摘要:
One step ortho-alkylation of anilines with styrenes to give chiral anilines is obtained using a strong acid catalyst, e.g. CF3SO3H. Condensation of the product to give ligand and metallation gives complex which catalyzes polymerization of propylene to give isotactic propylene or regiorandom propylene of low PDI or blocks thereof, depending on polymerization temperature.
摘要翻译:使用强酸催化剂,例如使用苯乙烯,苯乙烯,苯乙烯进行一步邻位烷基化得到手性苯胺。 CF 3 SO 3 H 3。 产物给予配体和金属化的缩合得到复合物,其根据聚合温度,催化丙烯的聚合,得到低PDI或其嵌段的全同立构丙烯或异氰酸酯丙烯。
摘要:
One step ortho-alkylation of anilines with styrenes to give chiral anilines is obtained using a strong acid catalyst, e.g. CF3SO3H. Condensation of the product to give ligand and metallation gives complex which catalyzes polymerization of propylene to give isotactic propylene or regiorandom propylene of low PDI or blocks thereof, depending on polymerization temperature.
摘要:
One step ortho-alkylation of anilines with styrenes to give chiral anilines is obtained using a strong acid catalyst, e.g. CF3SO3H. Condensation of the product to give ligand and metallation gives complex which catalyzes polymerization of propylene to give isotactic propylene or regiorandom propylene of low PDI or blocks thereof, depending on polymerization temperature.
摘要翻译:使用强酸催化剂,例如使用苯乙烯,苯乙烯,苯乙烯进行一步邻位烷基化得到手性苯胺。 CF 3 SO 3 H 3。 产物给予配体和金属化的缩合得到复合物,其根据聚合温度,催化丙烯的聚合,得到低PDI或其嵌段的全同立构丙烯或异氰酸酯丙烯。
摘要:
One step ortho-alkylation of anilines with styrenes to give chiral anilines is obtained using a strong acid catalyst, e.g. CF3SO3H. Condensation of the product to give ligand and metallation gives complex which catalyzes polymerization of propylene to give isotactic propylene or regiorandom propylene of low PDI or blocks thereof, depending on polymerization temperature.
摘要:
One step ortho-alkylation of anilines with styrenes to give chiral anilines is obtained using a strong acid catalyst, e.g. CF3SO3H. Condensation of the product to give ligand and metallation gives complex which catalyzes polymerization of propylene to give isotactic propylene or regiorandom propylene of low PDI or blocks thereof, depending on polymerization temperature.
摘要:
One step ortho-alkylation of anilines with styrenes to give chiral anilines is obtained using a strong acid catalyst, e.g. CF3SO3H. Condensation of the product to give ligand and metallation gives complex which catalyzes polymerization of propylene to give isotactic propylene or regiorandom propylene of low PDI or blocks thereof, depending on polymerization temperature.