公开(公告)号：US11773226B2

公开(公告)日：2023-10-03

申请号：US17429700

申请日：2020-02-13

申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

发明人： Shohei Azami ,  Shinji Ohtomo ,  Toyonari Ito

IPC分类号： C08J5/18 ,  B32B15/09 ,  B32B15/20 ,  B32B27/36 ,  C08G63/60 ,  H05K1/03

CPC分类号： C08J5/18 ,  B32B15/09 ,  B32B15/20 ,  B32B27/36 ,  C08G63/60 ,  B32B2307/204 ,  B32B2457/08 ,  C08J2367/04 ,  H05K1/0326

摘要： Provided is a film including a thermoplastic resin, in which a relative permittivity of the film at a frequency of 1 GHz is 3 or less, a dielectric loss tangent of the film at a frequency of 1 GHz is 0.005 or less, and a molecular orientation (MOR) value of the film, which is measured by a microwave orientation meter, is in a range of 1 to 1.1.

公开(公告)号：US20180215859A1

公开(公告)日：2018-08-02

申请号：US15936535

申请日：2018-03-27

申请人： Mitsubishi Chemical Corporation

发明人： Teruhiko OHARA ,  Naoki SUZUKI ,  Yasuko NAKAJIMA ,  Hiroto ITOU ,  Takayuki AOSHIMA ,  Naoki SUGAI ,  Takanao MATSUMOTO

IPC分类号： C08G18/42 ,  C09J175/06 ,  A43B1/00 ,  C09D175/06 ,  A43B1/14 ,  C08G63/60 ,  C08G63/20 ,  C08G63/16 ,  C08G63/06 ,  C08G18/76 ,  C08G18/66 ,  C08G18/08 ,  C07C69/704 ,  C07C69/70 ,  C07C69/675 ,  C07C69/66 ,  C07C69/40 ,  C07C69/34 ,  C07C59/245 ,  A43B13/04 ,  C08G101/00

CPC分类号： C08G18/4238 ,  A43B1/00 ,  A43B1/14 ,  A43B13/04 ,  C07C59/245 ,  C07C69/34 ,  C07C69/40 ,  C07C69/66 ,  C07C69/675 ,  C07C69/70 ,  C07C69/704 ,  C08G18/14 ,  C08G18/4241 ,  C08G18/4286 ,  C08G18/664 ,  C08G18/7657 ,  C08G18/7671 ,  C08G63/06 ,  C08G63/16 ,  C08G63/20 ,  C08G63/60 ,  C08G2101/0008 ,  C08G2410/00 ,  C09D175/06 ,  C09J175/06

摘要： The invention relates to a method for producing a biomass-resource-derived polyurethane, which comprises: reacting a dicarboxylic acid and an aliphatic diol to produce a polyester polyol; and reacting the polyester polyol and a polyisocyanate compound, wherein the dicarboxylic acid contains at least one component derived from biomass resources, a content of an organic acid in the dicarboxylic acid is more than 0 ppm and not more than 1,000 ppm relative to the dicarboxylic acid, and a pKa value of the organic acid at 25° C. is not more than 3.7.

公开(公告)号：US10035876B2

公开(公告)日：2018-07-31

申请号：US14630131

申请日：2015-02-24

申请人： SOLVAY SA

发明人： Henri Wautier

IPC分类号： C08G63/60 ,  B32B27/36 ,  C08G63/06 ,  C08G63/08 ,  C08G63/80 ,  C08J5/18 ,  C08G63/78 ,  B32B27/08 ,  B32B27/28

CPC分类号： C08G63/60 ,  B32B27/08 ,  B32B27/28 ,  B32B27/36 ,  B32B2250/24 ,  B32B2307/30 ,  B32B2307/7244 ,  B32B2439/60 ,  C08G63/06 ,  C08G63/08 ,  C08G63/78 ,  C08G63/80 ,  C08J5/18 ,  C08J2367/04 ,  Y10T428/1352 ,  Y10T428/1397

摘要： Process for manufacturing a polymer by polycondensation of a hydroxy acid, said polymer comprising at least 80% by weight of units that correspond to the hydroxy acid, according to which at least one polyfunctional reactant capable of giving rise to the formation of a three-dimensional polymer network is mixed with the hydroxy acid, and according to which the mixture is subjected to temperature and pressure conditions and for a duration which are all suitable for giving rise to the formation of the network. Poly(hydroxy acid) (PHA) obtainable by such a process.

