公开(公告)号：US20130244167A1

公开(公告)日：2013-09-19

申请号：US13755489

申请日：2013-01-31

申请人： Daiki YAMASHITA ,  Yoshihiro Moriya ,  Yukiko Nakajima ,  Taichi Nemoto ,  Yoshitaka Yamauchi ,  Keiji Makabe ,  Masahide Yamada ,  Suzuka Amemori

发明人： Daiki YAMASHITA ,  Yoshihiro Moriya ,  Yukiko Nakajima ,  Taichi Nemoto ,  Yoshitaka Yamauchi ,  Keiji Makabe ,  Masahide Yamada ,  Suzuka Amemori

IPC分类号： G03G9/087

CPC分类号： G03G9/08755 ,  G03G9/0821 ,  G03G9/0825 ,  G03G9/08795 ,  G03G9/08797

摘要： A toner including a binder resin having a glass transition temperature (Tg) observed at least at one point from 25 to 65° C. in a differential scanning calorimeter at a rate of temperature increase of 5° C./min, wherein the toner has a structure in which a structure appearing as a high phase difference image is dispersed in a structure appearing as a low phase difference image in a two-dimensional phase difference image observed by tapping mode AFM, and an X-ray diffraction chart in which a peak originated from an crystalline resin is observed in a range of a diffraction angle 2θ of from 20 to 25°, and wherein a ratio (I1/I2) of an intensity of the peak originated from an crystalline resin to an intensity (I2) of a halo originated from an amorphous composition is from 0.2 to 1.

摘要翻译： 在差示扫描量热计中以5℃/分钟的升温速率，在至少25℃至65℃的一点处观察到具有玻璃化转变温度（Tg）的粘合剂树脂的调色剂，其中调色剂具有 在通过分接模式AFM观察到的二维相位差图像中，作为高相位差图像的结构分散在作为低相位差图像的结构中的结构，以及X射线衍射图，其中峰值 在衍射角2θ为20°〜25°的范围内观察到来自结晶性树脂，并且其中源于结晶性树脂的峰强度与（I 2）的强度（I 2）的比（I 1 / I 2） 来自无定形组合物的卤素为0.2至1。

公开(公告)号：US09012116B2

公开(公告)日：2015-04-21

申请号：US13755489

申请日：2013-01-31

申请人： Daiki Yamashita ,  Yoshihiro Moriya ,  Yukiko Nakajima ,  Taichi Nemoto ,  Yoshitaka Yamauchi ,  Keiji Makabe ,  Masahide Yamada ,  Suzuka Amemori

发明人： Daiki Yamashita ,  Yoshihiro Moriya ,  Yukiko Nakajima ,  Taichi Nemoto ,  Yoshitaka Yamauchi ,  Keiji Makabe ,  Masahide Yamada ,  Suzuka Amemori

IPC分类号： G03G9/087 ,  G03G9/08

CPC分类号： G03G9/08755 ,  G03G9/0821 ,  G03G9/0825 ,  G03G9/08795 ,  G03G9/08797

摘要： A toner including a binder resin having a glass transition temperature (Tg) observed at least at one point from 25 to 65° C. in a differential scanning calorimeter at a rate of temperature increase of 5° C./min, wherein the toner has a structure in which a structure appearing as a high phase difference image is dispersed in a structure appearing as a low phase difference image in a two-dimensional phase difference image observed by tapping mode AFM, and an X-ray diffraction chart in which a peak originated from an crystalline resin is observed in a range of a diffraction angle 2θ of from 20 to 25°, and wherein a ratio (I1/I2) of an intensity of the peak originated from an crystalline resin to an intensity (I2) of a halo originated from an amorphous composition is from 0.2 to 1.

摘要翻译： 在差示扫描量热计中以5℃/分钟的升温速率，在至少25℃至65℃的一点处观察到具有玻璃化转变温度（Tg）的粘合剂树脂的调色剂，其中调色剂具有 在通过分接模式AFM观察到的二维相位差图像中，作为高相位差图像的结构分散在作为低相位差图像的结构中的结构，以及X射线衍射图 在衍射角2θ的范围内观察到来自结晶性树脂; 为20至25°，并且其中源于结晶树脂的峰的强度与源自无定形组合物的卤素的强度（I 2）的比（I 1 / I 2）为0.2至1。

