公开(公告)号：US09309344B2

公开(公告)日：2016-04-12

申请号：US14683718

申请日：2015-04-10

Applicant: EVONIK INDUSTRIES AG

Inventor： Renat Kadyrov ,  Christa Dumrath ,  Matthias Beller ,  Andreas Dumrath ,  Helfried Neumann ,  Stephanie Klein

IPC: C08G61/08 ,  C08G61/06 ,  C08F4/80 ,  C08F236/20 ,  C08F32/00 ,  C08F32/08 ,  B01J31/22

CPC classification number: C08F236/20 ,  B01J31/2265 ,  B01J31/2273 ,  B01J31/2295 ,  C08F4/80 ,  C08F32/00 ,  C08F32/08 ,  C08G61/08 ,  C08G2261/3325 ,  C08G2261/418

Abstract: The present invention relates to a process for preparing polymers by means of ring-opening metathetic polymerization, consisting of the following steps: a) providing a reaction mixture consisting of a cycloalkene or a cycloalkene mixture, b) adding a ruthenium compound of the general formula RuX1X2L1aL2b (I) where a=0 or 1, b=1 or 2, such that a+b=2; X1, X2=independently selected anionic ligands; L1=uncharged π-binding ligand; L2=N-heterocyclic carbene of the formula IIa, IIb or IIc; c) adding a chain transfer agent in a molar ratio in the range from 1:5 to 1:1000 based on the cycloalkene or the sum total of the cycloalkenes in the cycloalkene mixture, d) converting at a temperature within a range from 0° C. to 250° C.

Abstract translation: 本发明涉及通过开环易位聚合制备聚合物的方法，包括以下步骤：a）提供由环烯烃或环烯烃混合物组成的反应混合物，b）将通式钌化合物 RuX1X2L1aL2b（I）其中a = 0或1，b = 1或2，使得a + b = 2; X1，X2 =独立选择的阴离子配体; L1 =不带电的;结合配体; L2 =式IIa，IIb或IIc的N-杂环卡宾; c）基于环烯烃或环烯烃混合物中环烯烃的总和，加入摩尔比在1:5至1:1000范围内的链转移剂，d）在0° C.至250℃

公开(公告)号：US20160031845A1

公开(公告)日：2016-02-04

申请号：US14774862

申请日：2014-02-13

Applicant: EVONIK INDUSTRIES AG

Inventor： Renat Kadyrov ,  Christa Dumrath ,  Andreas Dumrath ,  Helfried Neumann ,  Matthias Beller

IPC: C07D313/08 ,  C07C41/18 ,  C07C67/333 ,  C07D207/48 ,  B01J31/24 ,  B01J31/22

CPC classification number: C07D313/08 ,  B01J31/2265 ,  B01J31/2295 ,  B01J31/24 ,  B01J2531/821 ,  C07C6/04 ,  C07C41/18 ,  C07C67/333 ,  C07C2527/14 ,  C07C2531/20 ,  C07C2531/22 ,  C07C2531/28 ,  C07C2601/10 ,  C07C2601/16 ,  C07D207/48 ,  C07C43/188 ,  C07C69/75 ,  C07C69/74 ,  C07C15/52

Abstract: The present invention relates to a process for preparing olefins by means of metathesis, which comprises the following steps a. provision of an olefin reaction mixture containing at least one olefin, b. addition of a ruthenium compound of the general formula [RuX2L1xL2y]z (I), where X=anionic ligand; L1=uncharged π-bonding ligand; L2=uncharged electron donor ligand; x=0, 1; y=1, 2, 3; z=1, 2, c. addition of a Lewis acid and/or an anionic, noncoordinating salt, d. reaction at temperatures in the range from 30° C. to 140° C., where no addition of an alkyne or alkynol is carried out. The invention further relates to the use of this process in metathesis reactions.

Abstract translation: 本发明涉及通过复分解制备烯烃的方法，其包括以下步骤a。 提供含有至少一种烯烃的烯烃反应混合物，b。 加入通式[RuX 2 L 1 x L 2y] z（I）的钌化合物，其中X =阴离子配体; L1 =不带电荷的键合配体; L2 =不带电子的电子给体配体; x = 0,1， y = 1，2，3; z = 1,2，c。 添加路易斯酸和/或阴离子非配位盐，d。 在30℃至140℃的温度下进行反应，其中不加入炔烃或炔醇。 本发明还涉及这种方法在复分解反应中的用途。