公开(公告)号：US5482821A

公开(公告)日：1996-01-09

申请号：US129840

申请日：1993-09-30

申请人： Daniel L. Kapp ,  Janet N. Younathan

发明人： Daniel L. Kapp ,  Janet N. Younathan

IPC分类号： G03C7/00 ,  G03C7/32 ,  G03C7/333 ,  G03C7/38 ,  G03C7/384 ,  G03C7/392

CPC分类号： G03C7/3225

摘要： The invention provides a photographic process and element where the element comprises a light sensitive silver halide layer containing (1) an image dye-forming bicyclic azole coupler having bonded to the coupling site a group other than hydrogen which is clearable during the development process; (2) an azopyrazolone masking coupler; and (3) a stabilizing coupler having bonded to the coupling site only hydrogen atoms and/or carbon atoms which are not cleavable to permit dye formation during development.

摘要翻译： 本发明提供了一种照相方法和元件，其中元件包括光敏卤化银层，其含有（1）成像染料形成双环唑偶合剂，其在偶联位点处键合除氢以外的基团，其在显影过程中是可清除的; （2）氮杂唑酮掩蔽成色剂; 和（3）稳定成色剂，其仅结合到偶联位点上，只有氢原子和/或碳原子不可裂解以允许显影期间形成染料。

公开(公告)号：US5622818A

公开(公告)日：1997-04-22

申请号：US564515

申请日：1995-11-29

申请人： Daniel L. Kapp ,  Janet N. Younathan ,  Robert J. Ross ,  James P. Merrill

发明人： Daniel L. Kapp ,  Janet N. Younathan ,  Robert J. Ross ,  James P. Merrill

IPC分类号： G03C7/333

CPC分类号： G03C7/3335

摘要： A multilayer silver halide color photographic element comprising a support bearing a light-sensitive silver halide emulsion layer and a non-diffusible yellow-colored magenta dye-forming masking coupler wherein the masking coupler is a 2'-hydroxy-5'-substituted-4-phenylazo-5-pyrazolone. The masking coupler has good coupling activity and desirable hues, and can be obtained in good yields by simple syntheses.

摘要翻译： 一种多层卤化银彩色照相元件，其包括带有感光卤化银乳剂层的支持体和不扩散的黄色品红色染料形成掩蔽剂，其中掩蔽成色剂是2'-羟基-5'-取代-4 - 苯偶氮-5-吡唑啉酮。 掩蔽成色剂具有良好的偶联活性和合适的色调，可通过简单合成得到良好的收率。

公开(公告)号：US5466568A

公开(公告)日：1995-11-14

申请号：US130071

申请日：1993-09-30

申请人： Daniel L. Kapp ,  Robert J. Ross ,  Janet N. Younathan ,  Stephen P. Singer

发明人： Daniel L. Kapp ,  Robert J. Ross ,  Janet N. Younathan ,  Stephen P. Singer

IPC分类号： G03C7/00 ,  G03C1/34 ,  G03C7/30 ,  G03C7/333 ,  G03C7/384 ,  G03C7/392 ,  G03C1/08 ,  G03C7/26 ,  G03C7/32

CPC分类号： G03C7/3008 ,  G03C1/34 ,  G03C7/39236

摘要： A photographic element and imaging process used therewith provides reduced fogging where the element comprises a light sensitive silver halide layer containing (1) an azopyrazolone masking coupler and (2) a ballasted aromatic nitro compound having a reduction peak potential which is more positive than -1.3 V vs. the Standard Calomel Electrode.

