公开(公告)号：US07810904B2

公开(公告)日：2010-10-12

申请号：US11813398

申请日：2006-01-20

申请人： Etsuko Hino ,  Norio Ohkuma ,  Yoshikazu Saito ,  Mitsutoshi Noguchi ,  Helmut Schmidt ,  Carsten Becker-Willinger ,  Pamela Kalmes

发明人： Etsuko Hino ,  Norio Ohkuma ,  Yoshikazu Saito ,  Mitsutoshi Noguchi ,  Helmut Schmidt ,  Carsten Becker-Willinger ,  Pamela Kalmes

IPC分类号： B41J2/135

CPC分类号： B41J2/1603 ,  B41J2/1623 ,  B41J2/1626 ,  B41J2/1631 ,  B41J2/1639 ,  B41J2/1645 ,  G03F7/038 ,  G03F7/0757

摘要： A method for producing an ink jet recording head having high durability and high ink resistance can enable high-quality image recording by employing a material capable of reducing the internal stress and having satisfactory patterning characteristics. Such an ink jet recording head can be produced with high precision. A cationically photopolymerizable resin composition containing a condensate of a hydrolysable organosilane compound, employed as a material for forming a flow path forming member, enables a reduction of internal stress and a highly precise pattern in the flow path forming member, thereby providing an ink jet recording head having a high durability and a high ink resistance and capable of high-quality printing over a prolonged time.

摘要翻译： 用于制造具有高耐久性和高油墨电阻的喷墨记录头的方法可以通过采用能够降低内应力并且具有令人满意的图案特征的材料来实现高质量的图像记录。 可以高精度地制造这样的喷墨记录头。 作为用于形成流路形成部件的材料的含有水解性有机硅烷化合物的缩合物的阳离子型光聚合性树脂组合物能够在流路形成部件中减少内部应力和高精度图案，从而提供喷墨记录 头部具有高耐久性和高耐油墨性，并且能够在长时间内进行高质量的印刷。

公开(公告)号：US20110122198A1

公开(公告)日：2011-05-26

申请号：US13017114

申请日：2011-01-31

申请人： Etsuko Hino ,  Norio Ohkuma ,  Yoshikazu Saito ,  Mitsutoshi Noguchi ,  Helmut Schmidt ,  Carsten Becker-Willinger ,  Pamela Kalmes

发明人： Etsuko Hino ,  Norio Ohkuma ,  Yoshikazu Saito ,  Mitsutoshi Noguchi ,  Helmut Schmidt ,  Carsten Becker-Willinger ,  Pamela Kalmes

IPC分类号： B41J2/14

CPC分类号： G03F7/0757 ,  B41J2/1603 ,  B41J2/1623 ,  B41J2/1626 ,  B41J2/1631 ,  B41J2/1639 ,  B41J2/1645 ,  G03F7/038

摘要： The invention provides a method for producing an ink jet recording head having a high durability and a high ink resistance and enabling a high-quality image recording by employing a material capable of reducing the internal stress and having satisfactory patterning characteristics. It also provides a method of producing such ink jet recording head with a high precision. A cationically photopolymerizable resin composition containing a condensate of a hydrolysable organosilane compound, employed as a material for forming a flow path forming member, enables a reduction of internal stress and a highly precise pattern in the flow path forming member thereby providing an ink jet recording head having a high durability and a high ink resistance and capable of high-quality printing over a prolonged time, and a producing method therefor.

