公开(公告)号：US20170320976A1

公开(公告)日：2017-11-09

申请号：US15145320

申请日：2016-05-03

申请人： ExxonMobil Chemical Patents Inc.

发明人： Jo Ann M. Canich ,  Vyatcheslav V. Izmer ,  Dmitry S. Kononovich ,  Alexander Z. Voskoboynikov

IPC分类号： C08F10/00 ,  C08F4/6592 ,  C07F17/00 ,  C08F4/659

CPC分类号： C08F10/00 ,  C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F4/65925 ,  C08F4/65927 ,  C08F110/02 ,  C08F2500/03 ,  C08F2500/04 ,  C08F210/16 ,  C08F210/14 ,  C08F110/06 ,  C08F2500/15 ,  C08F210/06

摘要： This invention relates to a compound represented by the formula: TyLAMXn−2 wherein: A is a substituted or unsubstituted tetrahydro-as-indacenyl group bonded to M; L is substituted or unsubstituted monocyclic or polycyclic arenyl ligand or monocyclic or polycyclic heteroarenyl ligand bonded to M; M is a group 3, 4, 5, or 6 transition metal (preferably group 4); T is a bridging group bonded to L and A; y is 0 or 1, indicating the absence or presence of T; X is a leaving group, typically a univalent anionic ligand, or two Xs are joined and bound to the metal atom to form a metallocycle ring, or two Xs are joined to form a chelating ligand, a diene ligand, or an alkylidene; n is the oxidation state of M and is 3, 4, 5, or 6.

公开(公告)号：US09803037B1

公开(公告)日：2017-10-31

申请号：US15145320

申请日：2016-05-03

申请人： ExxonMobil Chemical Patents Inc.

发明人： Jo Ann M. Canich ,  Vyatcheslav V. Izmer ,  Dmitry S. Kononovich ,  Alexander Z. Voskoboynikov

IPC分类号： C07F17/00 ,  C08F4/6592 ,  C08F10/00 ,  C08F4/659

CPC分类号： C08F10/00 ,  C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F4/65925 ,  C08F4/65927 ,  C08F110/02 ,  C08F2500/03 ,  C08F2500/04 ,  C08F210/16 ,  C08F210/14 ,  C08F110/06 ,  C08F2500/15 ,  C08F210/06

摘要： This invention relates to a compound represented by the formula: TyLAMXn-2 wherein: A is a substituted or unsubstituted tetrahydro-as-indacenyl group bonded to M; L is substituted or unsubstituted monocyclic or polycyclic arenyl ligand or monocyclic or polycyclic heteroarenyl ligand bonded to M; M is a group 3, 4, 5, or 6 transition metal (preferably group 4); T is a bridging group bonded to L and A; y is 0 or 1, indicating the absence or presence of T; X is a leaving group, typically a univalent anionic ligand, or two Xs are joined and bound to the metal atom to form a metallocycle ring, or two Xs are joined to form a chelating ligand, a diene ligand, or an alkylidene; n is the oxidation state of M and is 3, 4, 5, or 6.

公开(公告)号：US11766669B2

公开(公告)日：2023-09-26

申请号：US17355866

申请日：2021-06-23

申请人： ExxonMobil Chemical Patents Inc.

发明人： Jo Ann M. Canich ,  Vyatcheslav V. Izmer ,  Dmitry S. Kononovich ,  Alexander Z. Voskoboynikov

IPC分类号： C07F17/00 ,  C08F4/6592 ,  C08F10/00 ,  B01J31/22

CPC分类号： B01J31/2295 ,  C07F17/00 ,  C08F4/6592 ,  C08F4/65927 ,  B01J2231/12 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  C08F10/00

摘要： This invention relates to hexahydrocyclopenta[e]-as-indacen-1-yl and octahydrobenzo[e]-as-indacen-1-yl based catalyst complexes represented by the formula:

TyLAMXn-2

wherein: M is a group 3-6 metal; n is the oxidation state of M; A is a substituted or unsubstituted polycyclic arenyl ligand bonded to M wherein the polycyclic ligand contains an indenyl fragment with two partially unsaturated rings annulated to the phenyl ring of the indenyl ligand fragment; L is a substituted or unsubstituted monocyclic or polycyclic arenyl ligand bonded to M, or a substituted or unsubstituted monocyclic or polycyclic heteroarenyl ligand bonded to M, or is represented by the formula JR′z-y where J is a group 15 or 16 heteroatom bonded to M, R′ is a substituted or unsubstituted hydrocarbyl substituent bonded to J, and z is 1 or 2; T is a bridging group; y is 1 or 0; and each X is independently a univalent anionic ligand, or two Xs are joined and bound to the metal atom to form a metallocycle ring, or two Xs are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand.

公开(公告)号：US09796795B2

公开(公告)日：2017-10-24

申请号：US15145314

申请日：2016-05-03

申请人： ExxonMobil Chemical Patents Inc.