摘要翻译： 使用的照相元件和成像方法提供了减少的雾化，其中元件包括含有（1）氮杂吡咯酮掩蔽成色剂的光敏卤化银层和（2）具有比-1.3更正的还原峰电位的压载芳族硝基化合物 V与标准Calomel电极。

公开(公告)号：US06309813B1

公开(公告)日：2001-10-30

申请号：US09738730

申请日：2000-12-15

申请人： Janet N. Younathan ,  Daniel L. Kapp ,  Stephen P. Singer ,  David R. Foster

发明人： Janet N. Younathan ,  Daniel L. Kapp ,  Stephen P. Singer ,  David R. Foster

IPC分类号： G03C108

CPC分类号： G03C7/3335 ,  G03C7/39232

摘要： Disclosed is a photographic element comprising a light-sensitive silver halide emulsion layer containing an azopyrazolone masking coupler and a monosubstituted quinone of formula I: wherein R is selected from the group consisting of alkyl, aryl, alkoxy, aryloxy, alkylthio, arylthio, sulfinyl, sulfonyl,sulfamoyl, halogen, cyano, thiol, hydroxy, nitro, acyloxy, sulfonyloxy, heterocyclic, carboxylic acid, carboxylate, carbamoyl, amino, carbonamido and sulfonamido groups.

摘要翻译： 公开了一种照相元件，其包含含有氮杂吡唑酮掩蔽成色剂和式I的单取代醌的感光卤化银乳剂层：其中R选自烷基，芳基，烷氧基，芳氧基，烷硫基，芳硫基，亚磺酰基， 磺酰基，氨磺酰基，卤素，氰基，硫醇，羟基，硝基，酰氧基，磺酰氧基，杂环，羧酸，羧酸酯，氨基甲酰基，氨基，碳酰氨基和亚磺酰氨基。

公开(公告)号：US06440655B1

公开(公告)日：2002-08-27

申请号：US09593088

申请日：2000-06-13

申请人： Steven P. Szatynski ,  James H. Reynolds ,  Janet N. Younathan ,  George J. Burgmaier

发明人： Steven P. Szatynski ,  James H. Reynolds ,  Janet N. Younathan ,  George J. Burgmaier

IPC分类号： G03C7305

CPC分类号： G03C7/30511 ,  G03C7/30552 ,  G03C7/30558 ,  G03C7/30576 ,  G03C7/3924 ,  G03C2007/3027

摘要： A silver halide photographic element comprising at least one silver halide emulsion layer containing a dye-forming coupler which reacts with an oxidized color developing agent to form dye, said silver halide element further comprising a polyester support and an amido compound of Formula I wherein INH is a development inhibitor; LINK is a linking or timing group and m is 0, 1 or 2; R1 and R2 independently represent an aliphatic, aromatic or heterocyclic group, or R1 and R2 together with the nitrogen to which they are attached represent the atoms necessary to form a 5 or 6 membered ring or multiple ring system, or R1 and R2 are independently a —C(═O)(LINK)m—INH group, or are substituted with an —NR3aC(═O)—(LINK)m—INH group, with R3a being defined the same as R1 or R2, and wherein the compound of Formula I does not substantially react with oxidized developer to release INH.

摘要翻译： 一种卤化银照相元件，其包含至少一种含有染料形成成色剂的卤化银乳剂层，其与氧化的彩色显影剂反应形成染料，所述卤化银元素还包含聚酯载体和式I的酰氨基化合物，其中INH为 显影抑制剂; LINK是连接或定时基团，m是0,1或2; R 1和R 2独立地表示脂族，芳族或杂环基团，或者R 1和R 2与它们所连接的氮一起代表必需的原子 形成5或6元环或多环系统，或者R1和R2独立地为-C（= O）（LINK）m-INH基团，或被-NR3aC（= O） - （LINK）m- INH基团，其中R3a定义与R1或R2相同，并且其中式I化合物基本上不与氧化显影剂反应以释放INH。

公开(公告)号：US07175975B2

公开(公告)日：2007-02-13

申请号：US11211937

申请日：2005-08-25

申请人： Stephen P. Singer ,  Christopher Grote ,  Robert C. Stewart ,  John W. Harder ,  David S. Ross ,  Janet N. Younathan ,  Louis Elbert Friedrich

