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    Isomerization processes and catalysts therefor
    1.
    发明授权
    Isomerization processes and catalysts therefor 失效
    异构化方法和催化剂

    公开(公告)号：US5245103A

    公开(公告)日：1993-09-14

    申请号：US963166

    申请日：1992-10-19

    申请人： An-hsiang Wu

    发明人： An-hsiang Wu

    IPC分类号： B01J27/053 ,  C07C5/27 ,  C07C5/29

    CPC分类号： C07C5/2789 ,  B01J27/053 ,  C07C5/2721 ,  C07C5/29

    摘要： In one embodiment, C.sub.4 -C.sub.10 alkanes and/or C.sub.5 -C.sub.10 cycloalkanes are isomerized in the presence of a catalyst which has been prepared by heating AlCl.sub.3, at least one aluminum sulfate-containing support material and at least one chlorinated hydrocarbon (preferably CCl.sub.4) at about 40.degree.-90.degree. C., followed by separating the formed solid from the chlorinated hydrocarbon.In another embodiment, C.sub.5 -C.sub.10 cycloalkane(s) are isomerized in the presence of a catalyst which has been prepared by heating AlCl.sub.3, at least one sulfur-containing acid (H.sub.2 SO.sub.4 and/or ClSO.sub.3 H and/or FSO.sub.3 H and/or CF.sub.3 SO.sub.3 H) and at least one chlorinated hydrocarbon (preferably CCl.sub.4) at about 40.degree.-90.degree. C., followed by separating the formed solid from the chlorinated hydrocarbon.

    摘要翻译： 在一个实施方案中，C4-C10烷烃和/或C5-C10环烷烃在已经通过加热AlCl 3，至少一种含有硫酸铝的载体材料和至少一种氯化烃（优选CCl 4））制备的催化剂存在下异构化， 在约40℃-90℃下，然后从氯化烃中分离形成的固体。 在另一个实施方案中，C 5 -C 10环烷烃在已经通过加热AlCl 3，至少一种含硫酸（H 2 SO 4和/或ClSO 3 H和/或FSO 3 H和/或CF 3 SO 3 H）和 至少一种氯化烃（优选CCl 4），然后将形成的固体与氯化烃分离。

    Isomerization process and catalyst therefor
    2.
    发明授权
    Isomerization process and catalyst therefor 失效
    异构化方法和催化剂

    公开(公告)号：US5238896A

    公开(公告)日：1993-08-24

    申请号：US991845

    申请日：1992-12-16

    申请人： Gyanesh P. Khare

    发明人： Gyanesh P. Khare

    IPC分类号： B01J27/122 ,  B01J27/125 ,  B01J37/00 ,  C07C5/27 ,  C07C5/29

    CPC分类号： C07C5/2789 ,  B01J27/122 ,  B01J27/125 ,  B01J37/0018 ,  C07C5/2721 ,  C07C5/29 ,  C07C2101/14

    摘要： A composition is prepared by mixing at least one aluminum halide (preferably AlCl.sub.3), at least one copper(II) salt (preferably CuCl.sub.2), calcium aluminate and at least one alcohol (preferably ethanol), shaping the mixture, and drying the shaped particles. The thus-obtained catalyst composition can be employed as a catalyst in the isomerization of alkanes and/or cycloalkanes.

    摘要翻译： 通过混合至少一种卤化铝（优选AlCl 3），至少一种铜（II）盐（优选CuCl 2），铝酸钙和至少一种醇（优选乙醇）来制备组合物，使混合物成形，并干燥成型颗粒 。 由此获得的催化剂组合物可用作烷烃和/或环烷烃异构化中的催化剂。

    Cycloparaffin isomerization using a catalytically active aluminum halide intercalated in graphite
    3.
    发明授权
    Cycloparaffin isomerization using a catalytically active aluminum halide intercalated in graphite 失效
    使用插入石墨的催化活性铝卤化物进行环烷烃异构化

    公开(公告)号：US4102937A

    公开(公告)日：1978-07-25

    申请号：US747126

    申请日：1976-12-03

    申请人： Jesse R. Harris

    发明人： Jesse R. Harris

    IPC分类号： B01J27/08 ,  C07C5/27 ,  C07C5/29 ,  C07C5/28

    CPC分类号： C07C5/2721 ,  B01J27/08 ,  C07C5/29

    摘要： The percentage conversion of isomerizable cycloparaffins is improved as compared to prior art methods by contacting the isomerizable cycloparaffins with a compound of aluminum halide intercalated in grahite and a hydrogen halide to form a catalytically active composition with a continuation of contact of the isomerizable cycloparaffins and the catalytically active composition to achieve substantial isomerization of the cycloparaffins.

    摘要翻译： 与现有技术方法相比，可异构化的环烷烃的转化率提高了，通过使可异构化环烷烃与插入在海藻酸盐和卤化氢中的卤化铝化合物接触以形成具有连续的可异构化环烷烃和催化剂的接触的催化活性组合物 活性组合物以实现环烷烃的显着异构化。

    Catalyst pretreatment with hydrocarbon feedstock
    4.
    发明授权
    Catalyst pretreatment with hydrocarbon feedstock 失效
    用烃原料催化剂预处理

    公开(公告)号：US4058575A

    公开(公告)日：1977-11-15

    申请号：US586177

    申请日：1975-06-12

    申请人： Robert P. Cahn ,  John P. Longwell

    发明人： Robert P. Cahn ,  John P. Longwell

    IPC分类号： B01J27/12 ,  C07C5/27 ,  C07C13/00 ,  C07C3/56 ,  C07C5/28

    CPC分类号： B01J27/12 ,  C07C5/2721 ,  Y02P20/584

    摘要： Partially deactivated hydrocarbon conversion catalysts comprising (a) one or more Lewis acids of the formula MX.sub.n where M is a metal selected from Group III-A, IV-B, V or VI-B elements of the Periodic Table, X is a halogen, n is the ratio of halogen atoms to atoms of M and varies from 1-8, and (b) a strong Bronsted acid are contacted with a hydrocarbon feedstock to recover the active or potentially active catalyst species from the partially deactivated catalyst stream prior to regeneration. In addition, potential organic and inorganic catalyst poisons present in said feedstock are removed therefrom during said contacting prior to introducing said feedstock into a hydrocarbon conversion process.

    摘要翻译： 部分失活的烃转化催化剂，其包含（a）一种或多种式MXn的路易斯酸，其中M是选自元素周期表III-A，IV-B，V或VI-B族元素的金属，X是卤素， n是卤素原子与M原子的比率并且从1-8变化，和（b）强烈的布朗斯台德酸与烃原料接触以在再生之前从部分失活的催化剂物流中回收活性或潜在活性的催化剂物质 。 此外，在将所述原料引入烃转化过程之前，在所述接触期间，从所述原料中除去存在于所述原料中的潜在有机和无机催化剂毒物。