公开(公告)号：US3758623A

公开(公告)日：1973-09-11

申请号：US3758623D

申请日：1971-06-02

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： KRAMER G

IPC: C07C5/27 ,  C07C5/24

CPC classification number: C07C5/2721 ,  C07C5/2724 ,  Y10S585/906 ,  Y10S585/942 ,  Y10S585/952 ,  C07C15/067 ,  C07C15/00 ,  C07C9/00

Abstract: Benzene, which contains at least four substituted halogens, is an effective solvent for a Lewis acid catalyst employed in the isomerization of hydrocarbons. A particularly preferred isomerization solvent is 1,2,3,4-tetrachlorobenzene and is used in conjunction with aluminum bromide. In another aspect of this invention, if hydrogen, with or without added hydrogenation components, is added to the catalyst system, the isomerization selectivity of the reaction is greatly improved and the life of the catalyst system itself is greatly enhanced. When substantial amounts of benzene are present in the feed, a hydrogenation component is added to the system so that the benzene is hydrogenated to cyclohexane which is then subsequently isomerized to methylcyclopentane.

Abstract translation: 含有至少四个取代的卤素的苯是用于烃异构化的路易斯酸催化剂的有效溶剂。 特别优选的异构化溶剂是1,2,3,4-四氯苯，并与溴化铝一起使用。 在本发明的另一方面，如果在催化剂体系中加入氢或不加入氢化组分的氢气，反应的异构化选择性大大提高，催化剂体系本身的寿命大大提高。 当进料中存在大量的苯时，将氢化组分加入到体系中，使苯氢化成环己烷，然后将其异构化为甲基环戊烷。

公开(公告)号：US3725500A

公开(公告)日：1973-04-03

申请号：US3725500D

申请日：1971-09-28

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： KRAMER G

IPC: B01J27/08 ,  C07C5/27 ,  C07C5/28 ,  B01J11/74

CPC classification number: B01J27/08 ,  C07C5/2721

Abstract: A catalyst composition comprising (1) aluminum halo bromides such as aluminum bromide and (2) sulfur oxo halides such as sulfurylfluorochloride stabilizes high alkyl carbonium ion concentrations. The catalyst is useful in isomerization processes for converting normal paraffins and naphthenes to isoparaffins and highly branched naphthenes.

Abstract translation: 包含（1）卤化铝卤化物如溴化铝和（2）硫代氧代卤化物如硫酰氟氯化物的催化剂组合物稳定了高烷基碳鎓离子浓度。 该催化剂可用于将正构链烷烃和环烷烃转化为异链烷烃和高支化环烷烃的异构化方法。