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公开(公告)号:US20180366738A1
公开(公告)日:2018-12-20
申请号:US15625579
申请日:2017-06-16
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Nagappan Ramaswamy , Ellazar V. Niangar , Balasubramanian Lakshmanan
Abstract: Systems and methods of the present disclosure include supplying a porous substrate, heating the porous substrate to produce a pre-heated substrate, applying an electrode ink to the pre-heated substrate to produce a coated substrate, and drying the electrode ink of the coated substrate to produce an electrode on the porous substrate. The pre-heated substrate has a temperature greater than 23° C. The applying occurs via a coating mechanism. The electrode ink includes a catalyst and an ionomer dispersed in a solvent. The drying occurs via a drying mechanism.
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公开(公告)号:US20230223552A1
公开(公告)日:2023-07-13
申请号:US17573089
申请日:2022-01-11
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Nagappan Ramaswamy , Roland J. Koestner , Swaminatha P. Kumaraguru
CPC classification number: H01M4/8657 , H01M4/8885 , H01M4/8828 , H01M4/8663 , H01M2004/8689
Abstract: A cathode configured for use within a fuel cell system is provided. The cathode includes a cathode substrate. The cathode further includes a coating disposed upon the cathode substrate and including a fluorocarbon polymer additive configured for sintering at a temperature of less than 200° C. The fluorocarbon polymer additive may be mixed with a catalyst ink coating or may be applied separately as a topcoat layer.
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公开(公告)号:US10784527B2
公开(公告)日:2020-09-22
申请号:US15846777
申请日:2017-12-19
Applicant: GM Global Technology Operations LLC
Inventor: Swaminatha P. Kumaraguru , Jingxin Zhang , Nagappan Ramaswamy , Pinkhas A. Rapaport
IPC: H01M8/04828 , H01M8/04119 , H01M8/1004 , H01M8/04537 , H01M8/04858 , H01M8/04223 , H01M8/0432 , H01M8/043 , H01M8/1018
Abstract: A controller-executed method for conditioning a membrane electrode assembly (MEA) in a fuel cell for use in a fuel cell stack includes humidifying a fuel inlet to the stack to a threshold relative humidity level, and maintaining a current density and cell voltage of the fuel cell at a calibrated current density level and hold voltage level, respectively, via the controller in at least one voltage recovery stage. The recovery stage has a predetermined voltage recovery duration. The method includes measuring the cell voltage after completing the predetermined voltage recovery duration, and executing a control action with respect to the fuel cell or fuel cell stack responsive to the measured cell voltage exceeding a target voltage, including recording a diagnostic code via the controller indicative of successful conditioning of the MEA. A fuel cell system includes the fuel cell stack and controller.
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公开(公告)号:US10158128B2
公开(公告)日:2018-12-18
申请号:US15451893
申请日:2017-03-07
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Jingxin Zhang , Nagappan Ramaswamy , Balasubramanian Lakshmanan , Swaminatha P. Kumaraguru
IPC: H01M8/04 , H01M8/04119 , H01M8/04828 , H01M8/04223 , H01M8/04225 , H01M8/04302
Abstract: Disclosed are fuel cell stack break-in procedures, conditioning systems for performing break-in procedures, and motor vehicles with a fuel cell stack conditioned in accordance with disclosed break-in procedures. A break-in method is disclosed for conditioning a membrane assembly of a fuel cell stack. The method includes transmitting humidified hydrogen to the anode of the membrane assembly, and transmitting deionized water to the cathode of the membrane assembly. An electric current and voltage cycle are applied across the fuel cell stack while the fuel cell stack is operated in a hydrogen pumping mode until the fuel cell stack is determined to operate at a predetermined threshold for a fuel cell stack voltage output capability. During hydrogen pumping, the membrane assembly oxidizes the humidified hydrogen, transports protons from the anode to the cathode across the proton conducting membrane, and regenerates the protons in the cathode through a hydrogen evolution reaction.
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公开(公告)号:US20190280307A1
公开(公告)日:2019-09-12
申请号:US15915846
申请日:2018-03-08
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Nagappan Ramaswamy , Timothy Fuller , Swaminatha Kumaraguru
IPC: H01M4/86 , H01M8/1018 , H01M8/0258 , H01M8/1004 , H01M4/88 , H01M4/92
Abstract: A polymer electrolyte membrane fuel cell includes a proton-conductive polymer electrolyte membrane, an anode catalyst layer overlying a first face of the polymer electrolyte membrane, and a cathode catalyst layer overlying a second face of the polymer electrolyte membrane. At least one of the anode catalyst layer or the cathode catalyst layer includes a composite electrode layer that comprises a colloidal or soluble ionomer binder component, a catalyst dispersed along with the colloidal or soluble ionomer binder component, and insoluble ionomer nanofibers disseminated throughout a thickness of the composite electrode layer. The presence of the insoluble ionomer nanofibers within the composite electrode layer may enhance the voltage performance of the fuel cell, particularly at high current densities and/or low relative humidity operating conditions. A method of making a composite electrode layer for a polymer electrolyte membrane fuel cell is also disclosed.
