公开(公告)号：US07651547B2

公开(公告)日：2010-01-26

申请号：US10540376

申请日：2003-12-10

申请人： Dirk Nuber ,  Michael Ströder ,  Werner Stockhausen ,  Ali-Naghi Beyzavi ,  Lothar Formanek ,  Martin Hirsch

发明人： Dirk Nuber ,  Michael Ströder ,  Werner Stockhausen ,  Ali-Naghi Beyzavi ,  Lothar Formanek ,  Martin Hirsch

IPC分类号： B01J8/24 ,  C22B1/10 ,  C22B5/14

CPC分类号： B01J8/1818 ,  B01J8/1836 ,  B01J8/26 ,  B01J2208/00548 ,  B01J2208/00725 ,  C21B13/0033 ,  C22B1/10 ,  C22B5/14 ,  C22B34/1204 ,  C22B34/1209 ,  F27B15/02 ,  F27B15/10 ,  Y02P10/136

摘要： The present invention relates to a method and a plant for the heat treatment of solids containing titanium and possibly further metal oxides, in which fine-grained solids are heated to a temperature of 700 to 950° C. in a fluidized bed reactor (1). To improve the energy utilization, it is proposed to introduce a first gas or gas mixture from below through a gas supply tube (3) into a mixing chamber (7) of the reactor (1), the gas supply tube (3) being at least partly surrounded by a stationary annular fluidized bed (10) which is fluidized by supplying fluidizing gas. The gas velocities of the first gas or gas mixture as well as of the fluidizing gas for the annular fluidized bed (10) are adjusted such that the particle Froude numbers in the gas supply tube (3) are between 1 and 100, in the annular fluidized bed (10) between 0.02 and 2 and in the mixing chamber (7) between 0.3 and 30.

摘要翻译： 本发明涉及用于热处理包含钛和可能的其它金属氧化物的固体的方法和设备，其中在流化床反应器（1）中将细粒固体加热至700-950℃， 。 为了提高能量利用率，建议从下方通过气体供给管（3）将第一气体或气体混合物引入反应器（1）的混合室（7），气体供给管（3）处于 最少部分地被固定的环形流化床（10）包围，所述静止环形流化床通过供应流化气体而流化。 调节第一气体或气体混合物以及用于环形流化床（10）的流化气体的气体速度，使得气体供应管（3）中的微粒弗劳德数在1和100之间，在环形 流化床（10）在0.02和2之间，并且在混合室（7）中在0.3和30之间。

公开(公告)号：US07854608B2

公开(公告)日：2010-12-21

申请号：US10540436

申请日：2003-12-10

申请人： Dirk Nuber ,  Werner Stockhausen ,  Michael Ströder

发明人： Dirk Nuber ,  Werner Stockhausen ,  Michael Ströder

IPC分类号： B01J8/24 ,  C22B1/10 ,  C22B5/14

CPC分类号： B01J8/1836 ,  B01J8/0055 ,  B01J8/1863 ,  B01J2208/00141 ,  B01J2208/0053 ,  B01J2208/00548 ,  B01J2208/00654 ,  B01J2219/00006 ,  C04B11/0283 ,  F27B15/02 ,  F27B15/10 ,  F27B15/16

摘要： The present invention relates to a method for the heat treatment of fine-grained solids, in particular gypsum, in which the solids are heated to a temperature of 50 to 1000° C. in a fluidized bed reactor (1), and to a corresponding plant. To improve the energy utilization, it is proposed to introduce a first gas or gas mixture from below through a preferably central gas supply tube (3) into a mixing chamber (21) of the reactor (1), the gas supply tube (3) being at least partly surrounded by a stationary annular fluidized bed (2) which is fluidized by supplying fluidizing gas, and to adjust the gas velocities of the first gas or gas mixture as well as of the fluidizing gas for the annular fluidized bed (2) such that the particle Froude numbers in the gas supply tube (3) are between 1 and 100, in the annular fluidized bed (2) between 0.02 and 2 and in the mixing chamber (21) between 0.3 and 30.