公开(公告)号：US20140342284A1

公开(公告)日：2014-11-20

申请号：US14344515

申请日：2012-09-12

申请人： Yoshihiro Moriya ,  Masahide Yamada ,  Taichi Nemoto ,  Yukiko Nakajima ,  Yoshitaka Yamauchi ,  Keiji Makabe ,  Daiki Yamashita ,  Suzuka Amemori ,  Akiyoshi Sabu

发明人： Yoshihiro Moriya ,  Masahide Yamada ,  Taichi Nemoto ,  Yukiko Nakajima ,  Yoshitaka Yamauchi ,  Keiji Makabe ,  Daiki Yamashita ,  Suzuka Amemori ,  Akiyoshi Sabu

IPC分类号： G03G9/00

CPC分类号： G03G9/08755 ,  G03G9/0821 ,  G03G9/08788 ,  G03G9/08791 ,  G03G9/08795 ,  G03G9/08797

摘要： An electrophotographic toner including: a binder resin, wherein the binder resin has one glass transition temperature Tg and the glass transition temperature Tg of the binder resin is within 25° C. to 65° C. as measured in second heating with a differential scanning calorimeter at a heating rate of 5° C./min, and wherein a phase image of the binder resin obtained with an atomic force microscope (AFM) of tapping mode contains first phase difference regions and a second phase difference region such that the first phase difference regions are dispersed in the second phase difference region, where the first phase difference regions correspond to greater phase difference regions and the second phase difference region corresponds to a smaller phase difference region when an intermediate value between a maximum value and a minimum value of the phase differences is used as a threshold.

摘要翻译： 一种电子照相调色剂，包括：粘合剂树脂，其中粘合剂树脂具有一个玻璃化转变温度Tg，并且粘合剂树脂的玻璃化转变温度Tg在25℃至65℃之间，如用差示扫描量热计 以5℃/分钟的加热速率进行加压，其中用分接模式的原子力显微镜（AFM）获得的粘合剂树脂的相位图像包含第一相位差区域和第二相位差区域，使得第一相位差 区域分散在第二相位差区域中，其中第一相位差区域对应于较大的相位差区域，并且当相位的最大值和最小值之间的中间值时，第二相位差区域对应于较小的相位差区域 差异用作阈值。

公开(公告)号：US20130171550A1

公开(公告)日：2013-07-04

申请号：US13728060

申请日：2012-12-27

申请人： Suzuka Amemori ,  Masahide Yamada ,  Yoshihiro Moriya ,  Taichi Nemoto ,  Yukiko Nakajima ,  Yoshitaka Yamauchi ,  Daiki Yamashita ,  Keiji Makabe ,  Akiyoshi Sabu

发明人： Suzuka Amemori ,  Masahide Yamada ,  Yoshihiro Moriya ,  Taichi Nemoto ,  Yukiko Nakajima ,  Yoshitaka Yamauchi ,  Daiki Yamashita ,  Keiji Makabe ,  Akiyoshi Sabu

IPC分类号： G03G9/00 ,  G03G15/08

CPC分类号： G03G9/08755 ,  G03G9/08788 ,  G03G9/08797 ,  G03G15/08

摘要： To provide a toner including at least a binder resin and a colorant, wherein the binder resin has two glass transition temperatures Tg1 and Tg2 in a differential scanning calorimetry at a heating speed of 5° C./min, the glass transition temperature Tg1 is −20° C. to 20° C., and the glass transition temperature Tg2 is 35° C. to 65° C., wherein the binder resin comprises a polyester skeleton and a ring-containing skeleton molecule at ends thereof, and wherein the binder resin is obtained by block copolymerization of: a polyester skeleton A which includes a structural unit obtained by dehydration condensation of a hydroxycarboxylic acid in a repeating structure; and a skeleton B which does not include a structural unit obtained by dehydration condensation of a hydroxycarboxylic acid in a repeating structure.

摘要翻译： 为了提供至少包含粘合剂树脂和着色剂的调色剂，其中粘合剂树脂在加热速度为5℃/分钟的差示扫描量热法中具有两个玻璃化转变温度Tg1和Tg2，玻璃化转变温度Tg1为 - 20℃至20℃，玻璃化转变温度Tg2为35℃至65℃，其中粘合剂树脂在其端部包含聚酯骨架和含环骨架分子，并且其中粘合剂 树脂通过以下方式的嵌段共聚获得：聚酯骨架A，其包含通过重复结构的羟基羧酸的脱水缩合获得的结构单元; 和骨架B，其不包含通过重复结构的羟基羧酸的脱水缩合得到的结构单元。

