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    Bleaching-active metal complexes
    6.
    发明授权
    Bleaching-active metal complexes 失效
    漂白活性金属配合物

    公开(公告)号：US06602441B1

    公开(公告)日：2003-08-05

    申请号：US09613211

    申请日：2000-07-10

    申请人： Bernd Nestler

    发明人： Bernd Nestler

    IPC分类号： C09K300

    CPC分类号： C11D3/168 ,  C11D3/3932 ,  D06L4/13 ,  D21C9/1036 ,  D21C9/163

    摘要： Compounds of the following formula are suitable as activators for peroxy compounds in laundry detergents and cleaning products: [LnMmXp]zYq  (1) in which M is manganese in oxidation stage II, III, IV, V and/or VI or cobalt in oxidation stage II and/or III, X is a coordination group or bridging group, Y is a counterion in the corresponding stoichiometric amount to balance a charge z present, where z as the metal complex charge, can be positive, zero or negative, n and m, independently of one another, are integers of from 1 to 4, p is an integer from 0 to 15, q is z/charge of Y L is a ligand of the formula (2) in which substituents R1 to R8 are as defined in the description.

    摘要翻译： 下式的化合物适合用作衣物洗涤剂和清洁产品中过氧化合物的活化剂：其中M是在氧化阶段II和/或III中的氧化阶段II，III，IV，V和/或VI中的锰，X是 配位基团或桥接基团，Y是相应的化学计量量的平衡值，以平衡作为金属络合物电荷的电荷z存在，其中z可以是正的，零或负的，n和m彼此独立地是 1至4，p为0至15的整数，q为z / YL的电荷为式（2）的配体，其中取代基R 1至R 8如说明书中所定义。

    Metal complexes as bleach activators
    8.
    发明授权
    Metal complexes as bleach activators 失效
    金属配合物作为漂白活化剂

    公开(公告)号：US5969171A

    公开(公告)日：1999-10-19

    申请号：US107780

    申请日：1998-06-30

    申请人： Bernd Nestler

    发明人： Bernd Nestler

    IPC分类号： B01J31/22 ,  C07C235/50 ,  C07C235/60 ,  C07C251/24 ,  C07C251/54 ,  C07F13/00 ,  C07F15/06 ,  C11D3/16 ,  C11D3/26 ,  C11D3/39 ,  C11D3/395 ,  C11D7/32 ,  C11D7/54

    CPC分类号： C11D3/3932 ,  C07C235/50 ,  C07C251/24 ,  C07F13/005

    摘要： Metal complexes of the formula 1[L.sub.n M.sub.m X.sub.p ].sup.z Y.sub.q (1)whereM is manganese in oxidation state II, III, IV, V and/or VI or cobalt in oxidation state II and/or III or iron in oxidation state II and/or III,X is a coordinating or bridging group,Y is a counterion in the appropriate stoichiometric amount to compensate an existing charge z, wherez as the charge of the metal complex can be positive, zero or negative, n and m independently of one another are integers from 1 to 4,p is an integer from 0 to 15,q is z/charge of Y, andL is a ligand of the formula (2), (3) or (4) ##STR1## and A and R.sup.1 to R.sup.8 are as defined in the description.

    摘要翻译： 式1的金属络合物[LnMmXp] zYq（1）其中M是处于氧化态II和/或III的氧化态II，III，IV，V和/或氧化态II或氧化态的二氧化锰中的锰和/或 III，X是配位或桥接基团，Y是以适当的化学计量量的抗衡离子，以补偿现有电荷z，其中z作为金属络合物的电荷可以是正的，零或负的，n和m彼此独立 为1〜4的整数，p为0〜15的整数，q为Z的z /电荷，L为式（2），（3）或（4）的配位体，A，R 1〜R 8为 如说明书中所定义。

    Bleaching-active metal complexes
    9.
    发明授权
    Bleaching-active metal complexes 失效
    漂白活性金属配合物

    公开(公告)号：US05998645A

    公开(公告)日：1999-12-07

    申请号：US71551

    申请日：1998-05-01

    申请人： Bernd Nestler

    发明人： Bernd Nestler

    IPC分类号： B01J31/22 ,  C07F13/00 ,  C07F15/02 ,  C07F15/06 ,  C11D3/39 ,  C11D3/395 ,  C11D7/54 ,  D21C9/10 ,  D21C9/16

    CPC分类号： D21C9/1042 ,  C07F13/005 ,  C11D3/3932

    摘要： Compounds of the following formula are suitable as activators for peroxy compounds in laundry detergents and cleaning products:[L.sub.n M.sub.m X.sub.p ].sup.z Y.sub.q (1)in whichM is manganese in oxidation stage II, III, IV, V and/or VI or cobalt in oxidation stage II and/or Ill, and iron in oxidation stage II and/or III,X is a coordination group or bridging group,Y is a counterion in the corresponding stoichiometric amount to balance a charge z present, wherez as the metal complex charge can be positive, zero or negative,n and m, independently of one another, are integers from 1 to 4,p is an integer from 0 to 15,q is z/charge of Y andL is a ligand of the formula (2) ##STR1## in which substituents R.sup.1 to R.sup.8 are as defined in the description, and A is a C.sub.2 -C.sub.4 -alkylene, C.sub.5 -C.sub.10 -cycloalkylene or amino group.

    摘要翻译： 下式的化合物适用于衣物洗涤剂和清洁产品中过氧化合物的活化剂：[LnMmXp] zYq（1）其中M是氧化阶段II，III，IV，V和/或VI或钴在氧化阶段的锰 II和/或III族，铁在氧化阶段II和/或III中，X是配位基团或桥接基团，Y是相应化学计量量的抗衡离子，以平衡存在的电荷z，其中z作为金属络合物电荷 正，零或负，n和m彼此独立地是1至4的整数，p是0至15的整数，q是z / z的电荷，L是式（2）的配体， 其中取代基R 1至R 8如说明书中所定义，且A为C 2 -C 4 - 亚烷基，C 5 -C 10 - 亚环烷基或氨基。