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公开(公告)号：US4792620A
公开(公告)日：1988-12-20
申请号：US21384
申请日：1987-03-03
CPC分类号： B01J31/0231 , B01J31/1895 , B01J31/20 , B01J31/2409 , C07C51/10 , C07C51/12 , C07C51/14 , C07C67/36 , B01J2231/34 , B01J2531/822
摘要： A catalyst system having high activity and selectivity to carbonylation products comprises a rhodium-containing catalytically active component and a halogen-containing promoter component, the halogen being selected from the group consisting of bromine, iodine, bromide compounds, and iodide compounds.
摘要翻译： 对羰基化产物具有高活性和选择性的催化剂体系包括含铑催化活性组分和含卤素促进剂组分，卤素选自溴，碘，溴化物和碘化合物。
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公开(公告)号：US5003104A
公开(公告)日：1991-03-26
申请号：US265234
申请日：1988-10-31
CPC分类号： B01J31/26 , B01J31/0231 , B01J31/1895 , B01J31/20 , B01J31/2404 , C07C51/10 , C07C51/12 , C07C51/14 , C07C67/36 , B01J2231/321 , B01J2231/34 , B01J2531/822
摘要： This invention involves a process for the carbonylation of a carbonylatable reactant, e.g., an alkyl ester, a dialkyl ether or mixtures thereof by reacting the same with carbon monoxide. The process comprises effecting the carbonylation in the presence of a solution of a catalyst system containing a rhodium compound, an iodide and a lithium component at a temperature of from 50.degree. C. to 400.degree. C. at a carbon monoxide partial pressure of 1 psig to 15,000 psig. Hydrogen may also be present. The invention also concerns a carbonylation catalyst system effective for the addition of carbon monoxide to a carbonylatable reactant which comprises a solution containing as essential components a rhodium containing active component, an iodide and a lithium component.
摘要翻译： 本发明涉及通过使其与一氧化碳反应来羰基化可羰基化反应物，例如烷基酯，二烷基醚或其混合物的方法。 该方法包括在含有铑化合物，碘化物和锂组分的催化剂体系的溶液存在下，在50℃至400℃的温度下，在1psig的一氧化碳分压下进行羰基化 至15,000 psig。 氢也可能存在。 本发明还涉及一种有效地将一氧化碳加入到可羰基化反应物中的羰基化催化剂体系，其包含含有铑的活性组分，碘化物和锂组分作为主要成分的溶液。
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3.发明授权
公开(公告)号：US4690912A
公开(公告)日：1987-09-01
申请号：US541845
申请日：1983-10-14
CPC分类号： B01J31/2404 , B01J27/08 , B01J31/0231 , B01J31/20 , C07C51/12 , B01J2231/34 , B01J2531/822
摘要： A catalyst system having high activity and selectivity to carbonylation products comprises a rhodium-containing catalytically active component and a halogen-containing promoter component, the halogen being selected from the group consisting of bromine, iodine, bromide compounds, and iodide compounds.
摘要翻译： 对羰基化产物具有高活性和选择性的催化剂体系包括含铑催化活性组分和含卤素促进剂组分，卤素选自溴，碘，溴化物和碘化合物。
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公开(公告)号：US4060547A
公开(公告)日：1977-11-29
申请号：US325291
申请日：1973-01-22
CPC分类号： C07C51/12
摘要： The present invention relates to a process for the preparation of dicarboxylic acids, specifically by the reaction of non-vicinal glycols; halogen containing derivatives in which the OH radical of the glycol is substituted by Cl, Br, or I; ester derivatives of glycols; and cyclic ether derivatives of glycols; with carbon monoxide in the presence of catalyst compositions essentially comprising rhodium or iridium compounds and complexes, together with a halide promoter.
摘要翻译： 本发明涉及二羧酸的制备方法，特别是非邻位二醇的反应。 含有卤素的衍生物，其中二醇的OH基被Cl，Br或I取代; 二醇的酯衍生物; 和二醇的环醚衍生物; 在催化剂组合物存在下，一氧化碳基本上包含铑或铱化合物和络合物，以及卤化物促进剂。
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公开(公告)号：US3989747A
公开(公告)日：1976-11-02
申请号：US473464
申请日：1974-05-28
IPC分类号： C07C51/14
CPC分类号： C07C51/14
摘要： The present invention relates to an improved one-step process for the preparation of propionic acid, specifically by the reaction of ethylene with carbon monoxide and water at mild pressure, in the presence of catalyst compositions essentially comprising critical proportions of rhodium components with a bromide promoter. Under these reaction conditions, the process is catalytic both with respect to the rhodium and the bromide components.
摘要翻译： 本发明涉及一种用于制备丙酸的改进的一步法，特别是在温和压力下乙烯与一氧化碳和水的反应，在催化剂组合物存在下，基本上包含临界比例的铑组分与溴化促进剂 。 在这些反应条件下，相对于铑和溴化物组分，该方法是催化的。
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公开(公告)号：US3989748A
公开(公告)日：1976-11-02
申请号：US473527
申请日：1974-05-28
IPC分类号： C07C51/14
CPC分类号： C07C51/14
摘要： The present invention relates to an improved one-step process for the preparation of propionic acid, specifically by the reaction of ethylene with carbon monoxide and water at mild pressure, in the presence of catalyst compositions essentially comprising critical proportions of iridium components with a bromide promoter. Under these reaction conditions, the process is catalytic both with respect to the iridium and the bromide components.