公开(公告)号：US20180037768A1

公开(公告)日：2018-02-08

申请号：US15783226

申请日：2017-10-13

申请人： Norma Arcelia Alcantar ,  Ryan Gates Toomey ,  Fei Guo ,  Zeinab Veisi ,  Tunan Peng

发明人： Norma Arcelia Alcantar ,  Ryan Gates Toomey ,  Fei Guo ,  Zeinab Veisi ,  Tunan Peng

IPC分类号： C09D167/04 ,  C08G63/68 ,  C09D7/12 ,  C08G63/60

CPC分类号： C09D167/04 ,  A61K36/33 ,  C08G63/60 ,  C08G63/681 ,  C08K3/08 ,  C08K3/34 ,  C08K3/36 ,  C08K2003/0831 ,  C08K2003/0856 ,  C09D7/61

摘要： Cutin-based devices, coatings and methods of producing such devices and coatings are presented herein. Cutin-like materials (CLMs) are presented which mimic and adapt coatings found in nature for the next generation of functional coatings. Cutin has several advantages including excellent UV resistance, natural resistance to bacteria and viruses, noncorrosive, and stability under abrupt changes in temperature and environment. CLMs can be engineered at the nanoscale and readily impregnated with metals and metal oxides materials.

公开(公告)号：US20170362373A1

公开(公告)日：2017-12-21

申请号：US15532834

申请日：2015-11-30

申请人： BASF SE

发明人： Kian MOLAWI ,  Robert LOOS ,  Andreas KUNKEL

IPC分类号： C08G18/42 ,  C08G63/91 ,  C08G18/73

CPC分类号： C08G18/428 ,  C08G18/4286 ,  C08G18/73 ,  C08G63/08 ,  C08G63/18 ,  C08G63/181 ,  C08G63/60 ,  C08G63/78 ,  C08G63/80 ,  C08G63/91 ,  C08G63/916

摘要： The present invention relates to biodegradable copolyesters with molecular weight Mn from 10 000 to 100 000 measured by GPC, obtainable via reaction of i) from 51 to 84% by weight, based on the copolyester, of a branched polyester middle block produced from aliphatic or aliphatic and aromatic dicarboxylic acids and from aliphatic dihydroxy compounds with molecular weight Mn from 5000 to 25 000 measured by 1H NMR with from 15.9 to 48.9% by weight, based on the copolyester, of a lactide in the presence of a catalyst, and then the resultant polyester triblock with molecular weight Mn measured by 1H NMR from 5800 to 49 500 with ii) from 0.1 to 3% by weight, based on the copolyester, of a diisocyanate. The present invention further relates to a process for the production of, and to the use of, the abovementioned biodegradable copolyesters.

公开(公告)号：US20170335057A1

公开(公告)日：2017-11-23

申请号：US15522801

申请日：2015-10-27

申请人： RESINATE MATERIALS GROUP, INC.

发明人： Rick Tabor ,  Eric David Vrabel ,  Kevin Anthony Rogers ,  Matthew James Beatty ,  Woo-Sung Bae ,  Jack Rogers Kovsky ,  Michael Robert Christy

IPC分类号： C08G63/66 ,  C09D175/06 ,  C08G18/08 ,  C08G18/76 ,  C08G18/48 ,  C08G18/42 ,  C09J175/06 ,  C08G101/00

CPC分类号： C08G63/66 ,  C08G18/14 ,  C08G18/4244 ,  C08G18/4252 ,  C08G18/4837 ,  C08G18/7621 ,  C08G63/60 ,  C08G2101/0008 ,  C08G2101/0083 ,  C08J11/24 ,  C08J2367/02 ,  C09D175/06 ,  C09J175/06 ,  Y02P20/582 ,  Y02W30/706

