Optical article comprising a double-layer abrasion and scratch resistant coating and method for production thereof

    公开(公告)号:US10222511B2

    公开(公告)日:2019-03-05

    申请号:US15264290

    申请日:2016-09-13

    摘要: The invention relates to an optical article comprising a substrate coated with an abrasion and scratch resistant coating composed of a lower layer and an upper layer that do adhere to each other, the upper layer and the lower layer being layers of cured upper and lower layer compositions, said upper layer composition comprising at least one organosilane, or a hydrolyzate thereof, of formula RnYmSi(X)4-n-m and at least one compound, or a hydrolyzate thereof, of formula M(Z)x, the following ratio being lower than 2.3: Rs = ⁢ theoretical ⁢ ⁢ dry ⁢ ⁢ matter ⁢ ⁢ weight ⁢ ⁢ of compounds ⁢ ⁢ I ⁢ ⁢ in ⁢ ⁢ the ⁢ ⁢ upper ⁢ ⁢ layer ⁢ ⁢ composition theoretical ⁢ ⁢ dry ⁢ ⁢ matter ⁢ ⁢ weight ⁢ ⁢ of compounds ⁢ ⁢ II ⁢ ⁢ in ⁢ ⁢ the ⁢ ⁢ upper ⁢ ⁢ layer ⁢ ⁢ composition said lower layer composition comprising at least one organosilane, or a hydrolyzate thereof, of formula R′n′Y′m′Si(X′)4-n′-m′ and, optionally, at least one compound, or a hydrolyzate thereof, of formula M′(Z′)y, the following ratio being higher than 2.3: Ri = ⁢ theoretical ⁢ ⁢ dry ⁢ ⁢ matter ⁢ ⁢ weight ⁢ ⁢ of compounds ⁢ ⁢ III ⁢ ⁢ in ⁢ ⁢ the ⁢ ⁢ lower ⁢ ⁢ layer ⁢ ⁢ composition theoretical ⁢ ⁢ dry ⁢ ⁢ matter ⁢ ⁢ extract ⁢ ⁢ of compounds ⁢ ⁢ IV ⁢ ⁢ in ⁢ ⁢ the ⁢ ⁢ lower ⁢ ⁢ layer ⁢ ⁢ composition In the hereabove formulas, M and M′ are metals or metalloids of valences x and y, at least equal to 4, R and R′ groups are monovalent organic groups that are bound to silicon through a carbon atom and that contain at least one epoxy function, X, X′, Z and Z′ groups are hydrolyzable groups, Y and Y′ are monovalent organic groups that are bound to silicon through a carbon atom, n, m, n′ and m′ being integers such that n and n′=1 or 2 with n+m and n′+m′=1 or 2.

    ELECTROCHROMIC COMPOSITION
    7.
    发明申请
    ELECTROCHROMIC COMPOSITION 有权
    电致变色组合物

    公开(公告)号:US20160282694A1

    公开(公告)日:2016-09-29

    申请号:US15022775

    申请日:2014-09-16

    IPC分类号: G02F1/15 G02C7/10

    摘要: The present invention relates to an electrochromic composition comprising at least one reducing compound and at least two oxidizing compounds, said at least two oxidizing compounds having similar oxydo-reduction potentials. More specifically, said at least two oxidizing compounds are selected from viologen derivatives. Said composition can be used as a variable transmittance medium for the manufacture of an optical article, such as an ophthalmic lens.

    摘要翻译: 本发明涉及包含至少一种还原化合物和至少两种氧化化合物的电致变色组合物,所述至少两种氧化化合物具有相似的氧化还原电位。 更具体地说,所述至少两种氧化化合物选自紫精衍生物。 所述组合物可以用作用于制造诸如眼科镜片的光学制品的可变透射率介质。