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1.发明申请ALIPHATIC DIOL-BASED POLYCARBONATES, METHOD OF MAKING, AND ARTICLES FORMED THEREFROM 有权基于二氧化硅的聚碳酸酯，其制备方法和形成的制品公开(公告)号：US20090105444A1
公开(公告)日：2009-04-23
申请号：US11874871
申请日：2007-10-18
IPC分类号： C08G64/04
CPC分类号： C08G64/0208 , C08G63/64 , C08G64/305
摘要： The above-described and other deficiencies of the art are met by a method of making a polycarbonate polymer comprising isosorbide carbonate units, comprising melt reacting a dihydroxy compound comprising an isosorbide of the general formula (2a): and an activated carbonate, in the presence of a catalyst consisting essentially of a sodium salt capable of providing a hydroxide ion, wherein the polycarbonate polymer comprises greater than or equal to 50 mol % isosorbide carbonate units, and wherein the polycarbonate polymer has a Mw of greater than or equal to about 40,000 g/mol as determined by gel-permeation chromatography relative to polystyrene standards. Polycarbonates comprising the isosorbide carbonate unit, including isosorbide homopolycarbonate and an isosorbide-based polyester-polycarbonate, are also disclosed, as are a thermoplastic composition and an article including the isosorbide-based polycarbonate polymer.
摘要翻译： 通过制备包含异山梨醇碳酸酯单元的聚碳酸酯聚合物的方法，包括使包含通式（2a）的异山梨醇的二羟基化合物与活化的碳酸酯在存在下熔融反应来实现本领域的上述和其它缺陷： 基本上由能够提供氢氧根离子的钠盐组成的催化剂，其中所述聚碳酸酯聚合物包含大于或等于50mol％的异山梨醇碳酸酯单元，并且其中所述聚碳酸酯聚合物具有大于或等于约40,000g / mol，通过凝胶渗透色谱法相对于聚苯乙烯标准物测定。 还公开了包含异山梨醇碳酸酯单元的聚碳酸酯，包括异山梨醇均聚碳酸酯和异山梨醇基聚酯 - 聚碳酸酯，热塑性组合物和包含异山梨醇基聚碳酸酯聚合物的制品也是如此。
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2.发明授权Aliphatic diol-based polycarbonates, method of making, and articles formed therefrom 有权脂肪族二醇类聚碳酸酯，制造方法和由其形成的制品公开(公告)号：US07807772B2
公开(公告)日：2010-10-05
申请号：US12646208
申请日：2009-12-23
CPC分类号： C08G64/0208 , C08G63/64 , C08G64/305
摘要： Disclosed herein is a copolymer comprising isosorbide carbonate units and a polysiloxane block, wherein the copolymer comprises greater than or equal to 50 mol % isosorbide carbonate units.
摘要翻译： 本文公开了包含异山梨醇碳酸酯单元和聚硅氧烷嵌段的共聚物，其中所述共聚物包含大于或等于50摩尔％的异山梨醇碳酸酯单元。
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3.发明申请ALIPHATIC DIOL-BASED POLYCARBONATES, METHOD OF MAKING, AND ARTICLES FORMED THEREFROM 有权基于二氧化硅的聚碳酸酯，其制备方法和形成的制品公开(公告)号：US20100120993A1
公开(公告)日：2010-05-13
申请号：US12646208
申请日：2009-12-23
IPC分类号： C08F283/12
CPC分类号： C08G64/0208 , C08G63/64 , C08G64/305
摘要： Disclosed herein is a copolymer comprising isosorbide carbonate units and a polysiloxane block, wherein the copolymer comprises greater than or equal to 50 mol % isosorbide carbonate units.
摘要翻译： 本文公开了包含异山梨醇碳酸酯单元和聚硅氧烷嵌段的共聚物，其中所述共聚物包含大于或等于50摩尔％的异山梨醇碳酸酯单元。
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4.发明授权Aliphatic diol-based polycarbonates, method of making, and articles formed therefrom 有权脂肪族二醇类聚碳酸酯，制造方法和由其形成的制品公开(公告)号：US07718755B2
公开(公告)日：2010-05-18
申请号：US11874871
申请日：2007-10-18
CPC分类号： C08G64/0208 , C08G63/64 , C08G64/305
摘要： The above-described and other deficiencies of the art are met by a method of making a polycarbonate polymer comprising isosorbide carbonate units, comprising melt reacting a dihydroxy compound comprising an isosorbide of the general formula (2a): and an activated carbonate, in the presence of a catalyst consisting essentially of a sodium salt capable of providing a hydroxide ion, wherein the polycarbonate polymer comprises greater than or equal to 50 mol % isosorbide carbonate units, and wherein the polycarbonate polymer has a Mw of greater than or equal to about 40,000 g/mol as determined by gel-permeation chromatography relative to polystyrene standards. Polycarbonates comprising the isosorbide carbonate unit, including isosorbide homopolycarbonate and an isosorbide-based polyester-polycarbonate, are also disclosed, as are a thermoplastic composition and an article including the isosorbide-based polycarbonate polymer.
摘要翻译： 通过制备包含异山梨醇碳酸酯单元的聚碳酸酯聚合物的方法，包括使包含通式（2a）的异山梨醇的二羟基化合物与活化的碳酸酯在存在下熔融反应来实现本领域的上述和其它缺陷： 基本上由能够提供氢氧根离子的钠盐组成的催化剂，其中所述聚碳酸酯聚合物包含大于或等于50mol％的异山梨醇碳酸酯单元，并且其中所述聚碳酸酯聚合物具有大于或等于约40,000g / mol，通过凝胶渗透色谱法相对于聚苯乙烯标准物测定。 还公开了包含异山梨醇碳酸酯单元的聚碳酸酯，包括异山梨醇均聚碳酸酯和异山梨醇基聚酯 - 聚碳酸酯，热塑性组合物和包含异山梨醇基聚碳酸酯聚合物的制品也是如此。
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