公开(公告)号：US09141013B2

公开(公告)日：2015-09-22

申请号：US14344515

申请日：2012-09-12

申请人： Yoshihiro Moriya ,  Masahide Yamada ,  Taichi Nemoto ,  Yukiko Nakajima ,  Yoshitaka Yamauchi ,  Keiji Makabe ,  Daiki Yamashita ,  Suzuka Amemori ,  Akiyoshi Sabu

发明人： Yoshihiro Moriya ,  Masahide Yamada ,  Taichi Nemoto ,  Yukiko Nakajima ,  Yoshitaka Yamauchi ,  Keiji Makabe ,  Daiki Yamashita ,  Suzuka Amemori ,  Akiyoshi Sabu

IPC分类号： G03G9/08 ,  G03G9/087

CPC分类号： G03G9/08755 ,  G03G9/0821 ,  G03G9/08788 ,  G03G9/08791 ,  G03G9/08795 ,  G03G9/08797

摘要： An electrophotographic toner including: a binder resin, wherein the binder resin has one glass transition temperature Tg and the glass transition temperature Tg of the binder resin is within 25° C. to 65° C. as measured in second heating with a differential scanning calorimeter at a heating rate of 5° C./min, and wherein a phase image of the binder resin obtained with an atomic force microscope (AFM) of tapping mode contains first phase difference regions and a second phase difference region such that the first phase difference regions are dispersed in the second phase difference region, where the first phase difference regions correspond to greater phase difference regions and the second phase difference region corresponds to a smaller phase difference region when an intermediate value between a maximum value and a minimum value of the phase differences is used as a threshold.

摘要翻译： 一种电子照相调色剂，包括：粘合剂树脂，其中粘合剂树脂具有一个玻璃化转变温度Tg，并且粘合剂树脂的玻璃化转变温度Tg在25℃至65℃之间，如用差示扫描量热计 以5℃/分钟的加热速率进行加压，其中用分接模式的原子力显微镜（AFM）获得的粘合剂树脂的相位图像包含第一相位差区域和第二相位差区域，使得第一相位差 区域分散在第二相位差区域中，其中第一相位差区域对应于较大的相位差区域，并且当相位的最大值和最小值之间的中间值时，第二相位差区域对应于较小的相位差区域 差异用作阈值。

公开(公告)号：US08932790B2

公开(公告)日：2015-01-13

申请号：US13716385

申请日：2012-12-17

申请人： Yoshitaka Yamauchi ,  Masahide Yamada ,  Yoshihiro Moriya ,  Taichi Nemoto ,  Yukiko Nakajima ,  Keiji Makabe ,  Daiki Yamashita ,  Suzuka Amemori ,  Akiyoshi Sabu

发明人： Yoshitaka Yamauchi ,  Masahide Yamada ,  Yoshihiro Moriya ,  Taichi Nemoto ,  Yukiko Nakajima ,  Keiji Makabe ,  Daiki Yamashita ,  Suzuka Amemori ,  Akiyoshi Sabu

IPC分类号： G03G9/087 ,  C08G63/91 ,  G03G15/08 ,  G03G9/08

CPC分类号： G03G9/08755 ,  G03G9/0821 ,  G03G9/08788 ,  G03G9/08795 ,  G03G9/08797 ,  G03G15/08

摘要： The toner includes a pigment; and a block copolymer having a polyester block A including a residual group of a hydroxycarboxylic acid, and a polyester block B including an anionic group. When cross-section of the block copolymer is observed by a tapping mode atomic force microscope to obtain a phase image of the cross-section, the polyester block B, which has relatively large phase delay, is dispersed as domains having an average size of from 20 nm to 100 nm in a domain of the polyester block A, which has relatively small phase delay. The block copolymer has a first glass transition temperature of from −20° C. to 20° C., and a second glass transition temperature of from 35° C. to 65° C. when the first and second glass transition temperatures are determined from a thermogram obtained by subjecting the block copolymer to differential scanning calorimetry (DSC) at a temperature rising speed of 5° C./min.

