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1.发明授权
公开(公告)号：US4380616A
公开(公告)日：1983-04-19
申请号：US263647
申请日：1981-05-14
CPC分类号： C08F10/00 , Y10S526/907
摘要： Olefins are polymerized in the presence of chromium-containing catalysts which have been improved by depositing the chromium onto the inorganic oxide support in the vapor phase rather than as an inorganic or organic compound. The resulting polymers exhibit a higher molecular weight as compared to those polymers prepared in the presence of such chromium-containing catalysts prepared in the conventional manner.
摘要翻译： 烯烃在含铬催化剂的存在下聚合，其通过将铬沉积在气相中的无机氧化物载体上而不是无机或有机化合物而得到改善。 与在常规方法制备的这种含铬催化剂存在下制备的聚合物相比，所得聚合物显示出更高的分子量。
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公开(公告)号：US4362654A
公开(公告)日：1982-12-07
申请号：US263642
申请日：1981-05-14
摘要： Inorganic oxide supported chromium-containing catalysts are improved by depositing the chromium onto the inorganic oxide support in the vapor phase rather than as an inorganic or organic compound. Polymers resulting from polymerizing one or more .alpha.-olefins in the presence of such catalysts exhibit a higher molecular weight as compared to those polymers prepared in the presence of such chromium-containing catalysts prepared in the conventional manner.
摘要翻译： 无机氧化物负载的含铬催化剂通过将铬沉积在气相中的无机氧化物载体上而不是无机或有机化合物而得到改善。 与在常规方法制备的这种含铬催化剂存在下制备的那些聚合物相比，在这种催化剂存在下聚合一种或多种α-烯烃产生的聚合物表现出较高的分子量。
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公开(公告)号：US4285834A
公开(公告)日：1981-08-25
申请号：US108896
申请日：1979-12-31
CPC分类号： C08F10/00
摘要： A catalyst mixture containing at least two independently supported catalysts, at least one of which is an inorganic halide supported titanium and/or vanadium Ziegler type catalyst and at least one other is an inorganic oxide supported, chromium catalyst.These catalyst mixtures are suitable for polymerizing one or more .alpha.-olefins.
摘要翻译： 一种催化剂混合物，其含有至少两种独立负载的催化剂，其中至少一种是无机卤化物负载的钛和/或钒齐格勒型催化剂，至少另一种是无机氧化物担载的铬催化剂。 这些催化剂混合物适用于聚合一种或多种α-烯烃。
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公开(公告)号：US4204050A
公开(公告)日：1980-05-20
申请号：US959287
申请日：1978-11-09
CPC分类号： C08F10/00
摘要： .alpha.-olefins are polymerized with a catalyst prepared from (1) an inert support, (2) the reaction product of a tetravalent hydrocarbyloxy titanium halide such as di-n-butoxy titanium dichloride and hexavalent chromium oxide and (3) an organometal activating agent such as a tri alkyl aluminum.
摘要翻译： α-烯烃与由（1）惰性载体制备的催化剂聚合，（2）四价烃氧基卤化钛如二正丁氧基二氯化钛和六价铬氧化物的反应产物和（3）有机金属活化剂 例如三烷基铝。
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5.发明授权Organo zirconium-chromium compound, catalyst prepared therefrom and polymerization of olefins therewith 失效有机锆 - 铬化合物，由其制备的催化剂和烯烃的聚合
公开(公告)号：US4376065A
公开(公告)日：1983-03-08
申请号：US269232
申请日：1981-06-01
CPC分类号： C08F10/00
摘要： Dual transition metal compounds containing zirconium and chromium are prepared by reacting a tetrahydrocarbyloxy zirconium compound such as tetraisopropoxy zirconium or a tetravalent hydrocarbyloxy zirconium halide such as triisopropoxy zirconium halide with a chromium compound such as CrO.sub.3. These compounds, as well as combinations of other soluble chromium and zirconium compounds, are useful in the polymerization of .alpha.-olefins to produce polymers having a high molecular weight and a narrow molecular weight distribution.
摘要翻译： 通过四异丙氧基锆化合物如四异丙氧基锆或四异丙氧基锆卤化物如三异丙氧基卤化锆与铬化合物如CrO 3反应制备含锆和铬的双过渡金属化合物。 这些化合物以及其它可溶性铬和锆化合物的组合可用于α-烯烃的聚合以产生具有高分子量和窄分子量分布的聚合物。
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公开(公告)号：US4263422A
公开(公告)日：1981-04-21
申请号：US108721
申请日：1979-12-31
CPC分类号： C08F10/00 , C08F10/02 , C08F16/00 , C08F110/02
摘要： Alpha-olefins are polymerized in the presence of at least two independently supported catalysts, one of which is an inorganic halide supported titanium and/or vanadium Ziegler type catalyst and at least one other is inorganic oxide supported, chromium catalyst. This dual catalyst increases catalyst efficiency and/or provides more flexible control of the properties of the resulting polymers.
摘要翻译： α-烯烃在至少两种独立负载的催化剂存在下聚合，其中一种是无机卤化物负载的钛和/或钒齐格勒型催化剂，至少另外一种是无机氧化物担载的铬催化剂。 这种双重催化剂提高催化剂效率和/或提供对所得聚合物的性质的更灵活的控制。
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7.发明授权Organo titanium chromium compound, catalyst prepared therefrom and polymerization of olefins therewith 失效有机钛铬化合物，由其制备的催化剂和烯烃的聚合
公开(公告)号：US4321159A
公开(公告)日：1982-03-23
申请号：US959538
申请日：1978-11-13
CPC分类号： C08F10/00
摘要： Dual transition metal compounds containing titanium and chromium are prepared by reacting a hydrocarbyloxy titanium halide with CrO.sub.3. The compounds are useful in catalysts for the polymerization of .alpha.-olefins.
摘要翻译： 通过使烃氧基卤化钛与CrO 3反应制备含有钛和铬的双过渡金属化合物。 该化合物可用于α-烯烃聚合的催化剂。
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