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11 条记录 (耗时 0.026 秒)

    Levelling agent and anti-cratering agent
    1.
    发明授权
    Levelling agent and anti-cratering agent 有权

    公开(公告)号：US07173084B2

    公开(公告)日：2007-02-06

    申请号：US10491814

    申请日：2002-10-08

    申请人： Frank Oliver Heinrich Pirrung ,  Elizabeth Maaike Loen ,  Lothar Alexander Engelbrecht ,  Arend Noordam

    发明人： Frank Oliver Heinrich Pirrung ,  Elizabeth Maaike Loen ,  Lothar Alexander Engelbrecht ,  Arend Noordam

    IPC分类号： C08F18/20

    CPC分类号： C09D11/03 ,  C08F22/18 ,  C08F22/20 ,  C09D7/47 ,  C09D7/65

    摘要： Use of a polymer as a levelling agent or anti-cratering agent, said polymer comprising at least one fluorinated unit represented by formula 1, (Formula 1) wherein R?1 is a moiety represented by Cn?F2n+1?-(CH2?)m?-, ΛCn?F2n?-(CH2?)m?-, Cn?F2n+1?-(CII2?)m?-(OCII2?CIIR?5)p?-, ΛCn?F2n?-(CH2?m?-(OCH2?CHR?5)p′? Cn?F2n+1?-(CII2?)m?-X-, ACn?F2n?-(CII2?)m?-X-ΛCn?F2n?-(CH2?)m?-(OCH2?CHR?5)p?-X or Cn?F2n+1?-(CII2?)m?-(OCII2?CIIR?5)p?-X-; wherein A=H, Cl, Br, I, a C1–12? alkyl or a OC1–12 ?alkyl, wherein 4≦n≦20,0≦m˜≦4 and 0≦p≦20, wherein X is a spacer moiety selected from the group consisting of esters, amides, sulphoamides, mercapto groups, poltyurethane groups and alkyl groups, wherein R?2, is H, a metal moiety, an (alkyl)ammonium moiety or an alkyl group, Cn?F2n+1?-(CII2?)m?-, ACn?F2n?-(CII2?)m?-, Cn?F2n+1?-(CII2?)m?-(OCII2?CIIR?5)p?-, ΛCn?F2n?-(CH2?)m?-(OCH2?CHR?5)p′? Cn?F2n+1?-(CH2?)m?-X-, ΛCn?F2n?-(CH2?)m?-X-, ACn?F2n?-(CH2?)m?-(OCH2?CHR?5)p?-X or Cn?F2n+1?-(CH2?)m?-(OCH2?CHR?5)p?-X-; wherein A=H, Cl, Br, I, C1–12? alkyl or OC1-12 alkyl, wherein 4≦n≦20, 0≦m≦4 and 0≦p≦20, wherein X is a spacer moiety selected from the group consisting of esters, amides, sulphoamides, mercapto groups, polyurethane groups and alkyl groups, wherein R?3 and R?4 are independently selected from the group consisting of H, alkyl-groups and phenyl-groups and wherein R?5 is H and/or methyl group.

    Phosphoric acid esters and their use as wetting and dispersing agent
    2.
    发明授权
    Phosphoric acid esters and their use as wetting and dispersing agent 有权
    磷酸酯及其作为润湿分散剂的用途

    公开(公告)号：US07595416B2

    公开(公告)日：2009-09-29

    申请号：US10590467

    申请日：2005-02-28

    申请人： Frank Oliver Heinrich Pirrung ,  Arend Noordam ,  Petrus Johannes Harbers ,  Elizabeth Maaike Loen ,  Arona Eliane Munneke

    发明人： Frank Oliver Heinrich Pirrung ,  Arend Noordam ,  Petrus Johannes Harbers ,  Elizabeth Maaike Loen ,  Arona Eliane Munneke