摘要翻译： 调色剂包括颜料; 和具有包含残基的羟基羧酸的聚酯嵌段A和包含阴离子基团的聚酯嵌段B的嵌段共聚物。 当通过攻丝模式原子力显微镜观察嵌段共聚物的横截面以获得横截面的相位图像时，相位延迟相对较大的聚酯嵌段B被分散为具有平均尺寸为 具有相对较小的相位延迟的聚酯嵌段A的畴中的20nm至100nm。 当第一和第二玻璃化转变温度由下式确定时，嵌段共聚物的第一玻璃化转变温度为-20℃至20℃，第二玻璃化转变温度为35℃至65℃ 通过以5℃/分钟的升温速度对嵌段共聚物进行差示扫描量热法（DSC）而得到的热分析图。

公开(公告)号：US08735040B2

公开(公告)日：2014-05-27

申请号：US13728060

申请日：2012-12-27

申请人： Suzuka Amemori ,  Masahide Yamada ,  Yoshihiro Moriya ,  Taichi Nemoto ,  Yukiko Nakajima ,  Yoshitaka Yamauchi ,  Daiki Yamashita ,  Keiji Makabe ,  Akiyoshi Sabu

发明人： Suzuka Amemori ,  Masahide Yamada ,  Yoshihiro Moriya ,  Taichi Nemoto ,  Yukiko Nakajima ,  Yoshitaka Yamauchi ,  Daiki Yamashita ,  Keiji Makabe ,  Akiyoshi Sabu

IPC分类号： G03G9/087

CPC分类号： G03G9/08755 ,  G03G9/08788 ,  G03G9/08797 ,  G03G15/08

摘要： To provide a toner including at least a binder resin and a colorant, wherein the binder resin has two glass transition temperatures Tg1 and Tg2 in a differential scanning calorimetry at a heating speed of 5° C./min, the glass transition temperature Tg1 is −20° C. to 20° C., and the glass transition temperature Tg2 is 35° C. to 65° C., wherein the binder resin comprises a polyester skeleton and a ring-containing skeleton molecule at ends thereof, and wherein the binder resin is obtained by block copolymerization of: a polyester skeleton A which includes a structural unit obtained by dehydration condensation of a hydroxycarboxylic acid in a repeating structure; and a skeleton B which does not include a structural unit obtained by dehydration condensation of a hydroxycarboxylic acid in a repeating structure.

摘要翻译： 为了提供至少包含粘合剂树脂和着色剂的调色剂，其中粘合剂树脂在加热速度为5℃/分钟的差示扫描量热法中具有两个玻璃化转变温度Tg1和Tg2，玻璃化转变温度Tg1为 - 20℃至20℃，玻璃化转变温度Tg2为35℃至65℃，其中粘合剂树脂在其端部包含聚酯骨架和含环骨架分子，并且其中粘合剂 树脂通过以下方式的嵌段共聚获得：聚酯骨架A，其包含通过重复结构的羟基羧酸的脱水缩合获得的结构单元; 和骨架B，其不包含通过重复结构的羟基羧酸的脱水缩合得到的结构单元。

公开(公告)号：US08685604B2

公开(公告)日：2014-04-01

申请号：US13609627

申请日：2012-09-11

申请人： Yoshihiro Moriya ,  Masahide Yamada ,  Taichi Nemoto ,  Yukiko Nakajima ,  Yoshitaka Yamauchi ,  Daiki Yamashita ,  Keiji Makabe ,  Akiyoshi Sabu ,  Suzuka Amemori

发明人： Yoshihiro Moriya ,  Masahide Yamada ,  Taichi Nemoto ,  Yukiko Nakajima ,  Yoshitaka Yamauchi ,  Daiki Yamashita ,  Keiji Makabe ,  Akiyoshi Sabu ,  Suzuka Amemori

IPC分类号： G03G9/087 ,  G03G9/08

CPC分类号： G03G9/08788 ,  G03G9/0806 ,  G03G9/0825 ,  G03G9/08755 ,  G03G9/08791 ,  G03G9/08795 ,  G03G9/08797

摘要： A toner including a colorant and a first binder resin is provided. The first binder resin has first and second glass transition points at a temperature Tg1 of −20 to 20° C. and a temperature Tg2 of 35 to 65° C., respectively, measured by a differential scanning calorimeter at a heating rate of 5° C./min. A ratio h1/h2 of a baseline displacement h1 observed in the first glass transition point to a baseline displacement h2 observed in the second glass transition point is less than 1.0. The first binder resin has a structure in which a first phase is dispersed in a second phase. The first and second phases consist of portions having larger and smaller phase difference values, respectively, than an intermediate value between maximum and minimum phase difference values in a binarized phase image obtained by an atomic force microscope with a tapping mode method.