发明人： Stephen P. Singer ,  Christopher Grote ,  Robert C. Stewart ,  John W. Harder ,  David S. Ross ,  Janet N. Younathan ,  Louis Elbert Friedrich

IPC分类号： G03C1/46 ,  G03C1/08 ,  G03C7/26 ,  G03C7/32

CPC分类号： G03C7/30523 ,  G03C7/3029 ,  G03C7/30552 ,  G03C7/3212 ,  G03C7/344 ,  G03C2007/3034 ,  Y10S430/156 ,  Y10S430/158

摘要： This invention relates to a multilayer silver halide photographic element, generally processed with phenylenediamine based developer solutions, comprising a support bearing a cyan dye image-forming unit comprised of at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, and a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one layer additionally contains a 2-substituted-5-amino-1-napthol DIR according to Formula (I): wherein: X is chosen from among hydrogen, halogen atoms, an alkyl group with 6 carbon atoms or less or a N-substituted carbamoyl group where the N substituent is either an alkyl group with 6 carbon atoms or less or an aryl group with 8 total carbon atoms or less; R is a carbonyl or sulfonyl group; and INH is an inhibitor of silver development. It has been found that such 2-substituted-5-amino-1-napthol based DIRs have improved properties and can provide a conventional silver halide photographic element with excellent image structure and color reproduction.

摘要翻译： 本发明涉及通常用基于苯二胺的显影剂溶液加工的多层卤化银照相元件，其中包含载体，该载体带有青色染料影像形成单元，该单元由至少一种红色感光卤化银乳剂层组成，所述红色感光卤化银乳剂层具有至少一种青色染料 包含至少一种具有与其相关的至少一种形成品红色染料的成色剂的至少一种感绿卤化银乳剂层的品红色染料影像形成单元和包含至少一种蓝色感光性银的黄色染料影像形成单元 卤化物乳剂层，其与至少一种黄色染料形成成色剂相关联，其中至少一层另外含有根据式（I）的2-取代-5-氨基-1-萘酚DIR：其中：X选自氢 卤素原子，6个碳原子或更少的烷基或N-取代的氨基甲酰基，其中N取代基是具有6个碳原子的烷基 或更少或具有8个总碳原子或更少的芳基; R是羰基或磺酰基; 而INH是银发展的抑制剂。 已经发现这种2-取代-5-氨基-1-萘酚基DIR具有改进的性能，并且可以提供具有优异的图像结构和色彩再现的常规卤化银照相元件。

公开(公告)号：US06472133B1

公开(公告)日：2002-10-29

申请号：US09592705

申请日：2000-06-13

申请人： James H. Reynolds ,  Steven P. Szatynski ,  Stephen P. Singer ,  George J. Burgmaier ,  Janet N. Younathan ,  Lillian M. Kellogg

发明人： James H. Reynolds ,  Steven P. Szatynski ,  Stephen P. Singer ,  George J. Burgmaier ,  Janet N. Younathan ,  Lillian M. Kellogg

IPC分类号： G03C7305

CPC分类号： G03C7/30511 ,  G03C7/30552

摘要： This invention relates to a silver halide photographic element comprising at least one silver halide emulsion layer containing a dye-forming coupler which reacts with an oxidized color developing agent to form dye, said silver halide element further comprising an amido compound of Formula I wherein INH is a development inhibitor; LINK is a linking or timing group and m is 0, 1 or 2; and wherein INH is a development inhibitor; R1 and R2 independently represent an aliphatic, aromatic or heterocyclic group, or R1 and R2 together with the nitrogen to which they are attached represent the atoms necessary to form a 5 or 6 membered ring or multiple ring system, or R1 and R2 are independently a —C(═O)(LINK)m—INH group, or are substituted with an —NR3aC(═O)—(LINK)m—INH group, with R3a being defined the same as R1 or R2, and wherein the compound of Formula I does not substantially react with oxidized developer to release INH.

