公开(公告)号：US20230151028A1

公开(公告)日：2023-05-18

申请号：US17907663

申请日：2021-02-16

Applicant: ExxonMobil Technology and Engineering Company

Inventor： Carter W. Abney ,  Anna C. Ivashko ,  Gerardo J. Majano

IPC: C07F3/02 ,  C07F13/00

CPC classification number: C07F3/02 ,  C07F13/005

Abstract: Metal-organic frameworks are synthesized from either a high concentration synthesis where reaction solutions comprising increased reagent concentrations, or suspensions of reagents which exceed their solubility limit in the reaction solution in a high solids synthesis. In both approaches, the solubility of reagent is maximized by inclusion of a buffer, fixing a nominal pH of the reaction solution to allow metal-organic framework formation. These methods improve yields and scale up of metal-organic frameworks.