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公开(公告)号：US06982354B2
公开(公告)日：2006-01-03
申请号：US10770001
申请日：2004-02-02
IPC分类号： C07C45/38
CPC分类号： C07C45/002 , C07C2602/42 , C07C2603/68 , C07C2603/72 , C07C2603/86 , C07C49/433 , C07C49/453 , C07C49/423
摘要： A method of preparing a polycyclic compound containing a ketone functionality comprising: reacting a mixture comprising a catalyst, a reactant compound and an amount of water greater than or equal to 3 weight percent (wt %) based on the weight of the reactant compound; wherein said catalyst comprises nickel and base and said reactant compound comprises at least two fused rings, A and B wherein ring A is a saturated ring or ring system having 5 to 7 cyclic carbons and substituted with a hydroxyl functionality and ring B is a non-aromatic unsaturated ring having 5 to 6 cyclic carbons; and converting the hydroxyl functionality of ring A to a ketone functionality and non-aromatic unsaturated ring B to a saturated ring.
摘要翻译： 一种制备含有酮官能团的多环化合物的方法，包括：使包含催化剂，反应物化合物和大于或等于3重量％（wt％）的水的混合物与反应物化合物的重量反应; 其中所述催化剂包含镍和碱，并且所述反应物化合物包含至少两个稠合环A和B，其中环A是具有5-7个环状碳并被羟基官能团取代的饱和环或环系统，并且环B是非 - 具有5至6个环状碳的芳族不饱和环; 并将环A的羟基官能团转化为酮官能团和非芳族不饱和环B至饱和环。
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公开(公告)号：US07148386B2
公开(公告)日：2006-12-12
申请号：US10903149
申请日：2004-07-30
摘要： A process for the preparation of hydroquinone compounds comprising, reacting an aromatic hydroxy compound with an oxidizing agent in a biphasic solvent system. The reaction is carried out in the presence of a transition metal hydroxy phosphate catalyst to produce the corresponding hydroquinone compound.
摘要翻译： 一种制备氢醌化合物的方法，包括在双相溶剂体系中使芳族羟基化合物与氧化剂反应。 反应在过渡金属羟基磷酸盐催化剂存在下进行，生成相应的氢醌化合物。
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公开(公告)号：US20050171386A1
公开(公告)日：2005-08-04
申请号：US10770001
申请日：2004-02-02
申请人： Jegadeesh Thampi , Umesh Hasyagar , Anju Shukla , Pramod Kumbhar
发明人： Jegadeesh Thampi , Umesh Hasyagar , Anju Shukla , Pramod Kumbhar
IPC分类号： C07C45/00 , C07C49/423 , C07C49/453 , C08G63/64 , C07C45/29
CPC分类号： C07C45/002 , C07C2602/42 , C07C2603/68 , C07C2603/72 , C07C2603/86 , C07C49/433 , C07C49/453 , C07C49/423
摘要： A method of preparing a polycyclic compound containing a ketone functionality comprising: reacting a mixture comprising a catalyst, a reactant compound and an amount of water greater than or equal to 3 weight percent (wt %) based on the weight of the reactant compound; wherein said catalyst comprises nickel and base and said reactant compound comprises at least two fused rings, A and B wherein ring A is a saturated ring or ring system having 5 to 7 cyclic carbons and substituted with a hydroxyl functionality and ring B is a non-aromatic unsaturated ring having 5 to 6 cyclic carbons; and converting the hydroxyl functionality of ring A to a ketone functionality and non-aromatic unsaturated ring B to a saturated ring.
摘要翻译： 一种制备含有酮官能团的多环化合物的方法，包括：使包含催化剂，反应物化合物和大于或等于3重量％（wt％）的水的混合物与反应物化合物的重量反应; 其中所述催化剂包含镍和碱，并且所述反应物化合物包含至少两个稠合环A和B，其中环A是具有5-7个环状碳并被羟基官能团取代的饱和环或环系统，并且环B是非 - 具有5至6个环状碳的芳族不饱和环; 并将环A的羟基官能团转化为酮官能团和非芳族不饱和环B至饱和环。
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公开(公告)号：US20050137380A1
公开(公告)日：2005-06-23
申请号：US10757921
申请日：2004-01-14
IPC分类号： B01J27/122 , C07C37/07 , C07C39/08 , C07C46/08 , C08G64/04 , C08G64/00 , C07C37/06 , C07C50/04
摘要： A process for the preparation of benzoquinones and hydroquinones includes oxidizing an aromatic hydroxy compound with oxygen or an oxygen containing gas, a copper containing catalyst, and a promoter to form the benzoquonone. A reduction reaction is employed to form the hydroquinone.