摘要翻译： 本发明提供了一种制造具有高耐久性和高油墨电阻的喷墨记录头的方法，并且能够通过采用能够降低内应力并具有令人满意的图案特征的材料进行高质量的图像记录。 它还提供了一种以高精度制造这种喷墨记录头的方法。 作为用于形成流路形成部件的材料的含有可水解的有机硅烷化合物的缩合物的阳离子光聚合性树脂组合物能够在流路形成部件中降低内部应力和高精度图案，从而提供喷墨记录头 具有高耐久性和高耐油墨性并且能够在长时间内进行高质量印刷及其制造方法。

公开(公告)号：US20100309247A1

公开(公告)日：2010-12-09

申请号：US12857158

申请日：2010-08-16

申请人： Etsuko Hino ,  Norio Ohkuma ,  Yoshikazu Saito ,  Mitsutoshi Noguchi ,  Helmut Schmidt ,  Carsten Becker-Willinger ,  Pamela Kalmes

发明人： Etsuko Hino ,  Norio Ohkuma ,  Yoshikazu Saito ,  Mitsutoshi Noguchi ,  Helmut Schmidt ,  Carsten Becker-Willinger ,  Pamela Kalmes

IPC分类号： B41J2/015

CPC分类号： G03F7/0757 ,  B41J2/1603 ,  B41J2/1623 ,  B41J2/1626 ,  B41J2/1631 ,  B41J2/1639 ,  B41J2/1645 ,  G03F7/038

摘要： The invention provides a method for producing an ink jet recording head having a high durability and a high ink resistance and enabling a high-quality image recording by employing a material capable of reducing the internal stress and having satisfactory patterning characteristics. It also provide a method of producing such ink jet recording head with a high precision. A cationically photopolymerizable resin composition containing a condensate of a hydrolysable organosilane compound, employed as a material for forming a flow path forming member, enables a reduction of internal stress and a highly precise pattern in the flow path forming member thereby providing an ink jet recording head having a high durability and a high ink resistance and capable of high-quality printing over a prolonged time, and a producing method therefor.

摘要翻译： 本发明提供了一种制造具有高耐久性和高油墨电阻的喷墨记录头的方法，并且能够通过采用能够降低内应力并具有令人满意的图案特征的材料进行高质量的图像记录。 它还提供了一种以高精度制造这种喷墨记录头的方法。 作为用于形成流路形成部件的材料的含有可水解的有机硅烷化合物的缩合物的阳离子光聚合性树脂组合物能够在流路形成部件中降低内部应力和高精度图案，从而提供喷墨记录头 具有高耐久性和高耐油墨性并且能够在长时间内进行高质量印刷及其制造方法。

公开(公告)号：US08535796B2

公开(公告)日：2013-09-17

申请号：US11794742

申请日：2006-01-20

申请人： Carsten Becker-Willinger ,  Pamela Kalmes ,  Helmut Schmidt ,  Etsuko Hino ,  Mitsutoshi Noguchi ,  Yoshikazu Saito ,  Norio Ohkuma

发明人： Carsten Becker-Willinger ,  Pamela Kalmes ,  Helmut Schmidt ,  Etsuko Hino ,  Mitsutoshi Noguchi ,  Yoshikazu Saito ,  Norio Ohkuma

IPC分类号： B32B3/10 ,  B32B27/38 ,  B05D5/00 ,  B05D3/00 ,  B05D3/02 ,  C09D163/00 ,  C09D183/04 ,  C08L63/00 ,  C08L83/04

CPC分类号： G03F7/0757 ,  C08L83/06 ,  Y10T428/24802 ,  Y10T428/269 ,  Y10T428/31511 ,  Y10T428/31525 ,  Y10T428/31529 ,  Y10T428/31663 ,  C08L2666/14

摘要： A polymerizable composite composition comprising a) a hydrolysate and/or condensate of at least one hydrolysable alkylsilane having at least one alkyl group, at least one hydrolysable arylsilane having at least one aryl group or at least one hydrolysable alkylarylsilane having at least one alkylaryl group, and at least one hydrolysable silane containing an epoxy group, b) at least one organic compound having at least 2 epoxy groups, and c) a cationic initiator, is suitable to provide, upon curing, substrates with a patterned coating or patterned molded articles. The patterned coatings and molded articles obtained show high relaxation ability, high chemical resistance and mechanical stability. Micropatterns can be obtained with high stability of shape.

