公开(公告)号：US07795357B2

公开(公告)日：2010-09-14

申请号：US10570643

申请日：2004-09-03

申请人： Dirk Zierer ,  Klaus Kurz ,  Jens Schiebisch ,  Karl-Friedrich Mück ,  Holger Schmalz

发明人： Dirk Zierer ,  Klaus Kurz ,  Jens Schiebisch ,  Karl-Friedrich Mück ,  Holger Schmalz

IPC分类号： C08L59/00 ,  C08L59/04 ,  C08G2/38

CPC分类号： C08G81/00 ,  C08G2/32 ,  C08L59/00 ,  C08L71/02 ,  C08L2666/16

摘要： Multiblock copolymers are described and contain the structural unit of formula I -A-O—R1—O—CO—(R2—CO—)m—X-D-X—(CO—R2)m—CO—X—  (I), where A is a radical derived from a homo- or copolyoxymethylene, R1 is an alkylene radical-having at least two carbon atoms or a cycloalkylene radical, R2 is a direct carbon-carbon bond, or an alkylene, cycloalkylene, arylene, or aralkylene radical, X is selected from —O—, —S—, or —NH—, D is a divalent radical B which is a radical of a hydroxy-terminated, mercaptan-terminated, or amino-terminated polymer which derives from polyalkylene glycols, polyvinyl ethers, polyvinyl ether-alkene copolymers, polyvinyl esters, polyvinyl ester-alkene copolymers, polyvinyl alcohols, polyvinyl alcohol-alkene copolymers, polyvinylaromatics, polyacrylates, polymethacrylates, polyacetals, polycarbonates, polyesters, polyamides, polyimines, polyetherester elastomers, polyetheramide elastomers, polyalkadienes, polyurethanes, polyureas, polysiloxanes, or a triblock copolymer radical -PAO-B-PAO-, where B assumes one of the above meanings and PAO is a polyalkylene oxide radical, and m is 0 or 1. The multiblock copolymers may be used to produce moldings.

摘要翻译： 描述了多嵌段共聚物并含有式I-A-O-R 1 -O-CO-（R 2 -CO-）m -XDX-（CO-R 2）m -CO-X-I（I）的结构单元，其中A为 衍生自均聚或共聚甲醛的基团，R 1是具有至少两个碳原子的亚烷基或亚环烷基，R 2是直接碳 - 碳键或亚烷基，亚环烷基，亚芳基或亚芳基，选择X 由-O - ， - S-或-NH-取代，D是二价基团B，其是由聚亚烷基二醇衍生的羟基封端的，硫醇封端的或氨基封端的聚合物的基团，聚乙烯醚，聚乙烯醚 聚烯烃共聚物，聚乙烯基酯，聚乙烯基酯 - 烯烃共聚物，聚乙烯醇，聚乙烯醇 - 烯烃共聚物，聚乙烯芳烃，聚丙烯酸酯，聚甲基丙烯酸酯，聚缩醛，聚碳酸酯，聚酯，聚酰胺，聚亚胺，聚醚酯弹性体，聚醚酰胺弹性体，聚链烯二烯，聚氨酯，聚脲， 宝 溶解硅氧烷或三嵌段共聚物基团-PAO-B-PAO-，其中B为上述含义之一，而PAO为聚环氧烷基，m为0或1.多嵌段共聚物可用于制备模制品。

公开(公告)号：US20060160938A1

公开(公告)日：2006-07-20

申请号：US10570643

申请日：2004-09-03

申请人： Dirk Zierer ,  Klaus Kurz ,  Jens Schiebisch ,  Karl-Friedrich Muck ,  Holger Schmalz

发明人： Dirk Zierer ,  Klaus Kurz ,  Jens Schiebisch ,  Karl-Friedrich Muck ,  Holger Schmalz

