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公开(公告)号：US5871899A
公开(公告)日：1999-02-16
申请号：US848208
申请日：1997-04-30
CPC分类号： G03C7/396 , G03C1/043 , G03C2200/19 , G03C2200/29 , G03C2200/48 , G03C7/3029
摘要： A silver halide color photographic element comprising a support, a silver halide emulsion and poly(alkylene oxide)s wherein greater than 50 percent of the poly(alkylene oxide)s have acidic functional end groups with an aqueous pKa.ltoreq.10, or end groups which will react to form acidic functional end groups with an aqueous pKa.ltoreq.10 during development, on both termini; and wherein the poly(alkylene oxide)s have a molecular weight ranging substantially between 1700 and 6000 AMU.
摘要翻译： 包含载体，卤化银乳剂和聚（环氧烷烃）的卤化银彩色照相材料，其中大于50％的聚（氧化烯）具有酸性官能端基，具有pKa水溶液，或末端 将在开发期间在两个末端上反应以形成具有pKa水溶液的酸性官能端基的基团; 并且其中聚（环氧烷）的分子量基本上在1700和6000AMU之间。
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公开(公告)号：US5789143A
公开(公告)日：1998-08-04
申请号：US846944
申请日：1997-04-30
摘要： This invention relates to a silver halide color photographic element comprising a support, a silver halide emulsion and poly(thioether)s wherein greater than 50 percent of the poly(thioether)s have acidic functional end groups with an aqueous pKa.ltoreq.10, or end groups which will react to form acidic functional end groups with an aqueous pKa.ltoreq.10 during development, on both termini and wherein the poly(thioether)s have a molecular weight greater than 800.
摘要翻译： 本发明涉及包含载体，卤化银乳剂和聚（硫醚）的卤化银彩色照相元件，其中大于50％的聚（硫醚）具有酸性官能端基并具有pKa水溶液， 或端基，其在两个末端在显影期间反应形成具有水性pKa 10的酸性官能端基，并且其中聚（硫醚）的分子量大于800。
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3.发明授权Photographic elements containing development accelerators and release compounds that release development inhibitors 失效含有开发促进剂和释放化合物的照相元件释放开发抑制剂
公开(公告)号：US5478711A
公开(公告)日：1995-12-26
申请号：US250748
申请日：1994-05-27
CPC分类号： G03C7/305 , Y10S430/158
摘要： A photographic element comprising a support having located thereon at least one silver halide emulsion layer, the emulsion layer containing a development accelerator and a release compound that provides a non-imagewise distribution of a development inhibitor moiety. The release compound is characterized in that it comprises a blocking group from which the development inhibitor moiety is released.
摘要翻译： 一种照相元件，包括一个载体，其上设有至少一个卤化银乳剂层，该乳剂层含有显影促进剂和提供显影抑制剂部分的非成像分布的释放化合物。 释放化合物的特征在于其包含释放显影抑制剂部分的封闭基团。
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公开(公告)号：US5567577A
公开(公告)日：1996-10-22
申请号：US539381
申请日：1995-10-05
CPC分类号： G03C7/305 , Y10S430/156 , Y10S430/158 , Y10S430/16
摘要： A photographic element comprising a support having located thereon at least one silver halide emulsion layer, the element containing a release compound that provides a non-imagewise distribution of a photographically active moiety, the release compound comprising a blocking group from which the photographically active moiety is released, the release compound further comprising a ballasting group other than a coupler moiety, and an aqueous solubilizing group, both the ballasting group and the aqueous solubilizing group being attached to the blocking group.
摘要翻译： 一种照相元件，包括其上位于其上的载体，至少一个卤化银乳剂层，所述元件含有提供摄影活性部分的非成像分布的释放化合物，所述释放化合物包含封闭基团，其中照相活性部分为 释放的化合物，还包含除了成色剂部分之外的压载基团的释放化合物和水溶性增溶基团，均压基团和水性增溶基团都连接到封闭基团上。
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5.发明授权Photographic elements containing development accelerators and release compounds that release development inhibitors 失效含有开发促进剂和释放化合物的照相元件释放开发抑制剂
公开(公告)号：US5460932A
公开(公告)日：1995-10-24
申请号：US250189
申请日：1994-05-27
CPC分类号： G03C7/30594 , G03C1/005 , G03C5/50 , G03C7/305 , Y10S430/158
摘要： A photographic element comprising a support having located thereon a first layer which does not contain colloidal silver and a second layer, the first layer containing a release compound that comprises a development inhibitor moiety and a blocking group from which the development inhibitor moiety is non-imagewise released, and the second layer containing a development accelerator.