摘要翻译： 本发明涉及一种用于热处理细粒固体，特别是石膏的方法，其中将固体在流化床反应器（1）中加热至50至1000℃的温度，以及相应的 厂。 为了提高能量利用率，建议从下方通过优选的中心气体供给管（3）将第一气体或气体混合物引入反应器（1）的混合室（21），气体供给管（3） 至少部分地被固定的环形流化床（2）包围，所述静止环形流化床（2）通过供应流化气体而流化，并且调节第一气体或气体混合物以及用于环形流化床（2）的流化气体的气体速度， 使得气体供给管（3）中的微粒Froude数在1和100之间，在0.02和2之间的环形流化床（2）和在0.3和30之间的混合室（21）中。

公开(公告)号：US20100074805A1

公开(公告)日：2010-03-25

申请号：US12628479

申请日：2009-12-01

申请人： Dirk Nuber ,  Michael Stroeder ,  Werner Stockhausen ,  Ali-Naghi Beyzavi ,  Lothar Formanek ,  Martin Hirsch

发明人： Dirk Nuber ,  Michael Stroeder ,  Werner Stockhausen ,  Ali-Naghi Beyzavi ,  Lothar Formanek ,  Martin Hirsch

IPC分类号： B01J8/24

CPC分类号： B01J8/1818 ,  B01J8/1836 ,  B01J8/26 ,  B01J2208/00548 ,  B01J2208/00725 ,  C21B13/0033 ,  C22B1/10 ,  C22B5/14 ,  C22B34/1204 ,  C22B34/1209 ,  F27B15/02 ,  F27B15/10 ,  Y02P10/136

摘要： A plant for the heat treatment of solids containing titanium includes a fluidized bed reactor. The reactor includes at least one gas supply tube being at least partly surrounded by an annular chamber in which a stationary annular fluidized bed is located, and a mixing chamber being located above the upper orifice region of the gas supply tube. The gas flowing through the gas supply tube entrains solids from the stationary annular fluidized bed into the mixing chamber when passing through the upper orifice region of the gas supply system. The plant further includes a solids separator downstream of the reactor. The solids separator includes a solids conduit leading to the annular fluidized bed of the reactor.

摘要翻译： 用于热处理含钛固体的设备包括流化床反应器。 反应器包括至少一个气体供应管，其至少部分地被环形室围绕，其中定位有固定环形流化床，并且混合室位于气体供应管的上孔区域上方。 流过气体供应管的气体在通过气体供应系统的上部孔口区域时将固体从固定的环形流化床引入混合室。 该设备还包括在反应器下游的固体分离器。 固体分离器包括通向反应器的环形流化床的固体导管。

公开(公告)号：US20060162500A1

公开(公告)日：2006-07-27

申请号：US10540376

申请日：2003-12-10

申请人： Dirk Nuber ,  Michael Stroder ,  Werner Stockhausen ,  Ali-Naghi Beyzavi ,  Lothar Formanek ,  Martin Hirsch

发明人： Dirk Nuber ,  Michael Stroder ,  Werner Stockhausen ,  Ali-Naghi Beyzavi ,  Lothar Formanek ,  Martin Hirsch

IPC分类号： C22B34/12

CPC分类号： B01J8/1818 ,  B01J8/1836 ,  B01J8/26 ,  B01J2208/00548 ,  B01J2208/00725 ,  C21B13/0033 ,  C22B1/10 ,  C22B5/14 ,  C22B34/1204 ,  C22B34/1209 ,  F27B15/02 ,  F27B15/10 ,  Y02P10/136

摘要： The present invention relates to a method and a plant for the heat treatment of solids containing titanium and possibly further metal oxides, in which fine-grained solids are heated to a temperature of 700 to 950° C. in a fluidized bed reactor (1). To improve the energy utilization, it is proposed to introduce a first gas or gas mixture from below through a gas supply tube (3) into a mixing chamber (7) of the reactor (1), the gas supply tube (3) being at least partly surrounded by a stationary annular fluidized bed (10) which is fluidized by supplying fluidizing gas. The gas velocities of the first gas or gas mixture as well as of the fluidizing gas for the annular fluidized bed (10) are adjusted such that the particle Froude numbers in the gas supply tube (3) are between 1 and 100, in the annular fluidized bed (10) between 0.02 and 2 and in the mixing chamber (7) between 0.3 and 30.