IPC分类号： C08K5/09

CPC分类号： C08G81/00 ,  C08G2/32 ,  C08L59/00 ,  C08L71/02 ,  C08L2666/16

摘要： Multiblock copolymers are described and contain the structural unit of formula I -A-O—R1—O—CO—(R2—CO—)m—X-D-X—(CO—R2)m—CO—X—  (I), where A is a radical derived from a homo- or copolyoxymethylene, R1 is an alkylene radical having at least two carbon atoms, or a cycloalkylene radical, R2 is a direct carbon-carbon bond, or an alkylene, cycloalkylene, arylene, or aralkylene radical, X is selected from —O—, —S—, or —NH—, D is a divalent radical B which is a radical of a hydroxy-terminated, mercaptan-terminated, or amino-terminated polymer which derives from polyalkylene glycols, from polyvinyl ethers, from polyvinyl ether copolymers with alkenes, from polyvinyl esters, from polyvinyl ester copolymers with alkenes, from polyvinyl alcohols, or from polyvinyl alcohol-alkene copolymers, from polyvinylaromatics, from polyacrylates, from polymethacrylates, from polyacetals which have no, or up to 50 mol % of, oxymethylene units, from polycarbonates, from polyesters, from polyamides, from polyimines, from polyetherester elastomers (PEEs), from polyetheramide elastomers (PEAs), from polyalkadienes which may, where appropriate, have been hydrogenated, from polyurethanes, from polyureas, or from polysiloxanes, or is a hydroxy-terminated, mercaptan-terminated, or amino-terminated triblock copolymer radical -PAO-B-PAO-, where B assumes one of the above meanings and PAO is a polyalkylene oxide radical, and m is 0 or 1. The multiblock copolymers may be used to produce moldings.

摘要翻译： 多嵌段共聚物被描述并且包含式I的结构单元<？in-line-formula description =“In-line Formulas”end =“lead”？> - AOR 1 -O-CO-（ R 2 -CO-）m -X -X-（CO-R 2）m -CO-X- （I），<？in-line-formula description =“In-line Formulas”end =“tail”？>其中A是衍生自均聚或共聚甲醛的基团，R 1是 具有至少两个碳原子的亚烷基或亚环烷基，R 2是直接碳 - 碳键，或亚烷基，亚环烷基，亚芳基或亚芳基，X选自-O- ，-S-或-NH-，D是二价基团B，其是由聚亚烷基二醇衍生的羟基封端的，硫醇封端的或氨基封端的聚合物的基团，来自聚乙烯基醚，聚乙烯基醚共聚物与 来自聚乙烯基酯的烯烃，来自聚烯烃的聚乙烯酯共聚物，聚乙烯醇，或聚乙烯醇 - 烯烃共聚物，聚乙烯 聚丙烯酸酯，来自聚甲基丙烯酸酯的聚缩醛，来自聚甲醛，聚酯，聚酰胺，聚亚胺，聚醚酯弹性体（PEE），聚醚酰胺弹性体（PEAs），聚醚酯弹性体 来自聚适度地氢化的聚链烷二烯，聚氨酯，聚脲或聚硅氧烷，或是羟基封端的，硫醇封端的或氨基封端的三嵌段共聚物基团-PAO-B-PAO-，其中 B表示上述含义之一，PAO为聚环氧烷基，m为0或1.多嵌段共聚物可用于制备模制品。

公开(公告)号：US20070027300A1

公开(公告)日：2007-02-01

申请号：US10570585

申请日：2004-09-03

申请人： Dirk Zierer ,  Jens Schiebisch ,  Klaus Kurz

发明人： Dirk Zierer ,  Jens Schiebisch ,  Klaus Kurz

IPC分类号： C08G65/34

CPC分类号： C08G2/32 ,  C08L59/00 ,  Y10T428/31507

摘要： Homo- or copolyoxymethylenes are described and contain the repeat structural unit of formula I -A-O—R1—O—CO—(R2—CO—)m—O—  (I), where A is a radical derived from a homo- or copolyoxymethylene, R1 is an alkylene radical having at least two carbon atoms, or a cycloalkylene radical, R2 is a direct carbon-carbon bond, or an alkylene, cycloalkylene, arylene, or aralkylene radical, and m is 0 or 1. These polymers may be prepared by reacting end-group-functionalized homo- or copolyoxymethylenes with selected chain-linking agents. The reaction products can be used to produce moldings.