    IPC分类号： C07F9/02

    CPC分类号： C08K5/521 ,  C09D7/45 ,  C09D11/03

    摘要： The invention relates to a phosphoric acid ester and salts thereof of the general formula (I), wherein A is a monohydroxyl residue derived from C1-C20-alkyl-(AO)x-OH or Acyl-(AO)x-OH; or C1-C20-alkyl-(AO)x-(HA)y-OH or Acyl-(AO)x-(HA)y-OH; or C1-C20-alkyl-(AO)x-(AA-AO)y-OH or Acyl-(AO)x-(AA-AO)y-OH; or MO-(HA)y-OH or MO-(AA-AO)y-OH; wherein Acyl is an aromatic carboxylic acid residue or a saturated or unsaturated fatty acid residue; AO is a polyC2-C4alkyleneglycol residue, HA is a hydroxycarboxylic acid or a lactone thereof, AA is a dicarboxylic acid, MO is a monoalcohol, x is 1 to 250, y is 1 to 250, B is a mono-, di-, or tri- or polyhydroxy di-, tri or multi-carboxylic acid residue which is linked via the hydroxy group to the phosphoric acid and via one of the carboxylic acid groups to the monohydroxyl residue [A], the remaining carboxyl acid group(s) is/are free or is/are esterified with a further monohydroxyl residue [A], resulting in branched esters; n is 1-2; m is 1-4. The phosphoric acid esters are used as wetting agent or dispersants.

    摘要翻译： 本发明涉及通式（I）的磷酸酯及其盐，其中A为衍生自C1-C20烷基 - （AO）x-OH或酰基 - （AO）x-OH的单羟基残基; 或C 1 -C 20烷基 - （AO）x - （HA）y -OH或酰基 - （AO）x-（HA）y -OH; 或（C 1 -C 20 - 烷基 - （AO）x - （AA-AO）y -OH或酰基 - （AO）x-（AA-AO）y -OH） 或MO-（HA）y-OH或MO-（AA-AO）y-OH; 其中酰基是芳族羧酸残基或饱和或不饱和脂肪酸残基; AO是聚C 2 -C 4亚烷基二醇残基，HA是羟基羧酸或其内酯，AA是二羧酸，MO是一​​元醇，x是1至250，y是1至250，B是单，二， 或通过羟基与磷酸连接并经由一个羧酸基团与单羟基残基[A]连接的三元或多羟基二，三或多羧酸残基，剩余的羧酸基团， 与另一个单羟基残基[A]自由或被酯化，得到支链酯; n为1-2; m为1-4。 磷酸酯用作润湿剂或分散剂。

    Phosphoric Acid Esters and Their Use as Wetting and Dispersing Agent
    5.
    发明申请
    Phosphoric Acid Esters and Their Use as Wetting and Dispersing Agent 有权
    磷酸酯及其用作润湿分散剂

    公开(公告)号：US20070293692A1

    公开(公告)日：2007-12-20

    申请号：US10590467

    申请日：2005-02-28

    申请人： Frank Oliver Heinrich Pirrung ,  Arend Noordam ,  Petrus Harbers ,  Elizabeth Loen ,  Aron Munneke

    发明人： Frank Oliver Heinrich Pirrung ,  Arend Noordam ,  Petrus Harbers ,  Elizabeth Loen ,  Aron Munneke

    IPC分类号： C07F9/09

    CPC分类号： C08K5/521 ,  C09D7/45 ,  C09D11/03

    摘要： The invention relates to a phosphoric acid ester and salts thereof of the general formula (I), wherein A is a monohydroxyl residue derived from C1-C20-alkyl-(AO)x-OH or Acyl-(AO)x-OH; or C1-C20-alkyl-(AO)x-(HA)y-OH or Acyl-(AO)x-(HA)y-OH; or C1-C20-alkyl-(AO)x-(AA-AO)y-OH or Acyl-(AO)x-(AA-AO)y-OH; or MO-(HA)y-OH or MO-(AA-AO)y-OH; wherein Acyl is an aromatic carboxylic acid residue or a saturated or unsaturated fatty acid residue; AO is a polyC2-C4alkyleneglycol residue, HA is a hydroxycarboxylic acid or a lactone thereof, AA is a dicarboxylic acid, MO is a monoalcohol, x is 1 to 250, y is 1 to 250, B is a mono-, di-, or tri- or polyhydroxy di-, tri or multi-carboxylic acid residue which is linked via the hydroxy group to the phosphoric acid and via one of the carboxylic acid groups to the monohydroxyl residue [A], the remaining carboxyl acid group(s) is/are free or is/are esterified with a further monohydroxyl residue [A], resulting in branched esters; n is 1-2; m is 1-4. The phosphoric acid esters are used as wetting agent or dispersants.