摘要翻译： 本发明涉及一种卤化银照相元件，其包含至少一种含有染料形成成色剂的卤化银乳剂层，其与氧化的彩色显影剂反应形成染料，所述卤化银元素还包含式I的酰氨基化合物，其中INH为 显影抑制剂; LINK是连接或时序基团，m是0,1或2; 并且其中INH是开发抑制剂; R 1和R 2独立地表示脂族，芳族或杂环基团，或者R 1和R 2与它们所连接的氮一起代表形成5或6元环或多环体系所必需的原子， 或者R 1和R 2独立地为-C（= O）（LINK）m-INH基团，或被-NR 3 a C（= O） - （LINK）m-INH基团取代，其中R 3a定义与R 1或 R2，并且其中式I的化合物基本上不与氧化的显影剂反应以释放INH。

公开(公告)号：US06458521B1

公开(公告)日：2002-10-01

申请号：US09712427

申请日：2000-11-14

申请人： Philip T. Lau ,  Stephen P. Singer ,  Janet N. Younathan ,  Jerrold N. Poslusny ,  Susan D. Hill ,  Anabisdally I. Bodden

发明人： Philip T. Lau ,  Stephen P. Singer ,  Janet N. Younathan ,  Jerrold N. Poslusny ,  Susan D. Hill ,  Anabisdally I. Bodden

IPC分类号： G03C1815

CPC分类号： G03C7/36 ,  G03C7/24 ,  Y10S430/156

摘要： The invention provides a color photographic element that contains a coupler useful for forming a neutral silver-based image. Such couplers are particularly useful to provide an auxiliary silver-based image for optically recording a sound track in color motion picture films.

摘要翻译： 本发明提供了一种含有可用于形成中性银基图像的成色剂的彩色照相元件。 这种耦合器对于提供用于在彩色电影胶片中光学记录声轨的辅助银基图像特别有用。

公开(公告)号：US6132943A

公开(公告)日：2000-10-17

申请号：US418392

申请日：1999-10-14

申请人： Janet N. Younathan ,  Michael W. Crawley ,  Krishnan Chari

发明人： Janet N. Younathan ,  Michael W. Crawley ,  Krishnan Chari

IPC分类号： C07D231/52 ,  C09B29/50 ,  G03C7/305 ,  G03C7/333 ,  G03C7/384 ,  G03C1/46

CPC分类号： G03C7/3335 ,  G03C7/30547 ,  G03C7/384

摘要： A multilayer silver halide color photographic element is disclosed comprising a support bearing a light-sensitive silver halide emulsion layer and a non-diffusible yellow-colored magenta dye-forming masking coupler of the following formula ##STR1## wherein COUP is a magenta dye-forming coupler having the azo group attached to its coupling position; q is an integer of from 0 to 3, and each R' independently represents a substituent group or two R' groups together complete a ring of from 5-7 atoms, which ring may include 1 or more heteroatoms selected from O, N and S; m is 1 or 2, and DG represents a substituent of the formula ##STR2## where each L.sup.1 represents a divalent linking group, preferably --O(CH.sub.2).sub.y --, --NHCO(CH.sub.2).sub.y --, or --NRCO(CH.sub.2).sub.y --, where R represents an alkyl or aryl group and y represents an integer from 1 to 4; each k is either 0 or 1; each L.sup.2 represents --NHSO.sub.2 --, --NHCO--, --SO.sub.2 NH--, or --CONH--, preferably at least one L.sup.2 group being --NHSO.sub.2 -- or --SO.sub.2 NH--, more preferably --NHSO.sub.2 --; each Z represents --SO.sub.3 M or --PO.sub.3 M, where M represents H or a counter ion such as Na, K, Li, or NH.sub.4 ; and each n represents an integer of from 1 to 5; with the provisos that each DG substituent group, when present, is located in the 4- or 6-position meta to the 2-hydroxyl substituent on the arylazo group, and that when at least one L.sup.1 or L.sup.2 group comprises an --NHSO.sub.2 -- or --SO.sub.2 NH-- group then the total number of Z group substituents on the coupler is at least 2, and when no L.sup.1 or L.sup.2 group comprises an --NHSO.sub.2 -- or --SO.sub.2 NH-- group then the total number of Z group substituents on the coupler is at least 3, and if k is 0 for a DG substituent group then the L.sup.2 group for that DG substituent is either --NHSO.sub.2 -- or --NHCO--.