摘要翻译： 一种可聚合复合组合物，其包含a）至少一种具有至少一个烷基的至少一种可水解的烷基硅烷的水解产物和/或缩合物，至少一种具有至少一个芳基的至少一种可水解的芳基硅烷或具有至少一个烷基芳基的至少一个可水解的烷基芳基硅烷， 和至少一种含有环氧基的可水解硅烷，b）至少一种具有至少2个环氧基的有机化合物和c）阳离子引发剂，适用于在固化时具有图案化涂层或图案化模塑制品的基材。 获得的图案涂料和模制品显示出高的松弛能力，高耐化学性和机械稳定性。 可以获得具有高稳定性的微图案。

公开(公告)号：US08012364B2

公开(公告)日：2011-09-06

申请号：US12857158

申请日：2010-08-16

申请人： Etsuko Hino ,  Norio Ohkuma ,  Yoshikazu Saito ,  Mitsutoshi Noguchi ,  Helmut Schmidt ,  Carsten Becker-Willinger ,  Pamela Kalmes

发明人： Etsuko Hino ,  Norio Ohkuma ,  Yoshikazu Saito ,  Mitsutoshi Noguchi ,  Helmut Schmidt ,  Carsten Becker-Willinger ,  Pamela Kalmes

IPC分类号： G11B5/127

CPC分类号： G03F7/0757 ,  B41J2/1603 ,  B41J2/1623 ,  B41J2/1626 ,  B41J2/1631 ,  B41J2/1639 ,  B41J2/1645 ,  G03F7/038

摘要： A method for producing an ink jet recording head having high durability and high ink resistance can enabling enable high-quality image recording by employing a material capable of reducing the internal stress and having satisfactory patterning characteristics. Such an ink jet recording head can be produced with high precision. A cationically photopolymerizable resin composition containing a condensate of a hydrolysable organosilane compound, employed as a material for forming a flow path forming member, enables a reduction of internal stress and a highly precise pattern in the flow path forming member, thereby providing an ink jet recording head having high durability and high ink resistance and capable of high-quality printing over a prolonged time.

摘要翻译： 制造具有高耐久性和高耐油墨性的喷墨记录头的方法能够通过采用能够降低内应力并具有令人满意的图案特征的材料实现高质量的图像记录。 可以高精度地制造这样的喷墨记录头。 作为用于形成流路形成部件的材料的含有水解性有机硅烷化合物的缩合物的阳离子型光聚合性树脂组合物能够在流路形成部件中减少内部应力和高精度图案，从而提供喷墨记录 头部具有高耐久性和高耐油墨性，并且能够在长时间内进行高质量的印刷。

公开(公告)号：US20090284567A1

公开(公告)日：2009-11-19

申请号：US11813398

申请日：2006-01-20

申请人： Etsuko Hino ,  Norio Ohkuma ,  Yoshikazu Saito ,  Mitsutoshi Noguchi ,  Helmut Schmidt ,  Carsten Becker-Willinger ,  Pamela Kalmes

发明人： Etsuko Hino ,  Norio Ohkuma ,  Yoshikazu Saito ,  Mitsutoshi Noguchi ,  Helmut Schmidt ,  Carsten Becker-Willinger ,  Pamela Kalmes

IPC分类号： B41J2/135 ,  C09D11/02 ,  G03F7/20

CPC分类号： B41J2/1603 ,  B41J2/1623 ,  B41J2/1626 ,  B41J2/1631 ,  B41J2/1639 ,  B41J2/1645 ,  G03F7/038 ,  G03F7/0757

摘要： The invention provides a method for producing an ink jet recording head having a high durability and a high ink resistance and enabling a high-quality image recording by employing a material capable of reducing the internal stress and having satisfactory patterning characteristics. It also provides a method of producing such ink jet recording head with a high precision. A cationically photopolymerizable resin composition containing a condensate of a hydrolysable organosilane compound, employed as a material for forming a flow path forming member, enables a reduction of internal stress and a highly precise pattern in the flow path forming member thereby providing an ink jet recording head having a high durability and a high ink resistance and capable of high-quality printing over a prolonged time, and a producing method therefor.

