公开(公告)号：US4425219A

公开(公告)日：1984-01-10

申请号：US288765

申请日：1981-07-31

申请人： Erik Kroo ,  Laszlo Kovacs ,  Istvan Nemes ,  Katalin Szabo nee Mogyorosi ,  Geza Szentgyorgyi ,  Galina Moger nee Eremineva ,  Andras Nemeth ,  Dezso Gal ,  Szilard Riederauer ,  Janos Szepvolgyi

发明人： Erik Kroo ,  Laszlo Kovacs ,  Istvan Nemes ,  Katalin Szabo nee Mogyorosi ,  Geza Szentgyorgyi ,  Galina Moger nee Eremineva ,  Andras Nemeth ,  Dezso Gal ,  Szilard Riederauer ,  Janos Szepvolgyi

IPC分类号： C10G1/04 ,  C10B57/06

CPC分类号： C10G1/04

摘要： The invention relates to an improved method for the production of liquid carbon compounds from coal. According to the invention coal is oxidized at 80.degree. to 300.degree. C. in the presence of the vapors of a C.sub.1-5 aliphatic alcohol, optionally under the introduction of steam, and then the liquid carbon compounds are separated from the resulting product mixture.The process according to the invention can also be performed under atmospheric pressure, 50-80% of the carbon content of the coal converted appear in the liquid product. The liquid product contains the more valuable fraction, boiling below 300.degree. C., as major component.

摘要翻译： 本发明涉及一种从煤中生产液态碳化合物的改进方法。 根据本发明，任选地在蒸汽引入下，在C1-5脂族醇的蒸气存在下，在80℃至300℃下将煤氧化，然后将液体碳化合物与所得产物混合物分离。 根据本发明的方法也可以在大气压下进行，转化的碳含量的50-80％出现在液体产物中。 液体产品含有较贵的部分，沸点低于300℃，作为主要成分。

公开(公告)号：US4368333A

公开(公告)日：1983-01-11

申请号：US288761

申请日：1981-07-31

申请人： Laszlo Kovacs ,  Galina Moger nee Eremineva ,  Dezso Gal ,  Peter Hajdu ,  Julia Lukacs ,  Erik Kroo ,  Istvan Nemes ,  Andras Nemeth ,  Katalin Szabo nee Mogyorosi ,  Geza Szentgyorgyi ,  Szilard Riederauer ,  Janos Szepvolgyi

发明人： Laszlo Kovacs ,  Galina Moger nee Eremineva ,  Dezso Gal ,  Peter Hajdu ,  Julia Lukacs ,  Erik Kroo ,  Istvan Nemes ,  Andras Nemeth ,  Katalin Szabo nee Mogyorosi ,  Geza Szentgyorgyi ,  Szilard Riederauer ,  Janos Szepvolgyi

IPC分类号： C07C51/21 ,  C07C51/245 ,  C07C51/16

CPC分类号： C07C51/21 ,  C07C51/245

摘要： The invention relates to an improved method for the liquid phase oxidation of coal performed with oxygen optionally in the presence of water. According to the invention oxidation is performed in the presence of a cooxidation partner selected from the group of liquid hydrocarbons and oxygen-containing liquid hydrocarbons, and if water is also present, the pH of the homogeneous solution formed from the cooxidation partner and water is maintained at a slightly acidic value.By the method of the invention the formation of carbon dioxide can be suppressed significantly.

摘要翻译： 本发明涉及用氧气任选地在水存在下进行的用于液相氧化的改进方法。 根据本发明，在选自液体烃和含氧液体烃的共氧化配位体的存在下进行氧化，如果还存在水，则保持由共氧化伴侣和水形成的均匀溶液的pH 呈酸性。 通过本发明的方法，可以显着地抑制二氧化碳的形成。

公开(公告)号：US4366129A

公开(公告)日：1982-12-28

申请号：US251997

申请日：1981-04-08

申请人： Bela Czegledi ,  Mihaly Csovari ,  Miklos Erdelyi ,  Lajos Streker ,  Istvan Toth ,  Katalin Szabo nee Mogyorosi ,  Szilard Riederauer ,  Geza Szentgyorgyi

发明人： Bela Czegledi ,  Mihaly Csovari ,  Miklos Erdelyi ,  Lajos Streker ,  Istvan Toth ,  Katalin Szabo nee Mogyorosi ,  Szilard Riederauer ,  Geza Szentgyorgyi

IPC分类号： C01F7/22 ,  C01F7/26 ,  C01G49/00 ,  C01G49/06 ,  C21B15/00

CPC分类号： C01G49/06 ,  C01F7/26 ,  C01G49/0009 ,  C21B15/006 ,  C22B3/24 ,  C22B3/42 ,  Y02P10/234

摘要： The invention concerns a process for the preparation of alumina and ferric oxide from low-grade aluminium and iron carriers. The processes, in addition to conventional technological steps, comprises the steps of dissolving the iron content of a ground, mineral material in an aqueous hydrochloric acid solution containing 200 to 420 g./lit. of hydrochloric acid at 90.degree. to 130.degree. C., eliminating the iron from the slurry of from a solution obtained by filtration of the slurry, with an anion exchange resin or semipermeable membrane or cloth, continuously or discontinuously, eluting the iron from the ion exchange resin and recycling hydrochloric acid and sulfuric acid in a closed system.