摘要翻译： 提供了包括着色剂和第一粘合剂树脂的调色剂。 第一粘合剂树脂具有在温度Tg1为-20〜20℃，温差Tg2为35〜65℃的第一和第二玻璃化转变点，差示扫描量热计以5℃的加热速度 C./min。 在第一玻璃化转变点中观察到的基线位移h1与在第二玻璃化转变点中观察到的基线位移h2的比率h1 / h2小于1.0。 第一粘合剂树脂具有第一相分散在第二相中的结构。 第一和第二相分别具有比通过原子力显微镜使用轻敲模式法获得的二值化相位图像中的最大和最小相位差值之间的中间值具有更大和更小的相位差值的部分。

公开(公告)号：US20130202996A1

公开(公告)日：2013-08-08

申请号：US13716385

申请日：2012-12-17

申请人： Yoshitaka Yamauchi ,  Masahide Yamada ,  Yoshihiro Moriya ,  Taichi Nemoto ,  Yukiko Nakajima ,  Keiji Makabe ,  Daiki Yamashita ,  Suzuka Amemori ,  Akiyoshi Sabu

发明人： Yoshitaka Yamauchi ,  Masahide Yamada ,  Yoshihiro Moriya ,  Taichi Nemoto ,  Yukiko Nakajima ,  Keiji Makabe ,  Daiki Yamashita ,  Suzuka Amemori ,  Akiyoshi Sabu

IPC分类号： G03G9/00 ,  G03G15/08

CPC分类号： G03G9/08755 ,  G03G9/0821 ,  G03G9/08788 ,  G03G9/08795 ,  G03G9/08797 ,  G03G15/08

摘要： The toner includes a pigment; and a block copolymer having a polyester block A including a residual group of a hydroxycarboxylic acid, and a polyester block B including an anionic group. When cross-section of the block copolymer is observed by a tapping mode atomic force microscope to obtain a phase image of the cross-section, the polyester block B, which has relatively large phase delay, is dispersed as domains having an average size of from 20 nm to 100 nm in a domain of the polyester block A, which has relatively small phase delay. The block copolymer has a first glass transition temperature of from −20° C. to 20° C., and a second glass transition temperature of from 35° C. to 65° C. when the first and second glass transition temperatures are determined from a thermogram obtained by subjecting the block copolymer to differential scanning calorimetry (DSC) at a temperature rising speed of 5° C./min.

摘要翻译： 调色剂包括颜料; 和具有包含残基的羟基羧酸的聚酯嵌段A和包含阴离子基团的聚酯嵌段B的嵌段共聚物。 当通过攻丝模式原子力显微镜观察嵌段共聚物的横截面以获得横截面的相位图像时，相位延迟相对较大的聚酯嵌段B被分散为具有平均尺寸为 具有相对较小的相位延迟的聚酯嵌段A的畴中的20nm至100nm。 当第一和第二玻璃化转变温度由下式确定时，嵌段共聚物的第一玻璃化转变温度为-20℃至20℃，第二玻璃化转变温度为35℃至65℃ 通过以5℃/分钟的升温速度对嵌段共聚物进行差示扫描量热法（DSC）而得到的热分析图。

公开(公告)号：US09128397B2

公开(公告)日：2015-09-08

申请号：US13471809

申请日：2012-05-15

申请人： Yukiko Nakajima ,  Masahide Yamada ,  Taichi Nemoto ,  Yoshihiro Moriya ,  Yoshitaka Yamauchi ,  Keiji Makabe ,  Daiki Yamashita ,  Akiyoshi Sabu

发明人： Yukiko Nakajima ,  Masahide Yamada ,  Taichi Nemoto ,  Yoshihiro Moriya ,  Yoshitaka Yamauchi ,  Keiji Makabe ,  Daiki Yamashita ,  Akiyoshi Sabu

IPC分类号： G03G9/087 ,  C08G63/60 ,  C08G63/66 ,  C08G77/14

CPC分类号： G03G9/08755 ,  C08G63/60 ,  C08G63/66 ,  C08G77/14 ,  G03G9/08795 ,  G03G9/08797

摘要： A resin for use in toner is provided. The resin comprises an oligomer segment and a soft segment. The oligomer segment comprises a polyhydroxycarboxylic skeleton and an aromatic diol skeleton.

摘要翻译： 提供了用于调色剂的树脂。 树脂包括低聚物片段和软片段。 低聚物片段包含多羟基羧酸骨架和芳族二醇骨架。