摘要翻译： 本发明提供了一种制造具有高耐久性和高油墨电阻的喷墨记录头的方法，并且能够通过采用能够降低内应力并具有令人满意的图案特征的材料进行高质量的图像记录。 它还提供了一种以高精度制造这种喷墨记录头的方法。 作为用于形成流路形成部件的材料的含有可水解的有机硅烷化合物的缩合物的阳离子光聚合性树脂组合物能够在流路形成部件中降低内部应力和高精度图案，从而提供喷墨记录头 具有高耐久性和高耐油墨性并且能够在长时间内进行高质量印刷及其制造方法。

公开(公告)号：US08087748B2

公开(公告)日：2012-01-03

申请号：US13017114

申请日：2011-01-31

申请人： Etsuko Hino ,  Norio Ohkuma ,  Yoshikazu Saito ,  Mitsutoshi Noguchi ,  Helmut Schmidt ,  Carsten Becker-Willinger ,  Pamela Kalmes

发明人： Etsuko Hino ,  Norio Ohkuma ,  Yoshikazu Saito ,  Mitsutoshi Noguchi ,  Helmut Schmidt ,  Carsten Becker-Willinger ,  Pamela Kalmes

IPC分类号： B41J2/14

CPC分类号： G03F7/0757 ,  B41J2/1603 ,  B41J2/1623 ,  B41J2/1626 ,  B41J2/1631 ,  B41J2/1639 ,  B41J2/1645 ,  G03F7/038

摘要： An ink jet recording head having a high durability and high ink resistance can enable high-quality image recording by employing a material capable of reducing the internal stress and having satisfactory patterning characteristics. Such an ink jet recording head can be produced with high precision. A cationically photopolymerizable resin composition containing a condensate of a hydrolysable organosilane compound, employed as a material for forming a flow path forming member, enables a reduction of internal stress and a highly precise pattern in the flow path forming member, thereby providing an ink jet recording head having high durability and high ink resistance and capable of high-quality printing over a prolonged time.

摘要翻译： 具有高耐久性和高耐油墨性的喷墨记录头可以通过采用能够降低内应力并且具有令人满意的图案特征的材料来实现高质量的图像记录。 可以高精度地制造这样的喷墨记录头。 作为用于形成流路形成部件的材料的含有水解性有机硅烷化合物的缩合物的阳离子型光聚合性树脂组合物能够在流路形成部件中减少内部应力和高精度图案，从而提供喷墨记录 头部具有高耐久性和高耐油墨性，并且能够在长时间内进行高质量的印刷。

公开(公告)号：US20090258197A1

公开(公告)日：2009-10-15

申请号：US12373750

申请日：2007-07-11

申请人： Etsuko Hino ,  Mitsutoshi Noguchi ,  Norio Ohkuma ,  Yoshikazu Saito ,  Carsten Becker-Willinger ,  Pamela Kalmes ,  Michael Veith

发明人： Etsuko Hino ,  Mitsutoshi Noguchi ,  Norio Ohkuma ,  Yoshikazu Saito ,  Carsten Becker-Willinger ,  Pamela Kalmes ,  Michael Veith

IPC分类号： B32B3/10 ,  G03F7/038 ,  G03F7/20 ,  G03F7/075

CPC分类号： G03F7/038 ,  G03F7/0047 ,  G03F7/0757 ,  Y10T428/24802 ,  Y10T428/31663

摘要： The invention provides a composite composition comprising a cationically polymerizable organic resin, a cationic photoinitiator, a hydrolysate and/or condensate of at least one hydrolysable silane compound and inorganic nanoparticles. The composite composition is suitable for the preparation of patterned moulded articles or substrates having a patterned coating, in particular by photolithography. Micropatterns obtained show improved properties, such as a high shape stability and an excellent elastic modulus.