摘要翻译： 本发明涉及从低级铝和铁载体制备氧化铝和氧化铁的方法。 除了常规技术步骤之外，这些方法包括将研磨的矿物材料的铁含量溶解在含有200至420g / L的盐酸水溶液中的步骤。 的盐酸在90至130℃下，从阴离子交换树脂或半透膜或布连续或不连续地从通过过滤浆液获得的溶液的浆料中除去铁，从离子中洗脱铁 交换树脂，并在封闭系统中回收盐酸和硫酸。

公开(公告)号：US4416862A

公开(公告)日：1983-11-22

申请号：US340997

申请日：1982-01-20

申请人： Dinko Gencev ,  Katalin Szabo nee Mogyorosi ,  Szilard Riederauer ,  Janos Szepvolgyi

发明人： Dinko Gencev ,  Katalin Szabo nee Mogyorosi ,  Szilard Riederauer ,  Janos Szepvolgyi

IPC分类号： C01B33/18 ,  C01F7/60 ,  C01F7/56

CPC分类号： C01B33/181 ,  C01F7/60

摘要： The invention relates to a method for utilizing silicon tetrachloride formed as a by-product of the chlorination of aluminium- and silicon-containing minerals. More particularly, the invention relates to a process for the preparation of aluminium trichloride and silicon dioxide by chlorination of alumina with silicon tetrachloride. According to the invention alumina or a material essentially consisting of alumina is reacted with silicon tetrachloride as a single chlorinating agent at a temperature exceeding 400.degree. C., unreacted silicon tetrachloride is separated from the aluminium trichloride formed and is recycled into the chlorination step, silicon dioxide is isolated from the solid residue essentially consisting of the unreacted alumina and silicon dioxide, unreacted alumina is recycled into the chlorination step and aluminium trichlorine obtained is continuously eliminated.

摘要翻译： 本发明涉及一种利用四氯化硅作为含铝和含硅矿物的氯化副产物形成的方法。 更具体地说，本发明涉及通过用四氯化硅氧化氧化铝来制备三氯化铝和二氧化硅的方法。 根据本发明，在超过400℃的温度下，将氧化铝或基本上由氧化铝组成的材料与四氯化硅作为单一氯化剂反应，将未反应的四氯化硅与形成的三氯化铝分离，并循环到氯化步骤中，硅 从基本上由未反应的氧化铝和二氧化硅组成的固体残余物中分离二氧化物，将未反应的氧化铝再循环到氯化步骤中，并且连续消除获得的三氯化铝。

公开(公告)号：US4530819A

公开(公告)日：1985-07-23

申请号：US536232

申请日：1983-09-28

申请人： Bela Czegledi ,  Mihaly Csovari ,  Miklos Erdelyi ,  Jozsef Illi ,  Lajos Stocker ,  Attila Szoke ,  Katalin Szabo nee Mogyorosi ,  Szilard Riederauer ,  Miklos Ormossy ,  Gyula Terenyi ,  Istvan Csurgai

发明人： Bela Czegledi ,  Mihaly Csovari ,  Miklos Erdelyi ,  Jozsef Illi ,  Lajos Stocker ,  Attila Szoke ,  Katalin Szabo nee Mogyorosi ,  Szilard Riederauer ,  Miklos Ormossy ,  Gyula Terenyi ,  Istvan Csurgai

IPC分类号： C01F7/58 ,  C01F7/06 ,  C01F7/22 ,  C01F7/26 ,  C01F7/32 ,  C01F7/56 ,  C01G49/06 ,  C01G49/10 ,  C22B1/00 ,  C22B3/00 ,  C22B3/10

CPC分类号： C22B1/00 ,  C01F7/0613 ,  C01F7/32 ,  C01F7/56 ,  C01G49/06 ,  C01G49/10 ,  C22B3/10 ,  C22B3/24 ,  C22B3/42 ,  Y02P10/234

摘要： The invention relates to an improved process for reducing the iron content of iron-, silicon- and aluminium-containing raw materials and for producing ferric oxide, optionally along with an alumina concentrate. According to the invention the iron content of mineral raw materials, e.g. bauxites, clay minerals, colliary rocks, red muds, etc. is eliminated by passing through one or more beds prepared from the unground but preferably prebroaken and sized raw material an aqueous hydrochloric acid solution, the concentration of which exceeds 100 g./lit., at a temperature below 90.degree. C., preferably at room temperature, optionally in the presence of a flocculating agent. By pyrolytic decomposition of the ferric chloride prepared ferric oxide can be produced. The bed residue of reduced iron content can be utilized in the Bayer process for producing alum earth, as a starting substance of ceramic industry or, after treating with sulfuric acid, dissolving in hydrochloric acid or water, elimination of silica, pyrolytic decomposition of the aluminium sulfate obtained, as an alumina concentrate.

摘要翻译： 本发明涉及一种用于降低铁，硅和铝的原料的铁含量以及任选地与氧化铝浓缩物一起生产氧化铁的改进方法。 根据本发明，矿物原料的铁含量，例如 铝土矿，粘土矿物，泥岩，红泥等通过一个或多个床，通过一个或多个床，从未研磨，优选预先浸泡和定尺寸的原料盐酸水溶液中去除，其浓度超过100g / L。 ，温度低于90℃，优选在室温下，任选地在絮凝剂存在下进行。 通过热分解制备的三氯化铁可制得氧化铁。 还原铁含量的床残渣可用于生产明矾土的拜耳法，作为陶瓷工业的起始物质，或用硫酸处理后，溶解在盐酸或水中，消除二氧化硅，热分解铝 获得的硫酸铝作为氧化铝浓缩物。