公开(公告)号：US4698218A

公开(公告)日：1987-10-06

申请号：US683475

申请日：1984-12-19

申请人： Dominique Belot ,  Jean-Yves Rade ,  Jean-Francois Piffard ,  Christian Larquet ,  Philippe Cornut

发明人： Dominique Belot ,  Jean-Yves Rade ,  Jean-Francois Piffard ,  Christian Larquet ,  Philippe Cornut

IPC分类号： C01B33/04 ,  G03G5/08 ,  H01J9/20

CPC分类号： C01B33/043 ,  C01B33/04 ,  G03G5/08 ,  H01J9/20

摘要： Silicon hydrides are produced by acid hydrolysis of ternary silicon alloys. According to the process there are made to react an industrial ternary alloy of the formula M.sub.x M.sup.2.sub.y Si.sub.z, in which M.sup.1 is a reducing metal, M.sup.2 is an alkali alkaline-earth metal, with a dilute acid selected from hydracids and orthophosphoric acid, at a concentration of 2N to 6N, by adding the ternary alloy in the form of fine powder to the acid, the reaction being preformed between ambient temperature and 90.degree. C. The various hydrides are condensed, and separated by fractional evaporation under partial vacuum. The silicon hydrides--silane, disilane and higher polysilanes--after purification can be used as silicon vectors, depending on their chemical nature, particularly in the industries of electronic components, photovolaitic cells, photocopier drums and for frosting light bulbs by the dry method.

摘要翻译： 氢化硅是通过三元硅合金的酸水解产生的。 根据该方法，使式MxM2ySiz的工业三元合金（其中M1是还原金属，M2是碱金属碱金属）与选自氢酸和正磷酸的稀酸反应，浓度为 2N至6N，通过向酸中加入细粉末形式的三元合金，反应在环境温度和90℃之间进行。将各种氢化物冷凝，并在部分真空下通过分级蒸发分离。 取决于其化学性质，特别是在电子元件，光电池，复印机鼓中的工业以及通过干法的结霜灯泡，纯化后的硅氢化硅烷，硅烷和高级聚硅烷可以用作硅载体。