摘要翻译： 公开了一种多层卤化银彩色照相材料，其包含支持感光卤化银乳剂层的支持体和下式不可扩散的黄色品红色染料形成掩蔽剂，其中COUP是形成品红色染料的成色剂，其具有 偶氮基团连接到其耦合位置; q为0〜3的整数，每个R'独立地表示取代基或两个R'基团一起形成5-7个原子的环，该环可包括1个或多个选自O，N和S的杂原子 ; m为1或2，DG表示下式的取代基，其中每个L1表示二价连接基团，优选-O（CH 2）y - ， - NHCO（CH 2）y - 或-NRCO（CH 2）y - ，其中 R表示烷基或芳基，y表示1至4的整数; 每个k是0或1; 每个L2代表-NHSO2-，-NHCO-，-SO2NH-或-CONH-，优选至少一个L2基团是-NHSO2-或-SO2NH-，更优选-NHSO2-; 每个Z表示-SO 3 M或-PO 3 M，其中M表示H或抗衡离子如Na，K，Li或NH 4; 并且每个n表示1至5的整数; 条件是每个DG取代基（当存在时）位于芳基偶氮基上的2-羟基取代基的4-或6-位，并且当至少一个L1或L2基团包含-NHSO 2 - 或 -SO 2 NH-基团，则成色剂上Z基团取代基的总数至少为2，当没有L1或L2基团包含-NHSO2-或-SO2NH-基团时，耦合器上的Z基团取代基的总数为 至少3，如果DG取代基的k为0，则该DG取代基的L2基团为-NHSO 2 - 或-NHCO-。

公开(公告)号：US06780573B1

公开(公告)日：2004-08-24

申请号：US10449363

申请日：2003-05-30

申请人： Stephen P. Singer ,  Christopher W. Grote ,  Robert C. Stewart ,  Janet N. Younathan ,  Jerrold N. Poslusny

发明人： Stephen P. Singer ,  Christopher W. Grote ,  Robert C. Stewart ,  Janet N. Younathan ,  Jerrold N. Poslusny

IPC分类号： G03C746

CPC分类号： G03C7/30576 ,  G03C7/3022 ,  G03C7/3029 ,  G03C7/4136 ,  G03C2007/3025 ,  G03C2007/3034 ,  Y10S430/156

摘要： The invention relates to a color silver halide photographic element comprising a light-sensitive silver halide emulsion layer, said silver halide emulsion being in reactive association with an amino acid compound according to Formula (I): wherein: COUP is a moiety that reacts with oxidized developer to release the amino acid timing group but does not substantially contribute any density in the visible region to the element after processing is complete; n is 0 or 1; R1 is an alkyl or alkenyl group of 4 carbon atoms or more or an aryl group with 10 carbon atoms or more; R2 is an alkyl or aryl group so the sum total of carbon atoms in R1 and R2 together are at least 5; and PUG is a photographically useful group.

摘要翻译： 本发明涉及一种包含感光卤化银乳剂层的彩色卤化银照相元件，所述卤化银乳剂与根据式（I）的氨基酸化合物反应结合：其中：COUP是与氧化物 显影剂释放氨基酸定时基团，但在加工完成后基本上不对元素的可见区域贡献任何密度; n为0或1; R1为4个或更多个碳原子的烷基或烯基或芳基 具有10个或更多个碳原子; R 2是烷基或芳基，因此R 1和R 2中的碳原子总数至少为5; 和PUU是一个摄影有用的组。