摘要翻译： 制备苯醌和氢醌的方法包括用氧或含氧气体氧化芳族羟基化合物，含铜催化剂和助催化剂以形成苯醌。 采用还原反应形成氢醌。
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公开(公告)号：US07015365B2
公开(公告)日：2006-03-21
申请号：US10742474
申请日：2003-12-19
申请人： Debjani Kapila , Ramesh Krishnamurti , Jan-Pleun Lens , Gurram Kishan , Nileshkumar Kukalyekar , Jegadeesh Thampi , Umesh Krishna Hasyagar , Vinod Kumar Rai , Ashok S. Shyadligeri , Radhakrishna Sreenivasarao Arakali , Edward J. Nesakumar , Pramod Kumbhar
发明人： Debjani Kapila , Ramesh Krishnamurti , Jan-Pleun Lens , Gurram Kishan , Nileshkumar Kukalyekar , Jegadeesh Thampi , Umesh Krishna Hasyagar , Vinod Kumar Rai , Ashok S. Shyadligeri , Radhakrishna Sreenivasarao Arakali , Edward J. Nesakumar , Pramod Kumbhar
IPC分类号： C07C39/17
CPC分类号： C07C37/20 , C07C2601/14 , C07C2603/68 , C07C39/17
摘要： A process for forming a cycloalkylidene bisphenol comprises: reacting a cycloalkanone compound of formula: where [A] is a substituted or an unsubstituted aromatic group, R1–R4 independently represent a hydrogen or a C1–C12 hydrocarbyl group; and “a” and “b” are integers independently having values from 0–3; with an aromatic hydroxy compound of formula [A]-OH, where [A] is as previously described; at a mole ratio of greater than or equal to about 20, in the presence of a sulfonic acid type ion exchange resin catalyst crosslinked with greater than or equal to about 8 weight percent of divinylbenzene, and a promoter selected from the group consisting of a mercaptan compound and a resorcinol compound; to form a cycloalkylidene bisphenol of formula: where [A], R1–R4, “a” and “b” are as previously described. Moreover, any acid catalyst can be used with a resorcinol promoter.
摘要翻译： 形成环亚烷基双酚的方法包括：使下式的环烷酮化合物反应：其中[A]是取代或未取代的芳基，R 1〜R 4独立地表示 氢或C 1 -C 12烃基; “a”和“b”是独立地为0-3的数值的整数; 与式[A] -OH的芳族羟基化合物反应，其中[A]如前所述; 在大于或等于约8重量％的二乙烯基苯交联的磺酸型离子交换树脂催化剂存在下，摩尔比大于或等于约20，以及选自硫醇的助催化剂 化合物和间苯二酚化合物; 形成下式的亚环烷基双酚：其中[A]，R 1 -R 4，“a”和“b”如前所述。 此外，任何酸催化剂都可以与间苯二酚助催化剂一起使用。
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公开(公告)号：US20050222372A1
公开(公告)日：2005-10-06
申请号：US10815879
申请日：2004-03-31
IPC分类号： B01J21/10 , B01J23/72 , B01J27/232 , B01J35/10 , B01J37/00 , C07C37/14 , C07C37/16 , C07C39/08 , C08G65/38
CPC分类号： C07C37/14 , B01J21/10 , B01J23/72 , B01J27/232 , B01J35/1061 , B01J37/0018 , C07C37/16 , C07C39/08
摘要： A continuous process comprising: contacting a mixture comprising dihydroxy aromatic compound, water and an alkylating agent with a catalyst system in the presence of a flowing carrier gas, to form a mono alkylated dihydroxy aromatic compound, wherein the catalyst system is obtained by the calcination of a catalyst precursor system comprising a metal oxide precursor, a transition metal element and a pore former.
