公开(公告)号：US6139719A

公开(公告)日：2000-10-31

申请号：US169966

申请日：1998-10-13

申请人： Eric Benazzi ,  Jocelyne Brendle ,  Ronan Le Dred ,  Jacques Baron ,  Daniel Saehr ,  Nathalie Georges-Marchal ,  Sylvie Lacombe

发明人： Eric Benazzi ,  Jocelyne Brendle ,  Ronan Le Dred ,  Jacques Baron ,  Daniel Saehr ,  Nathalie Georges-Marchal ,  Sylvie Lacombe

IPC分类号： B01J21/16 ,  B01J27/135 ,  B01J27/19 ,  B01J27/198 ,  B01J29/04 ,  B01J29/16 ,  C01B33/38 ,  C10G47/16 ,  C10G47/20 ,  C10G47/00

CPC分类号： B01J29/049 ,  B01J29/084 ,  C10G47/16 ,  B01J2229/42 ,  B01J23/883

摘要： The invention relates to dioctahedral phyllosilicates 2:1 whose basal spacing is at least equal to 2.0.times.10.sup.-9 m and which in the interlayer space comprise pillars based on at least one of the compounds that is selected from the group that is formed by SiO.sub.2, Al.sub.2 O.sub.3, TiO.sub.2, ZrO.sub.2, V.sub.2 O.sub.5, or any combination of the latter. Preferably, they contain fluorine. The invention also relates to a process for their preparation that includes treatment with a surfactant, followed by treatment with a primary or secondary amine and at least one alkoxide of an element that is selected from the group that is formed by the elements Si, Al, Zr, Ti and V. The invention also relates to a catalyst that comprises said phyllosilicate, at least one matrix, and optionally a zeolite Y. The invention also relates to a process for converting hydrocarbons with this catalyst, and in particular a hydrocracking process.

摘要翻译： 本发明涉及基面间距至少等于2.0×10 -9 m的双八面体页硅酸盐2：1，其中在层间空间中包含基于选自由SiO 2形成的基团中的至少一种化合物的柱， Al 2 O 3，TiO 2，ZrO 2，V 2 O 5或后者的任意组合。 优选地，它们含有氟。 本发明还涉及一种其制备方法，其包括用表面活性剂处理，然后用伯胺或仲胺和至少一种选自下列元素的醇盐进行处理：元素Si，Al， Zr，Ti和V.本发明还涉及包含所述页硅酸盐，至少一种基质和任选的沸石Y的催化剂。本发明还涉及用该催化剂转化烃，特别是加氢裂化方法的方法。