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    Process for α,β-dihydroxyalkenes and derivatives
    3.
    发明授权
    Process for α,β-dihydroxyalkenes and derivatives 失效
    α，β-二羟基烯醇和衍生物的方法

    公开(公告)号：US07199252B2

    公开(公告)日：2007-04-03

    申请号：US11204786

    申请日：2005-08-16

    申请人： Robert Thomas Hembre ,  Jonathan Michael Penney

    发明人： Robert Thomas Hembre ,  Jonathan Michael Penney

    IPC分类号： C07D317/38

    CPC分类号： C07D301/14 ,  C07B2200/07 ,  C07B2200/09 ,  C07C29/172 ,  C07C29/44 ,  C07C31/20 ,  C07C33/025 ,  C07C31/22 ,  C07C31/24

    摘要： Disclosed is a process wherein a first olefin selected from certain α,β-dihydroxyalkenes and 4-(alkenyl)ethylenecarbonates is reacted with a second olefin reactant to produce an olefin metathesis product. When the first olefin reactant is an optically enriched or enantiomerically pure α,β-dihydroxyalkene, cross metathesis reactions produce products possessing the same optical purity. The α,β-dihydroxyalkenes and the 4-(alkenyl)ethylene carbonates may be converted to hydrogenated products, and the 4-(alkenyl)ethylenecarbonates may be decarboxylated to provide the corresponding epoxides. The products of the disclosure may be used as monomers for the preparation of specialty polyesters and as intermediates in the manufacture pharmaceuticals and other chemicals.

    摘要翻译： 公开了一种方法，其中选自某种α，β-二羟基烯烃和4-（链烯基）亚乙基碳酸酯的第一种烯烃与第二种烯烃反应物反应以产生烯烃复分解产物。 当第一种烯烃反应物是光学富集或对映体纯的α，β-二羟基亚油，交叉复分解反应产生具有相同光学纯度的产物。 α，β-二羟基烯烃和4-（烯基）亚乙基碳酸酯可以转化为氢化产物，并且4-（烯基）亚乙基碳酸酯可以脱羧以提供相应的环氧化物。 本公开的产品可以用作制备特种聚酯的单体和作为制造药物和其它化学品的中间体。

    PASSIVATION OF A HOMOGENEOUS HYDROGENATION CATALYST FOR THE PRODUCTION OF ETHYLENE GLYCOL
    5.
    发明申请
    PASSIVATION OF A HOMOGENEOUS HYDROGENATION CATALYST FOR THE PRODUCTION OF ETHYLENE GLYCOL 有权
    用于生产乙烯甘油的均质加氢催化剂的钝化

    公开(公告)号：US20130253230A1

    公开(公告)日：2013-09-26

    申请号：US13428333

    申请日：2012-03-23

    申请人： David William Norman ,  Jonathan Michael Penney ,  Peter Borden Mackenzie

    发明人： David William Norman ,  Jonathan Michael Penney ,  Peter Borden Mackenzie

    IPC分类号： C07C29/136

    CPC分类号： C07C29/147 ,  B01J31/24 ,  B01J31/2404 ,  B01J31/2409 ,  B01J2231/643 ,  B01J2531/821 ,  B01J2540/10 ,  Y02P20/52 ,  Y02P20/582 ,  C07C31/202

    摘要： A process for making ethylene glycol by feeding reactants including 1,2-dioxygenated organic compounds, an organometallic homogeneous catalyst, and hydrogen to a hydrogenation reactor, reacting at least a portion of the reactants with hydrogen in the presence of the organometallic homogeneous catalyst to produce a reaction product mixture containing ethylene glycol, and passivating the catalyst by contacting the catalyst with a carbon monoxide to thereby suppress the formation of by-product diols other thatn the ethylene glycol primary product, and suppress the formation of by-product tetrols and by-product glycolaldehyde acetals; and separating at least a portion of the ethylene glycol from the reaction product mixture.

    摘要翻译： 通过将包括1,2-二氧化有机化合物，有机金属均相催化剂和氢的反应物加入到氢化反应器中来制备乙二醇的方法，使至少一部分反应物与氢在有机金属均相催化剂存在下反应，生成 含有乙二醇的反应产物混合物，并通过使催化剂与一氧化碳接触来钝化催化剂，从而抑制乙二醇一级产物以外的副产物二醇的形成，并抑制副产物四环和副产物的形成， 产品乙二醇缩醛; 以及从反应产物混合物中分离出至少一部分乙二醇。

    Passivation of a homogeneous hydrogenation catalyst for the production of ethylene glycol
    6.
    发明授权
    Passivation of a homogeneous hydrogenation catalyst for the production of ethylene glycol 有权
    钝化用于生产乙二醇的均相氢化催化剂

    公开(公告)号：US08969632B2

    公开(公告)日：2015-03-03

    申请号：US13428333

    申请日：2012-03-23

    申请人： David William Norman ,  Jonathan Michael Penney ,  Peter Borden Mackenzie

    发明人： David William Norman ,  Jonathan Michael Penney ,  Peter Borden Mackenzie

    IPC分类号： C07C29/149 ,  C07C29/141 ,  C07C29/145

    CPC分类号： C07C29/147 ,  B01J31/24 ,  B01J31/2404 ,  B01J31/2409 ,  B01J2231/643 ,  B01J2531/821 ,  B01J2540/10 ,  Y02P20/52 ,  Y02P20/582 ,  C07C31/202

    摘要： A process for making ethylene glycol by feeding reactants including 1,2-dioxygenated organic compounds, an organometallic homogeneous catalyst, and hydrogen to a hydrogenation reactor, reacting at least a portion of the reactants with hydrogen in the presence of the organometallic homogeneous catalyst to produce a reaction product mixture containing ethylene glycol, and passivating the catalyst by contacting the catalyst with a carbon monoxide to thereby suppress the formation of by-product diols other that the ethylene glycol primary product, and suppress the formation of by-product tetrols and by-product glycolaldehyde acetals; and separating at least a portion of the ethylene glycol from the reaction product mixture.

    摘要翻译： 通过将包括1,2-二氧化有机化合物，有机金属均相催化剂和氢的反应物加入到氢化反应器中来制备乙二醇的方法，使至少一部分反应物与氢在有机金属均相催化剂存在下反应，生成 含有乙二醇的反应产物混合物，并通过使催化剂与一氧化碳接触来钝化催化剂，从而抑制副产物二醇的形成，而不是乙二醇一级产物，并抑制副产物四环和副产物的形成 产品乙二醇缩醛; 以及从反应产物混合物中分离出至少一部分乙二醇。