摘要翻译： 描述了均聚或共聚亚甲基，并且含有式I的重复结构单元<？in-line-formula description =“In-line Formulas”end =“lead”→AOR CO-（R 2 -CO-）m -O - （I），＆lt;？在线公式描述=“在线公式”end =“尾 “→”其中A是衍生自均聚或共聚甲醛的基团，R 1是具有至少两个碳原子的亚烷基，或亚环烷基，R 2， 是直接碳 - 碳键，或亚烷基，亚环烷基，亚芳基或芳亚烷基，m为0或1.这些聚合物可以通过端基官能化的均聚或共聚氧基亚甲基与选择的链连接剂反应来制备。 反应产物可用于生产模制品。

公开(公告)号：US07745548B2

公开(公告)日：2010-06-29

申请号：US10570585

申请日：2004-09-03

申请人： Dirk Zierer ,  Jens Schiebisch ,  Klaus Kurz

发明人： Dirk Zierer ,  Jens Schiebisch ,  Klaus Kurz

IPC分类号： C08L59/04 ,  C08G2/32 ,  C08G65/34

CPC分类号： C08G2/32 ,  C08L59/00 ,  Y10T428/31507

摘要： Homo- or copolyoxymethylenes are described and contain the repeat structural unit of formula I -A-O—R1—O—CO—(R2—CO—)m—O—  (I), where A is a radical derived from a homo- or copolyoxymethylene, R1 is an alkylene radical having at least two carbon atoms, or a cycloalkylene radical, R2 is a direct carbon-carbon bond, or an alkylene, cycloalkylene, arylene, or aralkylene radical, and m is 0 or 1. These polymers may be prepared by reacting end-group-functionalized homo- or copolyoxymethylenes with selected chain-linking agents.The reaction products can be used to produce moldings.

摘要翻译： 描述了同 - 或共聚亚甲基，并含有式I-A-R-O-R-O-（R 2 -CO-）m-O-（I）的重复结构单元，其中A是衍生自均聚或共聚甲醛 R1是具有至少两个碳原子的亚烷基或亚环烷基，R 2是直接碳 - 碳键，或亚烷基，亚环烷基，亚芳基或亚芳基，m是0或1.这些聚合物可以是 通过端基官能化的均聚或共聚氧基亚甲基与选择的链连接剂反应制备。 反应产物可用于生产模制品。

公开(公告)号：US07001959B2

公开(公告)日：2006-02-21

申请号：US10700195

申请日：2003-11-03

申请人： Karl-Friedrich Mück ,  Klaus Kurz ,  Michael Hoffmockel

发明人： Karl-Friedrich Mück ,  Klaus Kurz ,  Michael Hoffmockel

IPC分类号： C08G65/00

CPC分类号： C08G2/38

摘要： Copolymers are described containing blocks of the structural repeat units of the formula I and blocks containing structural units of the formula II [—O—CH2—]x,  (I) [—O—R1—],  (II) where R1 is a divalent radical derived from a hydroxy-terminated aliphatic or cycloaliphatic oligomer or polymer which, where appropriate, has ether groups and/or carbonyloxy groups in the chain, and x is a whole number, at least 10. The copolymers may be used for producing moldings.

摘要翻译： 描述了包含式I的结构重复单元的嵌段和含有结构单元的嵌段的共聚物

公开(公告)号：US20080182966A1

公开(公告)日：2008-07-31

申请号：US12058197

申请日：2008-03-28

申请人： Karl-Friedrich Mück ,  Klaus Kurz ,  Michael Hoffmockel

发明人： Karl-Friedrich Mück ,  Klaus Kurz ,  Michael Hoffmockel

IPC分类号： C08G65/34

CPC分类号： C08G2/38

摘要： Copolymers are described containing blocks of the structural repeat units of the formula I and blocks containing structural units of the formula II [—O—CH2—]x,   (I) [—O—R1—],   (II) where R1 is a divalent radical derived from a hydroxy-terminated aliphatic or cycloaliphatic oligomer or polymer which, where appropriate, has ether groups and/or carbonyloxy groups in the chain, and x is a whole number, at least 10.The copolymers may be used for producing moldings.

摘要翻译： 描述共聚物，其包含式I的结构重复单元的嵌段和含有式II的结构单元的嵌段<？in-line-formula description =“In-line Formulas”end =“lead”→[ - O-CH （I）<？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula- 公式描述=“在线公式”end =“lead”？> [ - OR ^{1 - ]，（II）<？in-line-formula description =“In-line Formulas”end = 其中R 1是衍生自羟基封端的脂族或脂环族低聚物或聚合物的二价基团，其在适当的情况下在链中具有醚基和/或羰氧基，x 是整数，至少为10.共聚物可用于生产模制品。}

公开(公告)号：US07410696B2

公开(公告)日：2008-08-12

申请号：US11328635

申请日：2006-01-10

申请人： Dirk Zierer ,  Rainer Bernstein ,  Jörg Schweitzer ,  Klaus Kurz

发明人： Dirk Zierer ,  Rainer Bernstein ,  Jörg Schweitzer ,  Klaus Kurz

IPC分类号： D02G3/00

CPC分类号： D01F6/78 ,  Y10T428/2913 ,  Y10T428/2967

摘要： Described are fibers comprising a polyoxymethylene copolymer having an ISO 1133 MVR melt index (determined at 190° C. under a load of 2.16 kg) in the range from 0.3 to 30 ml/10 min which possess a bend recovery (measured by the double loop method in air and/or water) of not less than 125° C. These fibers are useful in brushes.