摘要翻译： 一种连续方法，包括：在流动的载气存在下使包含二羟基芳族化合物，水和烷基化剂的混合物与催化剂体系接触，形成单烷基化二羟基芳族化合物，其中催化剂体系是通过煅烧 包含金属氧化物前体，过渡金属元素和成孔剂的催化剂前体体系。
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公开(公告)号：US20050209431A1
公开(公告)日：2005-09-22
申请号：US11132507
申请日：2005-05-19
申请人： Jegadeesh Thampi , Umesh Hasyagar , Anju Shukla , Pramod Kumbhar
发明人： Jegadeesh Thampi , Umesh Hasyagar , Anju Shukla , Pramod Kumbhar
IPC分类号： C07C45/00 , C07C49/423 , C07C49/453 , C08G63/64 , C08G8/02
CPC分类号： C07C45/002 , C07C2602/42 , C07C2603/68 , C07C2603/72 , C07C2603/86 , C07C49/433 , C07C49/453 , C07C49/423
摘要： A polycarbonate comprises structural units derived from a compound comprising a ketone functionality and at least two fused rings, A and B wherein ring A is a saturated ring or ring system having 5 to 7 cyclic carbons and substituted with a ketone functionality and ring B is a saturated ring having 5 to 6 cyclic carbons
摘要翻译： 聚碳酸酯包含衍生自包括酮官能团和至少两个稠合环的化合物的结构单元A和B，其中A环是具有5至7个环状碳并被酮官能团取代的饱和环或环系统，并且环B是 具有5〜6个环状碳原子的饱和环
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8.发明授权公开(公告)号：US07154010B2
公开(公告)日：2006-12-26
申请号：US10250107
申请日：2003-06-04
申请人： Pramod Shankar Kumbhar , Jegadeesh Thampi , Bharat Singh , John W. Fulmer , Prashant Anil Tatake
发明人： Pramod Shankar Kumbhar , Jegadeesh Thampi , Bharat Singh , John W. Fulmer , Prashant Anil Tatake
IPC分类号： C07C36/16
CPC分类号： C07C37/20 , C07C37/08 , C07C45/53 , Y02P20/125 , Y02P20/52 , C07C39/04 , C07C39/16 , C07C49/08
摘要： Use of a specific combination of catalysts for the first and second steps of the process for the conversion of CHP to BPA provides high yields of BPA and low impurity yields, without a requirement for the intermediate purification steps. In the first step, CHP is cleaved in the presence of a sulfated metal oxide catalyst such as sulfated Zirconia to produce phenol and acetone. In the second step, the phenol and acetone produced is reacted, preferably without intermediate purification, in the presence of a cation exchange resin catalyst that includes a cation exchange resin and a mercaptan or mercaptoalkanoic acid promoter to produce BPA.
摘要翻译： 用于将CHP转化为BPA的方法的第一和第二步骤的特定的催化剂组合的使用提供了高产率的BPA和低杂质产率，而不需要中间纯化步骤。 在第一步中，CHP在硫酸化金属氧化物催化剂如硫酸化氧化锆存在下裂解，生成苯酚和丙酮。 在第二步中，所生产的苯酚和丙酮优选不经中间纯化，在包含阳离子交换树脂和硫醇或巯基链烷酸促进剂以产生BPA的阳离子交换树脂催化剂的存在下反应。
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公开(公告)号：US07087705B2
公开(公告)日：2006-08-08
申请号：US10815879
申请日：2004-03-31
IPC分类号： C08G65/38
CPC分类号： C07C37/14 , B01J21/10 , B01J23/72 , B01J27/232 , B01J35/1061 , B01J37/0018 , C07C37/16 , C07C39/08
摘要： A continuous process comprising: contacting a mixture comprising dihydroxy aromatic compound, water and an alkylating agent with a catalyst system in the presence of a flowing carrier gas, to form a mono alkylated dihydroxy aromatic compound, wherein the catalyst system is obtained by the calcination of a catalyst precursor system comprising a metal oxide precursor, a transition metal element and a pore former.
摘要翻译： 一种连续方法，包括：在流动的载气存在下使包含二羟基芳族化合物，水和烷基化剂的混合物与催化剂体系接触，形成单烷基化二羟基芳族化合物，其中催化剂体系是通过煅烧 包含金属氧化物前体，过渡金属元素和成孔剂的催化剂前体体系。
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公开(公告)号：US20060025634A1
公开(公告)日：2006-02-02
申请号：US10903149
申请日：2004-07-30
IPC分类号： C07C37/60
摘要： A process for the preparation of hydroquinone compounds comprising, reacting an aromatic hydroxy compound with an oxidizing agent in a biphasic solvent system. The reaction is carried out in the presence of a transition metal hydroxy phosphate catalyst to produce the corresponding hydroquinone compound.
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