公开(公告)号：US20230087627A1

公开(公告)日：2023-03-23

申请号：US17904552

申请日：2021-01-19

Applicant: ExxonMobil Technology and Engineering Company

Inventor： Matthew T. Kapelewski ,  Joseph E. Gatt ,  Aaron W. Peters ,  Wesley Sattler ,  Thomas J. Ferro

IPC: B01J20/22 ,  B01J20/08 ,  B01J20/28 ,  B01J20/26 ,  B01J20/32

Abstract: Provided herein are methods of making an adsorbent bed useful as a micro-reactor, or a catalytic and/or separation device. The adsorbent bed comprises a metal-organic framework composite. In the present methods, one or more metal-organic frameworks in powder form are mixed in a liquid to produce a metal-organic framework suspension or other type of metal-organic framework coating. A monolith is coated with the suspension or coating to provide the metal-organic framework composite having at least one metal-organic framework coating layer deposited on and bounded to the monolith. The metal-organic framework composite produced has a BET surface area of about 1 m2/g to about 300 m2/g and/or a comparative BET surface area of about 40% to about 100% relative to the metal-organic framework monolith, and pore size between about 1 nm and about 50 nm.