发明人： Jo Ann M. Canich ,  Crisita Carmen H. Atienza ,  Vyatcheslav V. Izmer ,  Dmitry S. Kononovich ,  Alexander Z. Voskoboynikov

IPC分类号： C07F17/00 ,  C08F4/6592 ,  C08F10/00 ,  C08F4/76 ,  C07F7/28 ,  C08F110/02 ,  C08F110/06 ,  C08F210/02 ,  C08F4/659

CPC分类号： C08F4/76 ,  C07F7/28 ,  C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F110/02 ,  C08F110/06 ,  C08F210/02 ,  C08F2420/02 ,  C08F10/00 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/03

摘要： This invention relates to a compound represented by the formula: TyCp′mMGnXq wherein: Cp′ is a tetrahydroindacenyl group which may be substituted or unsubstituted, provided that when Cp′ is tetrahydro-s-indacenyl: 1) the 3 and/or 4 positions are not aryl or substituted aryl, 2) the 3 position is not directly bonded to a group 15 or 16 heteroatom, 3) there are no additional rings fused to the tetrahydroindacenyl ligand, 4) T is not bonded to the 2-position, and 5) the 5, 6, or 7-position is geminally disubstituted; M is a group 3, 4, 5, or 6 transition metal; G is a heteroatom group represented by the formula JRiz where J is N, P, O or S, Ri is a C1 to C20 hydrocarbyl group, and z is 1 or 2; T is a bridging group; y is 0 or 1; X is a leaving group; m=1; n=1, 2 or 3; q=1, 2 or 3, and the sum of m+n+q is equal to the oxidation state of the transition metal.

公开(公告)号：US09458254B2

公开(公告)日：2016-10-04

申请号：US14325449

申请日：2014-07-08

申请人： ExxonMobil Chemical Patents Inc.

发明人： Jo Ann M. Canich ,  Ilya S. Borisov ,  Arkady K. Golenishchev ,  Georgy P. Goryunov ,  Dmitry V. Uborsky ,  Pavel S. Kulyabin ,  Dmitry S. Kononovich ,  Vyatcheslav V. Izmer ,  Alexander Z. Voskoboynikov

IPC分类号： C07F17/00 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/06 ,  C08F210/06 ,  C08F4/659 ,  C08F110/06

CPC分类号： C08F4/65912 ,  C07F17/00 ,  C08F4/65908 ,  C08F4/65927 ,  C08F10/00 ,  C08F110/06 ,  C08F210/06

摘要： This invention relates to novel bridged a hafnium transition metal metallocene catalyst compounds having two indenyl ligands substituted at the 4 positions with a C1 to C10 alkyl, where the 3 positions are hydrogen (assuming the bridge position is counted as the one position) and the bridging atom is carbon or silicon which is incorporated into a cyclic group comprising 3, 4, 5, or 6 silicon and/or carbon atoms that make up the cyclic ring.

摘要翻译： 本发明涉及具有两个茚基配体的铪过渡金属茂金属催化剂化合物，其具有在4个位置被C1至C10烷基取代，其中3个位置是氢（假定桥位置被计为一个位置）和桥接 原子是碳或硅，其被引入到构成环的3,4,5或6个硅和/或碳原子的环状基团中。

公开(公告)号：US11345766B2

公开(公告)日：2022-05-31

申请号：US16098592

申请日：2017-03-31

申请人： ExxonMobil Chemical Patents Inc.

发明人： Jo Ann M. Canich ,  Vyatcheslav V. Izmer ,  Dmitry S. Kononovich ,  Alexander Z. Voskoboynikov

IPC分类号： C07F7/00 ,  C08F4/6592 ,  C08F4/76 ,  C08F10/00 ,  C07F17/00 ,  C08F4/659

摘要： This invention relates to a compound represented by the formula: TyLAMXn-2 wherein: A is a substituted or unsubstituted tetrahydro-as-indacenyl group bonded to M; L is substituted or unsubstituted monocyclic or polycyclic arenyl ligand or monocyclic or polycyclic heteroarenyl ligand bonded to M; M is a group 3, 4, 5, or 6 transition metal (preferably group 4); T is a bridging group bonded to L and A; y is 0 or 1, indicating the absence or presence of T; X is a leaving group, typically a univalent anionic ligand, or two Xs are joined and bound to the metal atom to form a metallocycle ring, or two Xs are joined to form a chelating ligand, a diene ligand, or an alkylidene; n is the oxidation state of M and is 3, 4, 5, or 6.

公开(公告)号：US20210402384A1

公开(公告)日：2021-12-30

申请号：US17355866

申请日：2021-06-23

申请人： ExxonMobil Chemical Patents Inc.