摘要翻译： 本发明涉及用于热处理包含钛和可能的其它金属氧化物的固体的方法和设备，其中在流化床反应器（1）中将细粒固体加热至700-950℃， 。 为了提高能量利用率，建议从下方通过气体供给管（3）将第一气体或气体混合物引入反应器（1）的混合室（7），气体供给管（3）处于 最少部分地被固定的环形流化床（10）包围，所述静止环形流化床通过供应流化气体而被流化。 调节第一气体或气体混合物以及用于环形流化床（10）的流化气体的气体速度，使得气体供应管（3）中的微粒弗劳德数在1和100之间，在环形 流化床（10）在0.02和2之间，并且在混合室（7）中在0.3和30之间。

公开(公告)号：US08021601B2

公开(公告)日：2011-09-20

申请号：US12628479

申请日：2009-12-01

申请人： Dirk Nuber ,  Michael Stroeder ,  Werner Stockhausen ,  Lothar Formanek ,  Martin Hirsch ,  Ali-Naghi Beyzavi

发明人： Dirk Nuber ,  Michael Stroeder ,  Werner Stockhausen ,  Lothar Formanek ,  Martin Hirsch ,  Ali-Naghi Beyzavi

IPC分类号： F27B15/02

CPC分类号： B01J8/1818 ,  B01J8/1836 ,  B01J8/26 ,  B01J2208/00548 ,  B01J2208/00725 ,  C21B13/0033 ,  C22B1/10 ,  C22B5/14 ,  C22B34/1204 ,  C22B34/1209 ,  F27B15/02 ,  F27B15/10 ,  Y02P10/136

摘要： A plant for the heat treatment of solids containing titanium includes a fluidized bed reactor. The reactor includes at least one gas supply tube being at least partly surrounded by an annular chamber in which a stationary annular fluidized bed is located, and a mixing chamber being located above the upper orifice region of the gas supply tube. The gas flowing through the gas supply tube entrains solids from the stationary annular fluidized bed into the mixing chamber when passing through the upper orifice region of the gas supply system. The plant further includes a solids separator downstream of the reactor. The solids separator includes a solids conduit leading to the annular fluidized bed of the reactor.

摘要翻译： 用于热处理含钛固体的设备包括流化床反应器。 反应器包括至少一个气体供应管，其至少部分地被环形室围绕，其中定位有固定环形流化床，并且混合室位于气体供应管的上孔区域上方。 流过气体供应管的气体在通过气体供应系统的上部孔口区域时将固体从固定的环形流化床引入混合室。 该设备还包括在反应器下游的固体分离器。 固体分离器包括通向反应器的环形流化床的固体导管。

公开(公告)号：US07662351B2

公开(公告)日：2010-02-16

申请号：US10540071

申请日：2003-12-13

申请人： Martin Hirsch ,  Werner Stockhausen ,  Michael Ströder

发明人： Martin Hirsch ,  Werner Stockhausen ,  Michael Ströder

IPC分类号： C01F1/00 ,  F27B15/00 ,  F27B15/12 ,  F27B15/18 ,  B22F1/00 ,  F27B15/08 ,  F27B15/14 ,  F27B15/16

CPC分类号： B01J8/384 ,  B01J8/0025 ,  B01J8/1827 ,  B01J8/1845 ,  B01J8/1863 ,  B01J8/1872 ,  C01B13/324 ,  C01F7/445 ,  F23C10/12 ,  F23C10/14 ,  Y02P20/129

摘要： The present invention relates to a process for producing metal oxide from metal compounds, in particular metal hydroxide or metal carbonate, in which the metal compound is conveyed into a reactor (25) with fluidized bed, heated there to a temperature of 650 15 to 1150° C. by combustion of fuel, and metal oxide is generated, as well as to a corresponding plant. To improve the utilization of energy, it is proposed to introduce a first gas or gas mixture from below through a gas supply tube (26) into a mixing chamber (20) of the reactor (25), the gas supply tube (26) being at least partly surrounded by a stationary annular fluidized bed (27) which is fluidized by supplying fluidizing gas, and 20 to adjust the gas velocities of the first gas or gas mixture and of the fluidizing gas for the annular fluidized bed (27) such that the Particle-Froude numbers in the gas supply tube (26) lie between 1 and 100, in the annular fluidized bed (27) between 0.02 and 2, and in the mixing chamber (20) between 0.3 and 30.