摘要翻译： 本发明提供一种复合组合物，其包含阳离子可聚合有机树脂，阳离子光引发剂，至少一种可水解硅烷化合物的水解产物和/或缩合物和无机纳米颗粒。 该复合组合物适用于制备具有图案化涂层的图案化模塑制品或基材，特别是通过光刻法。 获得的微图案显示出改进的性能，例如高的形状稳定性和优异的弹性模量。

公开(公告)号：US20100260978A9

公开(公告)日：2010-10-14

申请号：US12373750

申请日：2007-07-11

申请人： Etsuko Hino ,  Mitsutoshi Noguchi ,  Norio Ohkuma ,  Yoshikazu Saito ,  Carsten Becker-Willinger ,  Pamela Kalmes ,  Michael Veith

发明人： Etsuko Hino ,  Mitsutoshi Noguchi ,  Norio Ohkuma ,  Yoshikazu Saito ,  Carsten Becker-Willinger ,  Pamela Kalmes ,  Michael Veith

IPC分类号： B32B3/10 ,  G03F7/038 ,  G03F7/20 ,  G03F7/075

CPC分类号： G03F7/038 ,  G03F7/0047 ,  G03F7/0757 ,  Y10T428/24802 ,  Y10T428/31663

摘要： The invention provides a composite composition comprising a cationically polymerizable organic resin, a cationic photoinitiator, a hydrolysate and/or condensate of at least one hydrolysable silane compound and inorganic nanoparticles. The composite composition is suitable for the preparation of patterned moulded articles or substrates having a patterned coating, in particular by photolithography. Micropatterns obtained show improved properties, such as a high shape stability and an excellent elastic modulus.

摘要翻译： 本发明提供一种复合组合物，其包含阳离子可聚合有机树脂，阳离子光引发剂，至少一种可水解硅烷化合物的水解产物和/或缩合物和无机纳米颗粒。 该复合组合物适用于制备具有图案化涂层的图案化模塑制品或基材，特别是通过光刻法。 获得的微图案显示出改进的性能，例如高的形状稳定性和优异的弹性模量。

公开(公告)号：US08680179B2

公开(公告)日：2014-03-25

申请号：US12373750

申请日：2007-07-11

申请人： Etsuko Hino ,  Mitsutoshi Noguchi ,  Norio Ohkuma ,  Yoshikazu Saito ,  Carsten Becker-Willinger ,  Pamela Kalmes ,  Michael Veith

发明人： Etsuko Hino ,  Mitsutoshi Noguchi ,  Norio Ohkuma ,  Yoshikazu Saito ,  Carsten Becker-Willinger ,  Pamela Kalmes ,  Michael Veith

IPC分类号： C08K3/34

CPC分类号： G03F7/038 ,  G03F7/0047 ,  G03F7/0757 ,  Y10T428/24802 ,  Y10T428/31663

摘要： The invention provides a composite composition comprising a cationically polymerizable organic resin, a cationic photoinitiator, a hydrolysate and/or condensate of at least one hydrolysable silane compound and inorganic nanoparticles. The composite composition is suitable for the preparation of patterned moulded articles or substrates having a patterned coating, in particular by photolithography. Micropatterns obtained show improved properties, such as a high shape stability and an excellent elastic modulus.

摘要翻译： 本发明提供一种复合组合物，其包含阳离子可聚合有机树脂，阳离子光引发剂，至少一种可水解硅烷化合物的水解产物和/或缩合物和无机纳米颗粒。 该复合组合物适用于制备具有图案化涂层的图案化模塑制品或基材，特别是通过光刻法。 获得的微图案显示出改进的性能，例如高的形状稳定性和优异的弹性模量。