公开(公告)号：US20060084716A1

公开(公告)日：2006-04-20

申请号：US11250422

申请日：2005-10-17

申请人： Edward Zahora ,  Anthony Tortorello ,  Edward Murphy ,  Anthony Toussaint ,  Timothy Reichert ,  Kelly Hawkinson

发明人： Edward Zahora ,  Anthony Tortorello ,  Edward Murphy ,  Anthony Toussaint ,  Timothy Reichert ,  Kelly Hawkinson

IPC分类号： B29D11/00

CPC分类号： C09D175/16 ,  C08G18/4213 ,  C08G18/4238 ,  C08G18/8175 ,  G02B1/048 ,  Y10T428/29 ,  Y10T428/2938 ,  Y10T428/31551 ,  C08G18/42 ,  C08L33/08 ,  C08L33/10 ,  C08L75/04

摘要： The invention relates to a radiation curable composition including a polyester urethane (meth)acrylate oligomer prepared from ortho-carboxylic polyester polyols, where the composition, after cure, has a secant modulus greater than about 600 MPa and an elongation at break of at least about 10%. The invention also relates to coated optical fibers and optical fiber ribbon including at least one coating derived from this composition, and to a process of making these coated optical fibers.

摘要翻译： 本发明涉及一种可辐射固化组合物，其包含由邻羧基聚酯多元醇制备的聚酯氨基甲酸酯（甲基）丙烯酸酯低聚物，其中组合物在固化后具有大于约600MPa的割线模数，断裂伸长率为至少约 10％。 本发明还涉及包含衍生自该组合物的至少一种涂层的涂覆光纤和光纤带，以及制造这些涂覆光纤的方法。

公开(公告)号：US07276543B2

公开(公告)日：2007-10-02

申请号：US09972203

申请日：2001-10-09

申请人： Timothy E. Bishop ,  Paul E. Snowwhite ,  Tyson Norlin ,  James J. Schouten ,  John Southwell ,  Anthony Toussaint

发明人： Timothy E. Bishop ,  Paul E. Snowwhite ,  Tyson Norlin ,  James J. Schouten ,  John Southwell ,  Anthony Toussaint

IPC分类号： C08F2/50

CPC分类号： C09D175/16 ,  C03C25/106 ,  C03C25/1065 ,  C08F290/067 ,  C08G18/4854 ,  C08G18/672 ,  C08G18/75 ,  Y10T428/2938 ,  Y10T428/2947 ,  C08G18/48 ,  C08G18/40

摘要： The present invention relates to a coated optical fiber comprising a glass optical fiber with a single protective coating or a combination of an inner and an outer primary coating applied thereon and optionally with a colored coating subsequently applied thereon wherein the inner primary coating or at least a portion of the single coating is prepared from a radiation curable composition which when cured as a capillary film with a 100W medium pressure mercury lamp has a percentage reacted acrylate unsaturation of at least about 54% after exposure to a dose of about 4.4 mJ/cm2 or wherein the outer primary coating is prepared from a radiation curable composition which when cured as a capillary film with a 100 W medium pressure mercury lamp has a percentage reacted acrylate unsaturation of at least about 56% after exposure to a dose of about 4.4 mJ/cm2. The invention further relates to a radiation curable composition having a high cure speed.

摘要翻译： 本发明涉及一种涂覆光纤，其包括具有单一保护涂层的玻璃光纤或其上施加有内部和外部初级涂层的组合，并且可选地随后涂覆有着色涂层，其中所述内部初级涂层或至少一个 单一涂层的一部分由可辐射固化组合物制备，当用100W中压汞灯固化时，其暴露于约4.4mJ / cm 2的剂量后，丙烯酸酯不饱和度的百分比至少为约54％ 或者其中外部初级涂层由可辐射固化组合物制备，当用100W中压汞灯固化为毛细管膜时，其暴露于丙烯酸酯不饱和度的百分比至少为约56％ 约4.4mJ / cm 2的剂量。 本发明还涉及具有高固化速度的可辐射固化组合物。

公开(公告)号：US06438306B1

公开(公告)日：2002-08-20

申请号：US09544209

申请日：2000-04-07

申请人： Timothy E. Bishop ,  Paul E. Snowwhite ,  Tyson Norlin ,  James J. Schouten ,  John Southwell ,  Anthony Toussaint

发明人： Timothy E. Bishop ,  Paul E. Snowwhite ,  Tyson Norlin ,  James J. Schouten ,  John Southwell ,  Anthony Toussaint

IPC分类号： G02B602

CPC分类号： C09D4/06 ,  C03C25/106 ,  C03C25/1065 ,  C08F2/50 ,  C08F220/32 ,  C08F2220/346 ,  C09D4/00 ,  C08F290/14 ,  C08F290/06 ,  C08F2220/1875

摘要： The present invention relates to a coated optical fiber comprising a glass optical fiber with a single protective coating or a combination of an inner and an outer primary coating applied thereon and optionally with a colored coating subsequently applied thereon wherein the inner primary coating or at least a portion of the single coating is prepared from a radiation curable composition which when cured as a capillary film with a 100 W medium pressure mercury lamp has a percentage reacted acrylate unsaturation of at least about 54% after exposure to a dose of about 4.4 mJ/cm2 or wherein the outer primary coating is prepared from a radiation curable composition which when cured as a capillary film with a 100 W medium pressure mercury lamp has a percentage reacted acrylate unsaturation of at least about 56% after exposure to a dose of about 4.4 mJ/cm2. The invention further relates to a radiation curable composition having a high cure speed.

摘要翻译： 本发明涉及一种涂覆光纤，其包括具有单一保护涂层的玻璃光纤或其上施加有内部和外部初级涂层的组合，并且可选地随后涂覆有着色涂层，其中所述内部初级涂层或至少一个 单一涂层的一部分由可辐射固化组合物制备，当用100W中压汞灯固化时，其暴露于约4.4mJ / cm 2的剂量后具有至少约54％的丙烯酸酯不饱和度的百分比 或其中外部初级涂层由可辐射固化组合物制备，当用100W中压汞灯固化时，其具有至少约56％反应的丙烯酸酯不饱和度的百分比，暴露于约4.4mJ / cm2。 本发明还涉及具有高固化速度的可辐射固化组合物。