摘要翻译： 本发明涉及一种由金属化合物，特别是金属氢氧化物或金属碳酸盐生产金属氧化物的方法，其中金属化合物被输送到具有流化床的反应器（25）中，加热到650-1510℃的温度 通过燃料燃烧产生金属氧化物，以及生成相应的工厂。 为了提高能量的利用率，提出从下方将第一气体或气体混合物从气体供给管（26）引入反应器（25）的混合室（20），气体供给管（26）为 至少部分地由通过供应流化气体流化的固定环形流化床（27）和20来调节第一气体或气体混合物和用于环形流化床（27）的流化气体的气体速度，使得 在环形流化床（27）为0.02和2之间，以及在混合室（20）中，0.3至30之间，气体供应管（26）中的粒子 - 弗劳德数位于1和100之间。

公开(公告)号：US08048380B2

公开(公告)日：2011-11-01

申请号：US12501022

申请日：2009-07-10

申请人： Martin Hirsch ,  Werner Stockhausen ,  Michael Stroeder

发明人： Martin Hirsch ,  Werner Stockhausen ,  Michael Stroeder

IPC分类号： F27B15/08 ,  B01J8/18

CPC分类号： B01J8/384 ,  B01J8/0025 ,  B01J8/1827 ,  B01J8/1845 ,  B01J8/1863 ,  B01J8/1872 ,  C01B13/324 ,  C01F7/445 ,  F23C10/12 ,  F23C10/14 ,  Y02P20/129

摘要： A plant for producing metal oxide from metal compounds includes a fluidized-bed reactor in which the metal compounds are heated by a combustion of a fuel to produce metal oxide. The fluidized-bed-reactor reactor includes at least one gas supply tube at least partly surrounded by an annular chamber in which a stationary annular fluidized bed is disposed, and a mixing chamber disposed above an orifice region of the gas supply tube. A gas flowing through the gas supply tube entrains solids from the stationary annular fluidized bed when passing through the orifice region.

摘要翻译： 用于从金属化合物生产金属氧化物的设备包括流化床反应器，其中金属化合物被燃料燃烧而被加热以产生金属氧化物。 流化床反应器包括至少一个气体供应管，其至少部分地被设置有固定环形流化床的环形室环绕，以及设置在气体供应管的孔口区域上方的混合室。 流过气体供应管的气体在穿过孔口区域时夹带固体环形流化床的固体。

公开(公告)号：US20060263292A1

公开(公告)日：2006-11-23

申请号：US10540071

申请日：2003-12-13

申请人： Martin Hirsch ,  Werner Stockhausen ,  Michael Stroder

发明人： Martin Hirsch ,  Werner Stockhausen ,  Michael Stroder

IPC分类号： C01F7/02 ,  F27B15/00

CPC分类号： B01J8/384 ,  B01J8/0025 ,  B01J8/1827 ,  B01J8/1845 ,  B01J8/1863 ,  B01J8/1872 ,  C01B13/324 ,  C01F7/445 ,  F23C10/12 ,  F23C10/14 ,  Y02P20/129

摘要： The present invention relates to a process for producing metal oxide from metal compounds, in particular metal hydroxide or metal carbonate, in which the metal compound is conveyed into a reactor (25) with fluidized bed, heated there to a temperature of 650 15 to 1150° C. by combustion of fuel, and metal oxide is generated, as well as to a corre-sponding plant. To improve the utilization of energy, it is proposed to introduce a first gas or gas mixture from below through a gas supply tube (26) into a mixing chamber (20) of the reactor (25), the gas supply tube (26) being at least partly surrounded by a stationary annular fluidized bed (27) which is fluidized by supplying fluidizing gas, and 20 to adjust the gas velocities of the first gas or gas mixture and of the fluidizing gas for the annular fluidized bed (27) such that the Particle-Froude numbers in the gas supply tube (26) lie between 1 and 100, in the annular fluidized bed (27) between 0.02 and 2, and in the mixing chamber (20) between 0.3 and 30.

摘要翻译： 本发明涉及一种由金属化合物，特别是金属氢氧化物或金属碳酸盐生产金属氧化物的方法，其中金属化合物被输送到具有流化床的反应器（25）中，加热到650-1510℃的温度 通过燃料燃烧产生金属氧化物，以及相应的工厂。 为了提高能量的利用率，提出从下方将第一气体或气体混合物从气体供给管（26）引入反应器（25）的混合室（20），气体供给管（26）为 至少部分地由通过供应流化气体流化的固定环形流化床（27）和20来调节第一气体或气体混合物和用于环形流化床（27）的流化气体的气体速度，使得 在环形流化床（27）为0.02和2之间，以及在混合室（20）中，0.3至30之间，气体供应管（26）中的粒子 - 弗劳德数位于1和100之间。