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公开(公告)号:US20190190040A1
公开(公告)日:2019-06-20
申请号:US15846777
申请日:2017-12-19
Applicant: GM Global Technology Operations LLC
Inventor: Swaminatha P. Kumaraguru , Jingxin Zhang , Nagappan Ramaswamy , Pinkhas A. Rapaport
IPC: H01M8/04828 , H01M8/04119 , H01M8/04537 , H01M8/1004
Abstract: A controller-executed method for conditioning a membrane electrode assembly (MEA) in a fuel cell for use in a fuel cell stack includes humidifying a fuel inlet to the stack to a threshold relative humidity level, and maintaining a current density and cell voltage of the fuel cell at a calibrated current density level and hold voltage level, respectively, via the controller in at least one voltage recovery stage. The recovery stage has a predetermined voltage recovery duration. The method includes measuring the cell voltage after completing the predetermined voltage recovery duration, and executing a control action with respect to the fuel cell or fuel cell stack responsive to the measured cell voltage exceeding a target voltage, including recording a diagnostic code via the controller indicative of successful conditioning of the MEA. A fuel cell system includes the fuel cell stack and controller.
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公开(公告)号:US20180261858A1
公开(公告)日:2018-09-13
申请号:US15451893
申请日:2017-03-07
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Jingxin Zhang , Nagappan Ramaswamy , Balasubramanian Lakshmanan , Swaminatha P. Kumaraguru
IPC: H01M8/04119 , H01M8/04828
CPC classification number: H01M8/04141 , H01M8/04223 , H01M8/04225 , H01M8/04302 , H01M8/04835 , Y02P70/56
Abstract: Disclosed are fuel cell stack break-in procedures, conditioning systems for performing break-in procedures, and motor vehicles with a fuel cell stack conditioned in accordance with disclosed break-in procedures. A break-in method is disclosed for conditioning a membrane assembly of a fuel cell stack. The method includes transmitting humidified hydrogen to the anode of the membrane assembly, and transmitting deionized water to the cathode of the membrane assembly. An electric current and voltage cycle are applied across the fuel cell stack while the fuel cell stack is operated in a hydrogen pumping mode until the fuel cell stack is determined to operate at a predetermined threshold for a fuel cell stack voltage output capability. During hydrogen pumping, the membrane assembly oxidizes the humidified hydrogen, transports protons from the anode to the cathode across the proton conducting membrane, and regenerates the protons in the cathode through a hydrogen evolution reaction.
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公开(公告)号:US20240322191A1
公开(公告)日:2024-09-26
申请号:US18188668
申请日:2023-03-23
Applicant: GM Global Technology Operations LLC
Inventor: Nagappan Ramaswamy , Venkata Raviteja Yarlagadda , Nathan Mellott , Swaminatha P. Kumaraguru
CPC classification number: H01M4/926 , H01M4/8857 , H01M4/8882 , H01M2008/1095
Abstract: An electrode for a fuel cell system is provided. The electrode includes a carbon support. The carbon support includes carbon particles each functionalized with one or more sulfur and oxygen-containing moieties. Platinum-based catalyst particles are disposed on the carbon support. Ionomer is disposed on the carbon support. A weight ratio of the ionomer to the carbon support is about 0.4 or less.
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公开(公告)号:US11799088B2
公开(公告)日:2023-10-24
申请号:US17573089
申请日:2022-01-11
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Nagappan Ramaswamy , Roland J. Koestner , Swaminatha P. Kumaraguru
CPC classification number: H01M4/8657 , H01M4/8663 , H01M4/8828 , H01M4/8885 , H01M2004/8689
Abstract: A cathode configured for use within a fuel cell system is provided. The cathode includes a cathode substrate. The cathode further includes a coating disposed upon the cathode substrate and including a fluorocarbon polymer additive configured for sintering at a temperature of less than 200° C. The fluorocarbon polymer additive may be mixed with a catalyst ink coating or may be applied separately as a topcoat layer.
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公开(公告)号:US11302926B2
公开(公告)日:2022-04-12
申请号:US16552477
申请日:2019-08-27
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Nagappan Ramaswamy , Roland J. Koestner , Swaminatha P. Kumaraguru
Abstract: Systems, methods, fuel cells, and mixtures to inhibit ionomer permeation into porous substrates using a crosslinked ionomer are described. A method includes preparing an ionomer premix, mixing a crosslinking additive with the ionomer premix to thereby form a crosslinked-ionomer solution, and adding catalyst particles to the crosslinked-ionomer solution to produce a catalyst ink. The ionomer premix includes an ionomer dispersed within a solvent. The catalyst ink includes the catalyst particles distributed homogenously therethrough. The catalyst ink may be cast onto a porous substrate and dried to thereby form a catalyst layer for use in a fuel cell.
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