Method For Forming Resist Underlayer Film And Patterning Process

    公开(公告)号:US20240345483A1

    公开(公告)日:2024-10-17

    申请号:US18601583

    申请日:2024-03-11

    IPC分类号: G03F7/11 G03F7/075 G03F7/09

    CPC分类号: G03F7/11 G03F7/0752 G03F7/094

    摘要: The present invention is a method for forming a resist underlayer film, including the steps of: (i) coating a substrate with a composition for forming a resist underlayer film containing a metal compound having a metal-oxygen covalent bond and an organic solvent; (ii) forming a cured film by heating the coated substrate at a temperature of 100° C. or higher and 600° C. or lower for 10 seconds to 7,200 seconds for curing; and (iii) forming a resist underlayer film by irradiating the cured film with plasma, where a compound containing at least one crosslinking group represented by the following general formulae (a-1) to (a-4), (b-1) to (b-4), and (c-1) to (c-3) is used as the metal compound. This provides: a method for forming a resist underlayer film that contains metal and that exhibits both high filling property and high dry etching resistance; and a patterning process using the method.

    HIGH REFRACTIVE INDEX PHOTORESIST COMPOSITION

    公开(公告)号:US20240337943A1

    公开(公告)日:2024-10-10

    申请号:US18575890

    申请日:2022-08-01

    IPC分类号: G03F7/075 C08G77/38

    CPC分类号: G03F7/0757 C08G77/38

    摘要: A composition contains a photocurable resin that has a weight-average molecular weight of 3000-50000 Daltons, a glass transition temperature of at least 100 degrees Celsius and contains the following siloxane units: 50-80 mole-percent (HSiC>3/2). 10 to 30 mole-percent (R*SiC>3/2), 10 to 40 mole-percent (Ar*SiC>3/2), and 20.0 mole-percent or less of Si—OZ content, where mole-percent values are relative to moles of silicon atoms in the photocurable resin, R* is a photocurable group. Ar* in each occurrence is selected from a group of halogen-substituted aryl groups and polyaryl groups: Z in each occurrence is selected from hydrogen and alkyl groups. and subscripts x and y are independently in each occurrence either one or 2.

    Composition For Forming Silicon-Containing Resist Underlayer Film And Patterning Process

    公开(公告)号:US20240319598A1

    公开(公告)日:2024-09-26

    申请号:US18594575

    申请日:2024-03-04

    摘要: The present invention is a composition for forming a silicon-containing resist underlayer film, containing a condensation reaction-type thermosetting silicon-containing material (Sx), being a polysiloxane resin, where the material has a non-condensation reactive organic group that reacts with a radical chemical species, the resin includes more than 0 and 70 mol % or less of one or more of a repeating unit represented by the following general formula (Sx-4) and a repeating unit represented by the general formula (Sx-5), and the organic group remains unreacted after a heat-curing reaction of the polysiloxane resin. This provides: a composition for forming a resist underlayer film containing a thermosetting silicon-containing material in photolithography using a high-energy beam, the material improving sensitivity, LWR, and resolution of an upper layer resist and further contributing to the prevention of pattern collapse; and a patterning process using the composition for forming a resist underlayer film.