摘要翻译： 本发明涉及一种用于制备丙酸的改进的一步法，特别是在温和压力下乙烯与一氧化碳和水的反应，在催化剂组合物的存在下，基本上包括临界比例的铱组分与溴化促进剂 。 在这些反应条件下，相对于铱和溴化物组分，该方法是催化的。
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公开(公告)号：US06320071B1
公开(公告)日：2001-11-20
申请号：US09505833
申请日：2000-02-17
IPC分类号： C07F922
CPC分类号： C07F9/301
摘要： Processes for producing 2-carboxyalkyl(phenyl)phosphinic acid comprising hydrolyzing the reaction mixture produced from the reaction of dichloro(phenyl)phosphine with a carboxylic acid in the presence of water, wherein the hydrolysis is conducted with reduced levels of water.
摘要翻译： 制备2-羧基烷基（苯基）次膦酸的方法，包括在水存在下水解由二氯（苯基）膦与羧酸的反应产生的反应混合物，其中水解以水的水平降低进行。
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8.发明授权
公开(公告)号：US4733006A
公开(公告)日：1988-03-22
申请号：US524508
申请日：1983-08-18
摘要： The present invention provides for an improved process wherein an olefin, an alcohol, or an ester, halide or ether derivative of said alcohol is reacted with carbon monoxide in a liquid phase in the presence of a catalyst system that contains (a) a rhodium component, and (b) and iodine or bromine component. By passing at least a portion of the liquid reaction mass from the reaction zone to a separation zone of substantially lower CO partial pressure, at least a portion of the carbonylation products, as well as unreacted carbon monoxide, inert gases and unreacted olefin, alcohol or alcohol derivatives are vaporized and can be withdrawn from the separation zone. Precipitation of the rhodium catalyst under carbon monoxide deficient conditions is prevented or retarded by addition to the carbon monoxide deficient zones of the system of a catalyst stabilizer which is a germanium (IV) compound, an alkali metal compound, and mixtures thereof.
摘要翻译： 本发明提供了一种改进的方法，其中所述醇的烯烃，醇或酯，卤化物或醚衍生物在液相中与一氧化碳在催化剂体系存在下反应，所述催化剂体系含有（a）铑组分 ，和（b）和碘或溴成分。 通过将至少一部分液体反应物质从反应区通过至基本上较低的CO分压的分离区，至少部分羰基化产物，以及未反应的一氧化碳，惰性气体和未反应的烯烃，醇或 醇衍生物被蒸发并且可以从分离区中取出。 通过加入作为锗（IV）化合物，碱金属化合物及其混合物的催化剂稳定剂体系的一氧化碳缺乏区域来防止或延缓在一氧化碳缺乏条件下铑催化剂的沉淀。
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公开(公告)号：US4433166A
公开(公告)日：1984-02-21
申请号：US221231
申请日：1980-12-29
摘要： The present invention provides for an improved process wherein an olefin, an alcohol, or an ester, halide or ether derivative of said alcohol is reacted with carbon monoxide in a liquid phase in the presence of a catalyst system containing a rhodium component and an iodine or bromine component. By passing at least a portion of the liquid reaction mass from the reaction zone to a separation zone of substantially lower CO partial pressure, at least a portion of the carbonylation products, as well as unreacted carbon monoxide, inert gases, and unreacted olefin, alcohol, or alcohol derivatives are vaporized and can be withdrawn from the separation zone. Precipitation of the rhodium catalyst under carbon monoxide deficient conditions is prevented or retarded by addition to the system of a stabilizer which is a tin component which may be tin or a tin compound.
摘要翻译： 本发明提供一种改进的方法，其中所述醇的烯烃，醇或酯，卤化物或醚衍生物在含有铑组分和碘的催化剂体系存在下在液相中与一氧化碳反应，或 溴成分。 通过将至少一部分液体反应物质从反应区通过至基本上较低的CO分压的分离区，至少部分羰基化产物，以及未反应的一氧化碳，惰性气体和未反应的烯烃，醇 ，或醇衍生物蒸发，并可从分离区取出。 在一氧化碳缺乏条件下铑催化剂的沉淀通过添加到可以是锡或锡化合物的锡组分的稳定剂体系中来防止或延迟。
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公开(公告)号：US5844028A
公开(公告)日：1998-12-01
申请号：US961278
申请日：1997-10-30
申请人： Frank E. Paulik
发明人： Frank E. Paulik
IPC分类号： C07F9/6571 , C08K5/5357 , C08K5/49 , C07F9/02
CPC分类号： C07F9/657181 , C08K5/5357
摘要： Certain (1,3,2-dioxaphosphorinanemethan) amine compounds, which are useful as flame retardant compounds, are disclosed. The compounds are particularly useful in polyurethane compositions.
摘要翻译： 公开了可用作阻燃化合物的某些（1,3,2-二氧杂磷杂环丁烷）胺化合物。 该化合物在聚氨酯组合物中特别有用。
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