摘要： Polyester polyols, processes for making them, and applications for the polyols are disclosed. In some aspects, the polyols comprise recurring units from a thermoplastic polyester or an aromatic polyacid source, a glycol, and a hydroxy-functional ketal acid, ester or amide. Optionally, the polyols incorporate recurring units of a hydrophobe. The polyols are made in one or multiple steps; in some aspects, the thermoplastic polyester or aromatic polyacid source and the glycol are reacted first, followed by reaction with the hydroxy-functional ketal acid, ester or amide. The resulting polyols have good transparency and little or no particulate settling or phase separation. High-recycle-content polyols having desirable properties and attributes for formulating polyurethane products, including aqueous polyurethane dispersions, flexible and rigid foams, coatings, adhesives, sealants, and elastomers can be made. The polyols provide a sustainable alternative to bio- or petrochemical-based polyols.

公开(公告)号：US09745413B1

公开(公告)日：2017-08-29

申请号：US15437164

申请日：2017-02-20

申请人： SIRRUS, INC.

发明人： Aniruddha Palsule ,  Jeffrey M. Sullivan ,  Kshitij K. Parab ,  Elliott King ,  William Barrett

IPC分类号： C08G63/16 ,  C08G63/52 ,  C08G63/87

CPC分类号： C08G63/60 ,  B32B27/36 ,  C07C69/593 ,  C08G63/16 ,  C08G63/52 ,  C08G63/87 ,  C08G64/42 ,  C12P7/62 ,  C12P7/625

摘要： Disclosed are compositions comprising polyester macromers containing in one or more chains the residue of one or more diols and one or more diesters wherein the residue of the one or more diols and the one or more diesters alternate along the chain and a portion of the diesters are 1,1-diester-1-alkenes, and optionally one or more dihydrocarbyl dicarboxylates, and at least one terminal end comprises the residue of one of the 1,1-diester-1 alkenes and wherein one or more terminal ends may comprise the residue of one or more diols. The chains may contain the residue of the one or more diols and one or more diesters comprising one or more diesters 1,1-diester-1 alkenes and optionally one or more dihydrocarbyl dicarboxylates randomly disposed along the chains. Disclosed are methods of preparing the polyester macromers and incorporating them in a variety of polyester containing compositions such as coatings and films.

公开(公告)号：US20170232721A1

公开(公告)日：2017-08-17

申请号：US15504595

申请日：2015-07-17

申请人： SK CHEMICALS CO., LTD.

发明人： Seol-Hee LIM ,  Sung-Gi KIM

IPC分类号： B32B27/36 ,  C08G63/60 ,  B32B27/08

CPC分类号： B32B27/36 ,  B32B27/08 ,  B32B27/18 ,  B32B2250/02 ,  B32B2307/516 ,  B32B2307/71 ,  B32B2307/736 ,  B32B2309/105 ,  B32B2519/00 ,  C08G63/199 ,  C08G63/60 ,  C08J5/18 ,  C08K5/00 ,  C08L67/02

摘要： This disclosure relates to a thermo-shrinkable polyester film with excellent UV absorbance and heat resistance. According to one embodiment of the invention, provided is a thermo-shrinkable polyester film comprising a first resin layer comprising polyester resin comprising residues of dicarboxylic acid components comprising aromatic dicarboxylic acid, and residues of diol components comprising 4-(hydroxymethyl)cyclohexylmethyl 4′-(hydroxymethyl)cyclohexanecarboxylate, and 4,4-(oxybis(methylene)bis)cyclohexane methanol; and a second resin layer comprising the polyester resin and a UV absorber, formed on at least one side of the first layer.

公开(公告)号：US20160312008A1

公开(公告)日：2016-10-27

申请号：US15203991

申请日：2016-07-07

申请人： Furanix Technologies B.V.