摘要翻译： 描述的是包含具有ISO 1133 MVR熔体指数（在190℃，2.16kg负荷下测定）的聚甲醛共聚物的纤维，其范围为0.3至30ml / 10分钟，其具有弯曲恢复（通过双环测量 空气和/或水中的方法）不低于125℃。这些纤维在刷子中是有用的。

公开(公告)号：US20060154060A1

公开(公告)日：2006-07-13

申请号：US11328635

申请日：2006-01-10

申请人： Dirk Zierer ,  Rainer Bernstein ,  Jorg Schweitzer ,  Klaus Kurz

发明人： Dirk Zierer ,  Rainer Bernstein ,  Jorg Schweitzer ,  Klaus Kurz

IPC分类号： D02G3/00

CPC分类号： D01F6/78 ,  Y10T428/2913 ,  Y10T428/2967

摘要： Described are fibers comprising a polyoxymethylene copolymer having an ISO 1133 MVR melt index (determined at 190° C. under a load of 2.16 kg) in the range from 0.3 to 30 ml/10 min which possess a bend recovery (measured by the double loop method in air and/or water) of not less than 125°. These fibers are useful in brushes.

摘要翻译： 描述的是包含具有ISO 1133 MVR熔体指数（在190℃，2.16kg负荷下测定）的聚甲醛共聚物的纤维，其范围为0.3至30ml / 10分钟，其具有弯曲恢复（通过双环测量 空气和/或水中的方法）不小于125°。 这些纤维在刷子中是有用的。

公开(公告)号：US20060235119A1

公开(公告)日：2006-10-19

申请号：US11402687

申请日：2006-04-12

申请人： Holger Schmalz ,  Christine Kostler ,  Klaus Kurz

发明人： Holger Schmalz ,  Christine Kostler ,  Klaus Kurz

IPC分类号： C08G18/48

CPC分类号： C08G18/4825 ,  C08G18/798

摘要： Compositions are described comprising a) polyoxymethylene, b) thermoplastic elastomer having active hydrogen atoms, c) polyoxymethylene which differs from component a) and contains active hydrogen atoms, d) reagent for covalent coupling of components b) and c), and e) if appropriate, another impact modifier, which differs from component b). The compositions feature improved toughness and can be used for production of moldings.

摘要翻译： 描述的组合物包括a）聚甲醛，b）具有活性氢原子的热塑性弹性体，c）与组分a）不同的聚甲醛，含有活性氢原子，d）组分b）和c）共价偶联的试剂，和e）如果 合适的另一种抗冲改性剂，其不同于组分b）。 该组合物具有改进的韧性并可用于制造模制品。

公开(公告)号：US07915350B2

公开(公告)日：2011-03-29

申请号：US11402687

申请日：2006-04-12

申请人： Holger Schmalz ,  Christine Köstler ,  Klaus Kurz

发明人： Holger Schmalz ,  Christine Köstler ,  Klaus Kurz

IPC分类号： C08G18/48

CPC分类号： C08G18/4825 ,  C08G18/798

摘要： Compositions are described comprising a) polyoxymethylene, b) thermoplastic elastomer having active hydrogen atoms, c) polyoxymethylene which differs from component a) and contains active hydrogen atoms, d) reagent for covalent coupling of components b) and c), and e) if appropriate, another impact modifier, which differs from component b).The compositions feature improved toughness and can be used for production of moldings.

摘要翻译： 描述的组合物包括a）聚甲醛，b）具有活性氢原子的热塑性弹性体，c）与组分a）不同的聚甲醛，含有活性氢原子，d）组分b）和c）共价偶联的试剂，和e）如果 合适的另一种抗冲改性剂，其不同于组分b）。 该组合物具有改进的韧性并可用于制造模制品。