公开(公告)号：US07015365B2

公开(公告)日：2006-03-21

申请号：US10742474

申请日：2003-12-19

申请人： Debjani Kapila ,  Ramesh Krishnamurti ,  Jan-Pleun Lens ,  Gurram Kishan ,  Nileshkumar Kukalyekar ,  Jegadeesh Thampi ,  Umesh Krishna Hasyagar ,  Vinod Kumar Rai ,  Ashok S. Shyadligeri ,  Radhakrishna Sreenivasarao Arakali ,  Edward J. Nesakumar ,  Pramod Kumbhar

发明人： Debjani Kapila ,  Ramesh Krishnamurti ,  Jan-Pleun Lens ,  Gurram Kishan ,  Nileshkumar Kukalyekar ,  Jegadeesh Thampi ,  Umesh Krishna Hasyagar ,  Vinod Kumar Rai ,  Ashok S. Shyadligeri ,  Radhakrishna Sreenivasarao Arakali ,  Edward J. Nesakumar ,  Pramod Kumbhar

IPC分类号： C07C39/17

CPC分类号： C07C37/20 ,  C07C2601/14 ,  C07C2603/68 ,  C07C39/17

摘要： A process for forming a cycloalkylidene bisphenol comprises: reacting a cycloalkanone compound of formula: where [A] is a substituted or an unsubstituted aromatic group, R1–R4 independently represent a hydrogen or a C1–C12 hydrocarbyl group; and “a” and “b” are integers independently having values from 0–3; with an aromatic hydroxy compound of formula [A]-OH, where [A] is as previously described; at a mole ratio of greater than or equal to about 20, in the presence of a sulfonic acid type ion exchange resin catalyst crosslinked with greater than or equal to about 8 weight percent of divinylbenzene, and a promoter selected from the group consisting of a mercaptan compound and a resorcinol compound; to form a cycloalkylidene bisphenol of formula: where [A], R1–R4, “a” and “b” are as previously described. Moreover, any acid catalyst can be used with a resorcinol promoter.

摘要翻译： 形成环亚烷基双酚的方法包括：使下式的环烷酮化合物反应：其中[A]是取代或未取代的芳基，R 1〜R 4独立地表示 氢或C 1 -C 12烃基; “a”和“b”是独立地为0-3的数值的整数; 与式[A] -OH的芳族羟基化合物反应，其中[A]如前所述; 在大于或等于约8重量％的二乙烯基苯交联的磺酸型离子交换树脂催化剂存在下，摩尔比大于或等于约20，以及选自硫醇的助催化剂 化合物和间苯二酚化合物; 形成下式的亚环烷基双酚：其中[A]，R 1 -R 4，“a”和“b”如前所述。 此外，任何酸催化剂都可以与间苯二酚助催化剂一起使用。