    摘要翻译： 本发明涉及通式（I）的磷酸酯及其盐，其中A是衍生自C 1 -C 20 - 烷基 - （ AO）x-OH或酰基 - （AO）x-OH; 或（C 1 -C 20） - 烷基 - （AO）x - （HA）y -OH或酰基 - （AO）x-（HA）y -OH; 或（C 1 -C 20） - （AO）x - （AA-AO）y -OH或酰基 - （AO）x-（AA-AO）y -哦; 或MO-（HA）y-OH或MO-（AA-AO）y-OH; 其中酰基是芳族羧酸残基或饱和或不饱和脂肪酸残基; AO是聚C 2 -C 4亚烷基二醇残基，HA是羟基羧酸或其内酯，AA是二羧酸，MO是一​​元醇，x是1至 250，y为1至250，B为单羟基，二 - 或三 - 或多羟基二 - ，三 - 或多羧酸残基，其通过羟基与磷酸和羧酸 单个羟基残基[A]，剩余的羧基基团与另外的单羟基残基[A]自由或被酯化，得到支链酯; n为1-2; m为1-4。 磷酸酯用作润湿剂或分散剂。

    Polymers obtained via nitroxyl radical polymerization
    6.
    发明授权
    Polymers obtained via nitroxyl radical polymerization 有权

    公开(公告)号：US07858694B2

    公开(公告)日：2010-12-28

    申请号：US11991113

    申请日：2006-08-21

    申请人： Lothar Alexander Engelbrecht ,  Arend Noordam

    发明人： Lothar Alexander Engelbrecht ,  Arend Noordam

    IPC分类号： C08L39/04 ,  C08L31/00 ,  C08F20/06 ,  C08F26/06

    CPC分类号： C08F220/40 ,  C08F2/38 ,  C08F4/00 ,  C08F293/005 ,  C08F2438/02

    摘要： Polymer of formula (I): In-[(A)x-(B)y-(A′)x′-(E)z]n obtained by nitroxyl mediated controlled free radical polymerization whereby an access of acrylate is present, wherein In is the initiator fragment starting the polymerization reaction; A and A′ are the same or different monomers selected from the group consisting of acrylic acid, methacrylic acid, acrylonitrile, methacrylonitrile, acrylic acid (C1-C22)alkyl esters, acrylic acid (C1-C22)hydroxyalkyl esters, methacrylic acid (C1-C22)alkyl esters, methacrylic acid (C1-C22)hydroxyalkyl esters, acrylic acid (C1-C22)alkyl esters or methacrylic acid (C1-C22)alkyl esters which are substituted by amino, (C1-C22)alkylamino, (C1-C22)dialkylamino, —SO3H, epoxy, fluoro, perfluoro or siloxane groups, styrene, substituted styrene, acrylamide and methacrylamide, N-mono(C1-C22)alkyl acrylamide, N,N-di(C1-C22)alkyl acrylamide; provided that the amount of unsubstituted acrylic acid (C1-C22)alkyl esters or/and methacrylic acid (C1-C22)alkyl esters is more than 30% by weight based on the weight of the total monomer mixture; and B is at least one multifunctional monomer with two or more ethylenically unsaturated bonds with the proviso than at least one of these ethylenically unsaturated bonds is a high reactive double bond and the other or the others are less reactive double or triple bonds. E is a group bearing at least one stable free nitroxyl radical, which is bound via the oxygen atom to the polymer or copolymer; or a group which results from a substitution or elimination reaction of the attached stable free nitroxyl radical; x and x′ independently is zero or a number between 5 to 5000; y is a number between 5 to 5000; z is a number 1 or greater than 1 indicating the average number of end groups E attached to the monomer sequence (A)x-(B)y; preferably z is 1; n is a number from 1 to 20, preferably 1.

