Late addition to effect compositional modifications in condensation polymers
    1.
    发明申请
    Late addition to effect compositional modifications in condensation polymers 有权
    延迟缩合聚合物的组合改性

    公开(公告)号:US20070066792A1

    公开(公告)日:2007-03-22

    申请号:US11500800

    申请日:2006-08-08

    IPC分类号: C08G63/02

    摘要: A process for preparing modified polymer by withdrawing a slip stream of polymer melt from the discharge line of a continuous polymerization reactor, admixing in a highly modified polymeric additive into the polymer melt within the slip stream, then introducing the modifier containing slip stream late in the manufacturing process prior to the slip stream withdrawal point. The improved processes of the invention have particular utility for large-scale, continuous reactor where transitions and short production runs are economically prohibitive thereby limiting the product breath. The process is particularly suited for producing a family of copolyesters using a continuous melt phase production process.

    摘要翻译: 通过从连续聚合反应器的排出管中取出聚合物熔体的滑流来混合改性聚合物的方法,将高度改性的聚合物添加剂混合到滑流内的聚合物熔体中,然后将含有滑流的改性剂在 在滑流提取点之前的制造过程。 本发明的改进方法对于大规模的连续反应器具有特别的用途,其中过渡和短的生产运行在经济上是禁止的,从而限制了产品的呼吸。 该方法特别适用于使用连续熔融相制备方法生产一系列共聚酯。

    Aluminum containing polyester polymers having low acetaldehyde generation rates
    3.
    发明申请
    Aluminum containing polyester polymers having low acetaldehyde generation rates 有权
    含铝聚酯聚合物具有低乙醛生成速率

    公开(公告)号:US20070066791A1

    公开(公告)日:2007-03-22

    申请号:US11495431

    申请日:2006-07-28

    IPC分类号: C08G63/02

    摘要: A polyester polymer composition containing polyester polymers such as polymers having repeating ethylene terephthalate units, aluminum atoms in an amount of at least 3 ppm based on the weight of the polymer, the polyester polymers having an It.V. of at least 0.72 dL/g obtained through a melt phase polymerization and a residual acetaldehyde level of 10 ppm or less. Also provided are polyester polymer compositions containing polyester polymers and: (i) aluminum atoms (ii) alkaline earth metal atoms or alkali metal atoms or alkali compound residues, and (iii) a catalyst deactivator such as a phosphorus compound. The phosphorus compound is added to the polyester melt either late in the polycondensation or upon remelting a solid polyester polymer. The polyester polymer exhibits good L* brightness, clarity, and low levels of acetaldehyde generated upon melting.

    摘要翻译: 一种聚酯聚合物组合物,其包含聚酯聚合物,例如具有重复的对苯二甲酸乙二醇酯单元的聚合物,铝原子的量基于聚合物的重量为至少3ppm,聚酯聚合物具有It.V. 通过熔融相聚合获得的至少0.72dL / g,残余乙醛水平为10ppm以下。 还提供了含有聚酯聚合物的聚酯聚合物组合物,和:(i)铝原子(ii)碱土金属原子或碱金属原子或碱性化合物残基,和(iii)催化剂失活剂如磷化合物。 在缩聚后期或重熔固体聚酯聚合物时,将磷化合物加入到聚酯熔体中。 聚酯聚合物在熔化时表现出良好的L *亮度,透明度和低水平的乙醛。

    Material processing system through an injection nozzle
    4.
    发明申请
    Material processing system through an injection nozzle 审中-公开
    材料加工系统通过喷嘴

    公开(公告)号:US20070264435A1

    公开(公告)日:2007-11-15

    申请号:US11431239

    申请日:2006-05-10

    IPC分类号: B05D1/02

    CPC分类号: B01J4/00 B01J19/26

    摘要: A material-processing system includes a material processor configured to discharge a first material. Additionally, the material-processing system may include a passage, and the material-processing system may be configured to direct at least a portion of the first material discharged from the material processor through the passage. The material-processing system may also include a nozzle having an outlet in fluid communication with the passage. The material-processing system may also include a fluid-supply system configured to direct a fluid additive through the nozzle into the passage. Additionally, the nozzle may be insulated in a manner that slows heat transfer to the nozzle from the first material or the fluid additive.

    摘要翻译: 材料处理系统包括配置成排出第一材料的材料处理器。 另外,材料处理系统可以包括通道,并且材料处理系统可以被配置为引导从材料处理器排出的第一材料的至少一部分通过通道。 材料处理系统还可以包括具有与通道流体连通的出口的喷嘴。 材料处理系统还可以包括配置成将流体添加剂通过喷嘴引导到通道中的流体供应系统。 另外,喷嘴可以以减慢从第一材料或流体添加剂到喷嘴的热传递的方式被绝缘。

    Aluminum containing polyester polymers having low acetaldehyde generation rates
    5.
    发明授权
    Aluminum containing polyester polymers having low acetaldehyde generation rates 有权
    含铝聚酯聚合物具有低乙醛生成速率

    公开(公告)号:US07932345B2

    公开(公告)日:2011-04-26

    申请号:US11495431

    申请日:2006-07-28

    IPC分类号: C08G63/02 C08G64/00

    摘要: A polyester polymer composition containing polyester polymers such as polymers having repeating ethylene terephthalate units, aluminum atoms in an amount of at least 3 ppm based on the weight of the polymer, the polyester polymers having an It.V. of at least 0.72 dL/g obtained through a melt phase polymerization and a residual acetaldehyde level of 10 ppm or less. Also provided are polyester polymer compositions containing polyester polymers and: (i) aluminum atoms (ii) alkaline earth metal atoms or alkali metal atoms or alkali compound residues, and (iii) a catalyst deactivator such as a phosphorus compound. The phosphorus compound is added to the polyester melt either late in the polycondensation or upon remelting a solid polyester polymer. The polyester polymer exhibits good L* brightness, clarity, and low levels of acetaldehyde generated upon melting.

    摘要翻译: 一种聚酯聚合物组合物,其包含聚酯聚合物,例如具有重复的对苯二甲酸乙二醇酯单元的聚合物,铝原子的量基于聚合物的重量为至少3ppm,聚酯聚合物具有It.V. 通过熔融相聚合获得的至少0.72dL / g,残余乙醛水平为10ppm以下。 还提供了含有聚酯聚合物的聚酯聚合物组合物,和:(i)铝原子(ii)碱土金属原子或碱金属原子或碱性化合物残基,和(iii)催化剂失活剂如磷化合物。 在缩聚后期或重熔固体聚酯聚合物时,将磷化合物加入到聚酯熔体中。 聚酯聚合物在熔化时表现出良好的L *亮度,透明度和低水平的乙醛。