发明人： Laszlo Sipos

IPC分类号： C08K5/52

CPC分类号： C08G63/85 ,  C08G63/181 ,  C08G63/60 ,  C08G63/668 ,  C08G63/672 ,  C08G63/80 ,  C08K5/52

摘要： A process for preparing a polymer having a 2,5-furandicarboxylate moiety within the polymer backbone and having a number average molecular weight of at least 10,000 (as determined by GPC based on polystyrene standards) includes a first step where a prepolymer is made having the 2,5-furandicarboxylate moiety within the polymer backbone, followed in a second step by a polycondensation reaction. In the first step a 2,5-furandicarboxylate ester is transesterified with a compound or mixture of compounds containing two or more hydroxyl groups, in the presence of a tin(IV) based transesterification catalyst. In the second step at reduced pressure and under melt conditions the prepolymer prepared in the first step is polycondensed in the presence of a tin (II) based polycondensation catalyst until the polymer is obtained. This polymer may then be subjected to Solid State Polycondensation. Polymers so produced may have a 2,5-furandicarboxylate moiety within the polymer backbone, and having a number average molecular weight of at least 20,000 (as determined by GPC based on styrene standards), and an absorbance as a 5 mg/mL solution in a dichloromethane:hexafluoroisopropanol 8:2 at 400 nm of below 0.05.

摘要翻译： 制备聚合物主链中具有2,5-呋喃二羧酸酯部分并具有至少10,000的数均分子量（通过基于聚苯乙烯标准的GPC测定）的聚合物的方法包括第一步骤，其中制备预聚物，其具有 2,5-呋喃二羧酸酯部分，然后在第二步中进行缩聚反应。 在第一步中，在锡（IV）基酯交换催化剂的存在下，将2,5-呋喃二羧酸酯与含有两个或多个羟基的化合物或混合物进行酯交换。 在减压和熔融条件下的第二步中，在第一步中制备的预聚物在基于锡（II）的缩聚催化剂的存在下进行缩聚，直至得到聚合物。 然后可以对该聚合物进行固态缩聚。 如此制备的聚合物可以在聚合物主链内具有2,5-呋喃二羧酸酯部分，并且具有至少20,000的数均分子量（通过基于苯乙烯标准的GPC测定），并且作为5mg / mL溶液的吸光度 二氯甲烷：六氟异丙醇8：2在400nm以下0.05以下。

公开(公告)号：US09469761B2

公开(公告)日：2016-10-18

申请号：US13337725

申请日：2011-12-27

申请人： Toyonari Ito ,  Changbo Shim

发明人： Toyonari Ito ,  Changbo Shim

IPC分类号： C08L83/10 ,  C08L67/00 ,  C08J5/04 ,  C08L67/03 ,  C08J5/18 ,  C08J5/24 ,  C08G63/60 ,  C08L69/00 ,  C08L83/04 ,  H05K1/03 ,  C08L83/12

CPC分类号： C08L67/00 ,  C08G63/60 ,  C08G77/445 ,  C08G77/46 ,  C08J5/04 ,  C08J5/18 ,  C08J5/24 ,  C08J2300/12 ,  C08J2367/00 ,  C08L67/03 ,  C08L69/00 ,  C08L83/04 ,  C08L83/10 ,  C08L83/12 ,  H05K1/0326 ,  H05K2201/0141

摘要： An object of the present invention is to provide a liquid crystal polyester-containing liquid composition which is capable of producing a prepreg and a resin film in which surface defects are remarkably reduced even in case of drying at high temperature to remove the solvent in the production process. Disclosed Are a liquid crystal polyester-containing liquid composition comprising a liquid crystal polyester, an organic solvent, and one or more kinds of selected leveling agents, wherein the content of the leveling agent is from 0.001 to 2.0 parts by mass based on 100 parts by mass of the total amount of the liquid crystal polyester and the organic solvent; and a method for producing a resin film, which comprises applying the above-described liquid crystal polyester-containing liquid composition on a support, and then removing the solvent from the liquid crystal polyester-containing liquid composition on the support at 50° C. or higher.

摘要翻译： 本发明的目的在于提供一种能够制造预浸料和树脂膜的液晶聚酯的液体组合物，其中即使在高温下干燥以除去生产中的溶剂，表面缺陷也显着降低 处理。 公开了包含液晶聚酯，有机溶剂和一种或多种选择的流平剂的液晶聚酯的液体组合物，其中流平剂的含量相对于100份（重量）为0.001份 液晶聚酯和有机溶剂的总量的质量; 以及制造树脂膜的方法，其包括将上述含液晶聚酯的液体组合物涂布在载体上，然后从载体上的液晶聚酯的液体组合物中在50℃下除去溶剂，或 更高。