发明人： Jo Ann M. Canich ,  Vyatcheslav V. Izmer ,  Dmitry S. Kononovich ,  Alexander Z. Voskoboynikov

IPC分类号： B01J31/22 ,  C08F4/6592

摘要： This invention relates to hexahydrocyclopenta[e]-as-indacen-1-yl and octahydrobenzo[e]-as-indacen-1-yl based catalyst complexes represented by the formula: TyLAMXn-2 wherein: M is a group 3-6 metal; n is the oxidation state of M; A is a substituted or unsubstituted polycyclic arenyl ligand bonded to M wherein the polycyclic ligand contains an indenyl fragment with two partially unsaturated rings annulated to the phenyl ring of the indenyl ligand fragment; L is a substituted or unsubstituted monocyclic or polycyclic arenyl ligand bonded to M, or a substituted or unsubstituted monocyclic or polycyclic heteroarenyl ligand bonded to M, or is represented by the formula JR′z-y where J is a group 15 or 16 heteroatom bonded to M, R′ is a substituted or unsubstituted hydrocarbyl substituent bonded to J, and z is 1 or 2; T is a bridging group; y is 1 or 0; and each X is independently a univalent anionic ligand, or two Xs are joined and bound to the metal atom to form a metallocycle ring, or two Xs are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand.

公开(公告)号：US20210238319A1

公开(公告)日：2021-08-05

申请号：US16098592

申请日：2017-03-31

申请人： ExxonMobil Chemical Patents Inc.

发明人： Jo Ann M. Canich ,  Vyatcheslav V. Izmer ,  Dmitry S. Kononovich ,  Alexander Z. Voskoboynikov

IPC分类号： C08F10/00 ,  C07F17/00 ,  C08F4/6592

摘要： This invention relates to a compound represented by the formula: TyLAMXn-2 wherein: A is a substituted or unsubstituted tetrahydro-as-indacenyl group bonded to M; L is substituted or unsubstituted monocyclic or polycyclic arenyl ligand or monocyclic or polycyclic heteroarenyl ligand bonded to M; M is a group 3, 4, 5, or 6 transition metal (preferably group 4); T is a bridging group bonded to L and A; y is 0 or 1, indicating the absence or presence of T; X is a leaving group, typically a univalent anionic ligand, or two Xs are joined and bound to the metal atom to form a metallocycle ring, or two Xs are joined to form a chelating ligand, a diene ligand, or an alkylidene; n is the oxidation state of M and is 3, 4, 5, or 6.

公开(公告)号：US20160244535A1

公开(公告)日：2016-08-25

申请号：US15145314

申请日：2016-05-03

申请人： ExxonMobil Chemical Patents Inc.

发明人： Jo Ann M. Canich ,  Crisita Carmen H. Atienza ,  Vyatcheslav V. Izmer ,  Dmitry S. Kononovich ,  Alexander Z. Voskoboynikov

IPC分类号： C08F4/76 ,  C08F210/02 ,  C08F110/06 ,  C07F7/28 ,  C08F110/02

CPC分类号： C08F4/76 ,  C07F7/28 ,  C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F110/02 ,  C08F110/06 ,  C08F210/02 ,  C08F2420/02 ,  C08F10/00 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/03

摘要： This invention relates to a compound represented by the formula: TyCp′mMGnXq wherein: Cp′ is a tetrahydroindacenyl group which may be substituted or unsubstituted, provided that when Cp′ is tetrahydro-s-indecenyl: 1) the 3 and/or 4 positions are not aryl or substituted aryl, 2) the 3 position is not directly bonded to a group 15 or 16 heteroatom, 3) there are no additional rings fused to the tetrahydroindacenyl ligand, 4) T is not bonded to the 2-position, and 5) the 5, 6, or 7-position is geminally disubstituted; M is a group 3, 4, 5, or 6 transition metal; G is a heteroatom group represented by the formula JRiz where J is N, P, O or S, Ri is a C1 to C20 hydrocarbyl group, and z is 1 or 2; T is a bridging group; y is 0 or 1; X is a leaving group; m=1; n=1, 2 or 3; q=1, 2 or 3, and the sum of m+n+q is equal to the oxidation state of the transition metal.

摘要翻译： 本发明涉及由下式表示的化合物：TyCp'mMGnXq其中：Cp'是可被取代或未取代的四氢茚基，条件是当Cp'为四氢-s-异十烯基时：1）3和/或4位 不是芳基或取代的芳基，2）3位不直接键合到基团15或16杂原子上，3）没有与四氢茚基配体稠合的其他环，4）T不与2-位键合， 5）5,6或7位是双取代的; M是3,4,5或6族过渡金属; G是由式JRi表示的杂原子，其中J是N，P，O或S，R 1是C 1至C 20烃基，z是1或2; T是一个桥接组; y为0或1; X是离职团体 m = 1; n = 1,2或3; q = 1,2或3，m + n + q的和等于过渡金属的氧化态。