公开(公告)号：US20060079712A1

公开(公告)日：2006-04-13

申请号：US11285721

申请日：2005-11-22

申请人： Eric Haupfear ,  Jerald Heise ,  Amy Jorgenson ,  Michael Rogers ,  Henry Chien ,  Eduardo Casanova ,  William Hooper ,  William Scholle ,  Juan Arhancet ,  Mark Leiber ,  Kent Wittler ,  Karen Wittler

发明人： Eric Haupfear ,  Jerald Heise ,  Amy Jorgenson ,  Michael Rogers ,  Henry Chien ,  Eduardo Casanova ,  William Hooper ,  William Scholle ,  Juan Arhancet ,  Mark Leiber ,  Kent Wittler ,  Karen Wittler

IPC分类号： C07F9/38

CPC分类号： C07F9/3813 ,  Y02P20/582

摘要： This invention generally relates to liquid phase oxidation processes for making N-(phosphonomethyl)glycine (also known in the agricultural chemical industry as glyphosate) and related compounds. This invention, for example, particularly relates to processes wherein an N-(phosphonomethyl)iminodiacetic acid (NPMIDA) substrate (i.e., N-(phosphonomethyl)iminodiacetic acid, a salt of N-(phosphonomethyl)iminodiacetic acid, or an ester of N-(phosphonomethyl)iminodiacetic acid) is continuously oxidized to form an N-(phosphonomethyl)glycine product (i.e., N-(phosphonomethyl)glycine, a salt of N-(phosphonomethyl)glycine, or an ester of N-(phosphonomethyl)glycine). This invention also, for example, particularly relates to processes wherein an N-(phosphonomethyl)iminodiacetic acid substrate is oxidized to form an N-(phosphonomethyl)glycine product, which, in turn, is crystallized (at least in part) in an adiabatic crystallizer.

公开(公告)号：US20090259068A1

公开(公告)日：2009-10-15

申请号：US12365507

申请日：2009-02-04

申请人： Eric Haupfear ,  Jerald D. Heise ,  Amy L. Jorgenson ,  Michael Rogers ,  Henry Chien ,  Eduardo Casanova ,  William Hooper ,  William Scholle ,  Juan Arhancet ,  Mark A. Leiber ,  Kent Wittler ,  Karen A. Wittler

发明人： Eric Haupfear ,  Jerald D. Heise ,  Amy L. Jorgenson ,  Michael Rogers ,  Henry Chien ,  Eduardo Casanova ,  William Hooper ,  William Scholle ,  Juan Arhancet ,  Mark A. Leiber ,  Kent Wittler ,  Karen A. Wittler

IPC分类号： C07F9/38 ,  B01D1/00 ,  B01D9/00

CPC分类号： C07F9/3813 ,  Y02P20/582

摘要： This invention generally relates to liquid phase oxidation processes for making N-(phosphonomethyl)glycine (also known in the agricultural chemical industry as glyphosate) and related compounds. This invention, for example, particularly relates to processes wherein an N-(phosphonomethyl)iminodiacetic acid (NPMIDA) substrate (i.e., N-(phosphonomethyl)iminodiacetic acid, a salt of N-(phosphonomethyl)iminodiacetic acid, or an ester of N-(phosphonomethyl)iminodiacetic acid) is continuously oxidized to form an N-(phosphonomethyl)glycine product (i.e., N-(phosphonomethyl)glycine, a salt of N-(phosphonomethyl)glycine, or an ester of N-(phosphonomethyl)glycine). This invention also, for example, particularly relates to processes wherein an N-(phosphonomethyl)iminodiacetic acid substrate is oxidized to form an N-(phosphonomethyl)glycine product, which, in turn, is crystallized (at least in part) in an adiabatic crystallizer.

摘要翻译： 本发明一般涉及制备N-（膦酰基甲基）甘氨酸（农业化学工业中也称为草甘膦）和相关化合物的液相氧化方法。 本发明特别涉及N-（膦酰基甲基）亚氨基二乙酸（NPMIDA）底物（即N-（膦酰基甲基）亚氨基二乙酸，N-（膦酰基甲基）亚氨基二乙酸的盐或N - （膦酰基甲基）亚氨基二乙酸）连续氧化形成N-（膦酰基甲基）甘氨酸产物（即N-（膦酰基甲基）甘氨酸，N-（膦酰基甲基）甘氨酸的盐或N-（膦酰基甲基）甘氨酸的酯 ）。 本发明还特别涉及其中N-（膦酰基甲基）亚氨基二乙酸底物被氧化以形成N-（膦酰基甲基）甘氨酸产物的方法，其反过来在绝热中结晶（至少部分地） 结晶器。