C59/147 ,  C07C55/14 ,  C07C57/03

Abstract: The invention relates to a process for the production of 5-formylvaleric acid and adipic acid or esters thereof from an isomeric mixture of pentenoic acid or esters thereof said mixture comprising at least 4-pentenoic acid or esters thereof, and further comprising 3-pentenoic acid and/or 2-pentenoic acid or esters thereof.The process allows for efficient production of two different intermediates for producing polyamide using a single process, with good selectivity, little waste, in an economically efficient fashion. The process is very suitable to use an isomeric pentenoic acid mixture obtained from valerolactone, and can be used to produce renewable polyamide intermediates using a single process.

Abstract translation: 本发明涉及从戊烯酸或其酯的异构体混合物生产5-甲酰戊酸和己二酸或其酯的方法，所述混合物包含至少4-戊烯酸或其酯，并且还包含3-戊烯酸 和/或2-戊烯酸或其酯。 该方法允许以经济有效的方式有效地生产用于使用单一工艺生产聚酰胺的两种不同中间体，具有良好的选择性，少量的废料。 该方法非常适合于使用由戊内酯获得的异戊烯酸混合物，并可用于使用单一工艺生产可再生聚酰胺中间体。