摘要翻译： 一种照相元件，其特征在于，包括一个载体，所述载体上具有不含胶体银的第一层和第二层，所述第一层含有包含显影抑制剂部分的释放化合物和显影抑制剂部分是非成像的 释放，第二层含有显影促进剂。
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6.发明授权公开(公告)号：US06770428B2
公开(公告)日：2004-08-03
申请号：US10295069
申请日：2002-11-15
IPC分类号： G03C1498
CPC分类号： G03C1/49818 , G03C1/04 , G03C1/49845 , G03C1/49863 , G03C1/49881 , G03C2001/03535 , G03C2001/03558 , G03C2007/3025 , Y10S430/145 , Y10S430/156
摘要： Aqueous-based thermally developable emulsions and photothermographic imaging materials include photosensitive silver halide core-shell grains that comprise at least 20 mol % iodide based on total silver, an amount of iodide in the core of the grains that can be up to the iodide saturation limit in silver iodobromide, and an amount of iodide in the shell of the grains that is at least 2 mol % less than the amount of iodide present in the core, and further provided that the total amount of silver in the shell is from about 10 to about 80 mol % of total silver in the grains. These materials provide desired Dmax and reduced image “print out”.
摘要翻译： 基于水的热显影乳液和光热成像材料包括光敏卤化银核 - 壳晶粒，其包含基于总银的至少20mol％的碘化物，可以达到碘化物饱和极限的晶粒核中的碘化物量 在碘化银中，并且所述晶粒壳中的碘化物的量相对于存在于芯中的碘化物的量少至少2摩尔％，并且进一步规定，壳中的银的总量为约10至 约80mol％的银中总银。 这些材料提供所需的Dmax和缩小的图像“打印输出”。
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7.发明授权公开(公告)号：US06387611B2
公开(公告)日：2002-05-14
申请号：US09764665
申请日：2001-01-18
IPC分类号： G03C1498
CPC分类号： G03C1/498 , G03C1/49809 , G03C1/4989
摘要： There is disclosed an oxidation-reduction imaging forming composition comprising an aqueous based dispersion of (i) nanoparticulate silver carboxylate particles having on the surface of the particles a surface modifier which is a phosphoric acid ester and (ii) an organic reducing agent. In particular, the surface modifiers can be mixtures of mono- and di-esters of orthophosphoric acid and hydroxyl-terminated, oxyethylated long-chain alcohols or oxyethylated alkyl phenols or derivatives thereof. Also disclosed are various compositions including the dispersions including oxidation-reduction imaging forming compositions, thermographic elements and photothermographic compositions and elements. The preferred carboxylate is a silver salt of a long chain fatty acid such as silver behenate. A media milling method and a controlled precipitation method of making the dispersions are also disclosed
摘要翻译： 公开了一种氧化还原成像组合物，其包含（i）纳米颗粒状羧酸银颗粒的水性分散体，其在颗粒表面上具有作为磷酸酯的表面改性剂和（ii）有机还原剂。 特别地，表面改性剂可以是正磷酸和羟基封端的羟乙基化长链醇或羟乙基化烷基酚或其衍生物的单酯和二酯的混合物。 还公开了包括包括氧化还原成像组合物，热成像元件和光热成像组合物和元素的分散体的各种组合物。 优选的羧酸酯是长链脂肪酸的银盐，例如山嵛酸银。 还公开了制备分散体的介质研磨方法和受控沉淀法
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8.发明授权公开(公告)号：US06733959B2
公开(公告)日：2004-05-11
申请号：US09923039
申请日：2001-08-06
IPC分类号： G03C1498
CPC分类号： G03C1/49845 , G03C1/08 , G03C1/09 , G03C1/498 , G03C2001/098 , Y10S430/145 , Y10S430/165
摘要： Photothermographic materials prepared using aqueous formulations include silver halides that are chemically sensitized using certain tellurium-containing compounds. Such tellurium-containing chemical sensitizing compounds are generally provided in aqueous solution or in an aqueous solid particulate dispersion and can be represented by the following Structure I, II, or III: Te(L)m(X1)n (II) Pd(X2)2[Te(R′)2]2 (III) wherein X represents the same or different COR, CSR, CNRRa, CR, PRRa, or P(OR)2 groups, R and Ra are independently alkyl, alkenyl, or aryl groups, L is a ligand derived from a neutral Lewis base, X1 and X2 independently represent a halo, OCN, SCN, S2CNRRa, S2COR, S2CSR S2P(OR)2, S2PRRa, SeCN, TeCN, CN, SR, OR, alkyl, aryl, N3, or O2CR group, R′ is an alkyl or aryl group, p is 2 or 4, m is 0, 1, 2, or 4, and n is 2 or 4 provided that when m is 0 or 2, n is 2 or 4, and when m is 1 or 4, n is 2.