公开(公告)号：US20090274589A1

公开(公告)日：2009-11-05

申请号：US12501022

申请日：2009-07-10

申请人： Martin Hirsch ,  Werner Stockhausen ,  Michael Stroeder

发明人： Martin Hirsch ,  Werner Stockhausen ,  Michael Stroeder

IPC分类号： F27B15/08 ,  F27B15/14 ,  F27B15/16

CPC分类号： B01J8/384 ,  B01J8/0025 ,  B01J8/1827 ,  B01J8/1845 ,  B01J8/1863 ,  B01J8/1872 ,  C01B13/324 ,  C01F7/445 ,  F23C10/12 ,  F23C10/14 ,  Y02P20/129

摘要： A plant for producing metal oxide from metal compounds includes a fluidized-bed reactor in which the metal compounds are heated by a combustion of a fuel to produce metal oxide. The fluidized-bed-reactor reactor includes at least one gas supply tube at least partly surrounded by an annular chamber in which a stationary annular fluidized bed is disposed, and a mixing chamber disposed above an orifice region of the gas supply tube. A gas flowing through the gas supply tube entrains solids from the stationary annular fluidized bed when passing through the orifice region.

摘要翻译： 用于从金属化合物生产金属氧化物的设备包括流化床反应器，其中金属化合物被燃料燃烧而被加热以产生金属氧化物。 流化床反应器包括至少一个气体供应管，其至少部分地被设置有固定环形流化床的环形室环绕，以及设置在气体供应管的孔口区域上方的混合室。 流过气体供应管的气体在穿过孔口区域时夹带固体环形流化床的固体。

公开(公告)号：US6015539A

公开(公告)日：2000-01-18

申请号：US68758

申请日：1998-09-03

申请人： Hans Werner Schmidt ,  Martin Rahn ,  Werner Stockhausen ,  Dietrich Werner ,  Martin Hirsch

发明人： Hans Werner Schmidt ,  Martin Rahn ,  Werner Stockhausen ,  Dietrich Werner ,  Martin Hirsch

IPC分类号： B01J8/18 ,  C01F7/44 ,  C01F7/02

CPC分类号： C01F7/445

摘要： A process is disclosed for preparing anhydrous alumina from aluminum hydroxide which comprises feeding aluminum hydroxide into a first suspension preheater and partially dehydrating the aluminum hydroxide with a hot exhaust gas, transporting the partially dehydrated aluminum hydroxide with said exhaust gas to a first separating means and separately withdrawing the exhaust gas and the partially dehydrated aluminum hydroxide, and dividing the partially dehydrated aluminum hydroxide into a first and second partial stream of solids. The process uses a circulating fluidized bed comprising a fluidized bed reactor, a recycle separator connected to the upper portion of said fluidized bed reactor, and a return line for leading solids from said recycle separator to the lower portion of said fluidized bed reactor. The second partial stream of solids is fed into a second suspension preheater and contacted with hot exhaust gas from the recycle separator. The solids and the exhaust gas are transported to a second separating means and an exhaust gas stream is withdrawn and fed into the first suspension preheater. A dehydrated solids stream is fed into the fluidized bed reactor and the reactor temperature is adjusted to 850 to 1000.degree. C. A third partial stream of solids is mixed with the first partial stream of solids to form a hot solids mixture. The hot solids mixture is cooled in at least one fluidized bed cooler and then is fed into the fluidized bed reactor. The hot solids mixture is cooled in at least one fluidized bed cooler.

摘要翻译： PCT No.PCT / EP96 / 04764 Sec。 371日期：1998年9月3日 102（e）1998年9月3日PCT PCT 1996年11月2日PCT公布。 公开号WO97 / 18165 日期1997年5月22日公开了一种从氢氧化铝制备无水氧化铝的方法，其包括将氢氧化铝进料到第一悬浮预热器中，并用热废气部分使氢氧化铝脱水，将部分脱水的氢氧化铝与所述排气一起输送到第一 分离装置，分别排出废气和部分脱水的氢氧化铝，将部分脱水的氢氧化铝分成第一和第二部分固体物流。 该方法使用循环流化床，其包括流化床反应器，连接到所述流化床反应器的上部的循环分离器和用于将固体从所述再循环分离器引导到所述流化床反应器的下部的返回管线。 将第二部分固体物流进入第二悬浮预热器并与来自再循环分离器的热废气接触。 固体和废气被输送到第二分离装置，废气流被排出并进入第一悬浮预热器。 将脱水的固体物流进料到流化床反应器中，并将反应器温度调节至850至1000℃。固体的第三部分流与第一部分固体物流混合以形成热固体混合物。 将热固体混合物在至少一个流化床冷却器中冷却，然后进料到流化床反应器中。 热固体混合物在至少一个流化床冷却器中冷却。