    Polymers obtained via nitroxyl radical polymerization
    9.
    发明申请
    Polymers obtained via nitroxyl radical polymerization 有权

    公开(公告)号：US20090088518A1

    公开(公告)日：2009-04-02

    申请号：US11991113

    申请日：2006-08-21

    申请人： Lothar Alexander Engelbrecht ,  Arend Noordam

    发明人： Lothar Alexander Engelbrecht ,  Arend Noordam

    IPC分类号： C08L39/04 ,  C08F20/06 ,  C08F26/06 ,  C08L31/00

    CPC分类号： C08F220/40 ,  C08F2/38 ,  C08F4/00 ,  C08F293/005 ,  C08F2438/02

    摘要： Polymer of formula (I): In—[(A)x—(B)y—(A′)x′—(E)z]n obtained by nitroxyl mediated controlled free radical polymerization whereby an access of acrylate is present, wherein In is the initiator fragment starting the polymerisation reaction; A and A′ are the same or different monomers selected from the group consisting of acrylic acid, methacrylic acid, acrylonitrile, methacrylonitrile, acrylic acid (C1-C22)alkyl esters, acrylic acid (C1-C22)hydroxyalkyl esters, methacrylic acid (C1-C22)alkyl esters, methacrylic acid (C1-C22)hydroxyalkyl esters, acrylic acid (C1-C22)alkyl esters or methacrylic acid (C1-C22)alkyl esters which are substituted by amino, (C1-C22)alkylamino, (C1-C22)dialkylamino, —SO3H, epoxy, fluoro, perfluoro or siloxane groups, styrene, substituted styrene, acrylamide and methacrylamide, N-mono(C1-C22)alkyl acrylamide, N,N-di(C1-C22)alkyl acrylamide; provided that the amount of unsubstituted acrylic acid (C1-C22)alkyl esters or/and methacrylic acid (C1-C22)alkyl esters is more than 30% by weight based on the weight of the total monomer mixture; and B is at least one multifunctional monomer with two or more ethylenically unsaturated bonds with the proviso than at least one of these ethylenically unsaturated bonds is a high reactive double bond and the other or the others are less reactive double or triple bonds. E is a group bearing at least one stable free nitroxyl radical, which is bound via the oxygen atom to the polymer or copolymer; or a group which results from a substitution or elimination reaction of the attached stable free nitroxyl radical; x and x′ independently is zero or a number between 5 to 5000; y is a number between 5 to 5000; z is a number 1 or greater than 1 indicating the average number of end groups E attached to the monomer sequence (A)x—(B)y; preferably z is 1; n is a number from 1 to 20, preferably 1.

    2-Hydroxypropane sulphonic acid derivatives: their preparation and curable compositions thereof
    10.
    发明授权
    2-Hydroxypropane sulphonic acid derivatives: their preparation and curable compositions thereof 失效
    2-羟基丙磺酸衍生物：其制备方法和可固化组合物

    公开(公告)号：US4514547A

    公开(公告)日：1985-04-30

    申请号：US489435

    申请日：1983-04-28

    申请人： Arend Noordam

    发明人： Arend Noordam

    IPC分类号： B01D21/18 ,  C07C67/00 ,  C07C301/00 ,  C07C303/02 ,  C07C303/32 ,  C07C309/08 ,  C07C309/09 ,  C08G59/00 ,  C08G59/14 ,  C08K5/42 ,  C08L63/02 ,  C09D163/00

    CPC分类号： C07C309/00 ,  C08G59/1411 ,  C08K5/42

    摘要： The invention provides 2-hydroxypropane sulphonic acid derivatives of general formula ##STR1## wherein n is a number having an average value from 0 to 12, .circle.A denotes saturation or aromatic unsaturation in an associated carbocyclic ring and the or each of the R.sup.1 and R.sup.2 groups are independently selected from hydrogen and C.sub.1-12 alkyl groups provided that each --C(R.sup.1)(R.sup.2)-- group contains not more than 13 carbon atoms; and salts thereof; a process for their preparation and curable compositions containing them.

    摘要翻译： 本发明提供了通式为（I）的图像的2-羟基丙烷磺酸衍生物，其中n是平均值为0至12的数，并且A表示相关碳环中的饱和或不饱和度， 每个R 1和R 2基团独立地选自氢和C 1-12烷基，条件是每个-C（R 1）（R 2） - 基团含有不超过13个碳原子; 及其盐; 其制备方法和含有它们的可固化组合物。