摘要翻译： 使用水性制剂制备的光热照相材料包括使用某些含碲化合物化学增感的卤化银。 这种含碲的化学增感化合物通常提供在水溶液或水性固体颗粒分散体中，并且可以由以下结构I，II或III表示：其中X表示相同或不同的COR，CSR，CNRRa，CR， PRRa或P（OR）2基团，R和Ra独立地是烷基，烯基或芳基，L是衍生自中性路易斯碱的配体，X 1和X 2独立地表示卤素，OCN， SCN，S2CNRRa，S2COR，S2CSR S2P（OR）2，S2PRRa，SeCN，TeCN，CN，SR，OR，烷基，芳基，N 3或O 2 CR基团，R'为烷基或芳基，p为2或4， m为0,1,2或4，n为2或4，条件是当m为0或2时，n为2或4，当m为1或4时，n为2。
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公开(公告)号：US6150077A
公开(公告)日：2000-11-21
申请号：US60802
申请日：1998-04-15
CPC分类号： G03C7/30511 , G03C7/30 , Y10S430/156 , Y10S430/158 , Y10S430/16
摘要： Photographic elements are provided which contain a compound having the formula:R.sup.1 --NH--(Q).sub.m --C(R.sup.2)(R.sup.3)--(TIME).sub.n -PAMwherein: R.sup.1 is an electron withdrawing moiety; Q is a group comprising a conjugated system; m is 0 or 1, and when m=1, --NH--Q--C(R.sup.2)(R.sup.3)-- is a timing or linking group which undergoes electron migration along a conjugated system to cause a cleavage reaction; TIME is a timing or linking group; n is 0, 1, 2 or 3, preferably 0 or 1; PAM is a photographically active moiety; and R.sup.2 and R.sup.3 are independently hydrogen, susbtituted or unsubstituted alkyl, aryl, heteroaryl, alkenyl, or alkynyl groups, can be combined with R.sup.1 to form a ring, or can combine together to form a ring, with the proviso R.sup.2 and R.sup.3 cannot together form a double bond with another atom and neither R.sup.2 nor R.sup.3 can be selected from RO--, RS--, R.sub.2 N--, or RSe-- where R represents any substituent. Photographic elements comprising the novel blocked image-modifying compounds of the present invention provide for the opportunity to specifically control the strength and location of image modification. They are also useful when incorporated in oligomeric or other polymeric species. Further, when such compounds unblock to fonn development inhibitors, excellent control of push processing, control of fog development, and control of specific layer developability can be obtained. These three applications can be realized by controlling the release rates. To control push processing, steady release upon extended processing is desirable; for control of fog development, gradual release during keeping is desirable; and for control of specific layer developability, rapid release upon processing is desirable.
摘要翻译： 提供了含有下列化学式的化合物的摄影元件：R1-NH-（Q）m-C（R2）（R3） - （TIME）n-PAM其中：R1是吸电子部分; Q是包含共轭体系的基团; m为0或1，当m = 1时，-NH-Q-C（R2）（R3） - 是沿着共轭体系发生电子迁移以引起裂解反应的定时或连接基团; TIME是一个时间或连接组; n为0,1,2或3，优选0或1; PAM是摄影活性部分; 并且R2和R3独立地是氢，取代或未取代的烷基，芳基，杂芳基，烯基或炔基可与R 1结合形成环，或者可以结合在一起形成环，条件是R 2和R 3不能一起 与另一个原子形成双键，R2和R3都不能选自RO-，RS-，R2N-或RSe-，其中R表示任何取代基。 包含本发明的新型阻塞图像修饰化合物的照相元件提供了专门控制图像修饰的强度和位置的机会。 当掺入低聚物或其他聚合物种时，它们也是有用的。 此外，当这些化合物阻断开发抑制剂时，可以获得优异的推压加工控制，雾化发展的控制和特定层显影性的控制。 这三个应用可以通过控制释放速率来实现。 为了控制推动处理，期望在延长处理时稳定地释放; 为了控制雾的发展，保持逐渐释放是可取的; 并且为了控制特定层显影性，期望在加工时快速释放。
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公开(公告)号：US4698915A
公开(公告)日：1987-10-13
申请号：US892608
申请日：1986-08-04
申请人： David A. Dickinson
发明人： David A. Dickinson
CPC分类号： B23K1/015
摘要： A technique for condensation soldering of articles (29) in a facility (40 or 80) having a vapor chamber (42) and a pair of aligned input (102) and exit (104) throats. An article (29) to be soldered is transported sequentially through the input channel (56), the vapor chamber (42) and the output channel (58). Simultaneously, air is moved, in a controlled manner, into and through a portion of the exit channel, in a direction opposite to the movement of the article and withdrawn from the input channel. The air exiting the input channel is processed to recover the expensive vapor entrained therein.
摘要翻译： 一种用于在具有蒸气室（42）和一对排列输入（102）和出口（104）喉部的设备（40或80）中冷凝焊接物品（29）的技术。 待焊接的物品（29）依次通过输入通道（56），蒸气室（42）和输出通道（58）输送。 同时，空气以受控的方式在与制品的运动相反的方向上移动并穿过出口通道的一部分，并从输入通道退出。 处理输入通道的空气被处理以回收夹带在其中的昂贵的蒸气。
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