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    Process for the manufacture of 2-chloroethane-phosphonic acid
    4.
    发明授权
    Process for the manufacture of 2-chloroethane-phosphonic acid 失效
    2-氯乙烷 - 膦酸的制备方法

    公开(公告)号：US4322371A

    公开(公告)日：1982-03-30

    申请号：US871550

    申请日：1978-01-23

    申请人： Gerhard Stahler

    发明人： Gerhard Stahler

    IPC分类号： C07F9/38 ,  C07F9/40

    CPC分类号： C07F9/3808 ,  C07F9/4075

    摘要： An improved process for the manufacture of 2-chloroethane-phosphonic acid in which 2-chloroethane-phosphonic acid bis(2-chloroethyl) ester is heated with 50 to 500% by weight of aqueous hydrochloric acid at temperatures above 100.degree. C. under pressure, the 1,2-dichloroethane formed during the reaction is continuously or discontinuously distilled off and the decrease in pressure is compensated by adding gaseous hydrogen chloride.

    摘要翻译： 一种改进的制备2-氯乙烷 - 膦酸的方法，其中2-氯乙烷 - 膦酸双（2-氯乙基）酯与50-500重量％的盐酸水溶液在高于100℃的温度下加压 ，在反应过程中形成的1,2-二氯乙烷连续或不连续地蒸馏掉，并通过加入氯化氢气来补偿压力的降低。

    Mono-, di- and tri-esters of thiophosphonic acid and their use as pesticides
    5.
    发明授权
    Mono-, di- and tri-esters of thiophosphonic acid and their use as pesticides 失效
    硫代膦酸的单，二酯和三酯及其作为农药的用途

    公开(公告)号：US4110336A

    公开(公告)日：1978-08-29

    申请号：US816968

    申请日：1977-07-19

    申请人： Hilmar Mildenberger ,  Gerhard Stahler ,  Ludwig Emmel

    发明人： Hilmar Mildenberger ,  Gerhard Stahler ,  Ludwig Emmel

    IPC分类号： A01N57/24 ,  C07F9/653 ,  C07F9/40

    CPC分类号： A01N57/24 ,  C07F9/65312

    摘要： Compounds having the formula ##STR1## in which R is alkyl, haloalkyl, cycloalkyl, cycloalkenyl, phenyl, optionally substituted by chlorine, methyl or methoxy, moreover bicycloheptyl or bicycloheptenyl; R.sub.1 is alkyl, optionally substituted by halogen, nitro, cyano or a radical having the formula ##STR2## ALKENYL, OPTIONALLY SUBSTITUTED BY HALOGEN; ALKINYL, ALKOXYALKYL, ALKYLMERCAPTO-ALKYL, CYCLOALKYL, PHENYL, HALOPHENYL, TRIFLUOROMETHYLPHENYL, BENZYL OR A RADICAL HAVING THE FORMULA ##STR3## R.sub.2 is alkyl, alkoxyalkyl, phenyl or halophenyl, R.sub.3 is methyl or ethyl, and X and Y are oxygen or sulfur are valuable pesticides.

    摘要翻译： 具有式（I）的化合物，其中R是烷基，卤代烷基，环烷基，环烯基，苯基，任选被氯，甲基或甲氧基取代，此外是双环庚基或双环庚烯基; R 1是烷基，任选地被卤素，硝基，氰基或具有下式的基团取代：由HALOGEN取代的式 烷基，烷氧基，烷氧基，烷基，亚苄基，环丙基，苯基，二甲苯基，三氟甲基苯基，苄基或具有该化合物的辐射R2是烷基，烷氧基烷基，苯基或卤代苯基，R3是甲基或乙基，X和Y是氧或硫 是有价值的农药。

    Process for the preparation of phosphonic acid dihalides
    6.
    发明授权
    Process for the preparation of phosphonic acid dihalides 失效
    制备膦酸二卤化物的方法

    公开(公告)号：US3972923A

    公开(公告)日：1976-08-03

    申请号：US415341

    申请日：1973-11-13

    申请人： Manfred Finke ,  Hans-Jerg Kleiner ,  Gerhard Stahler ,  Klaus Dehmer

    发明人： Manfred Finke ,  Hans-Jerg Kleiner ,  Gerhard Stahler ,  Klaus Dehmer

    IPC分类号： C07F9/42

    CPC分类号： C07F9/42

    摘要： Process for preparing phosphonic acid dihalides of the formula ##EQU1## wherein R is alkyl of 1 to 18 carbon atoms, cycloalkyl of 4 to 8 carbon atoms, alkenyl of 2 to 18 carbon atoms, phenyl, phenalkyl or alkyl-phenyl of 7 to 8 carbon atoms, phenyl, phenalkyl or alkyl-phenyl of 7 to 8 carbon atoms, all radicals R optionally being substituted by chlorine, bromine, cyano or lower acyloxy, and wherein X is halogen such as 2-chloroethane phosphonic acid dichloride, by reacting phosphonic or thio-phosphonic acids of the formula ##EQU2## wherein Y is oxygen or sulfur, their salts or functional derivatives, with acid halides of the formula(CO).sub.n X.sub.2 (III)wherein X is chlorine or bromine and n is 1 or 2, in the presence of 0.2 - 5% or in the presence of 0.01 to 0.2% by weight of1. compounds containing at least one tri- to pentavalent nitrogen or phosphorus atom, which in the case of nitrogen is bound with 1 to 4, in the case of phosphorus with at least 3 valences to organic radicals having up to 20 carbon atoms, two of these valences optionally forming a double bond, or2. mono-di- or tribasic organic or inorganic fully amidated acids or tri- or pentavalent phosphorus, the N atom of which optionally being substituted by aliphatic radicals having up to 20 carbon atoms, and the organic radicals of which contain up to 20 carbon atoms,If required, in the presence of an inert solvent.

    摘要翻译： 制备式XRP膦酸二卤化物的方法其中R为1至18个碳原子的烷基，4至8个碳原子的环烷基，2至18个碳原子的烯基，苯基，苯烷基或烷基 - 7至8个碳原子的苯基，7至8个碳原子的苯基，苯烷基或烷基 - 苯基，所有基团R任选被氯，溴，氰基或低级酰氧基取代，其中X是卤素如2-氯乙烷膦酸 通过使式YH RP ANGLE（II）PARALLEY YYH的膦酸或硫代膦酸与式（CO）n X 2（III）的酰卤反应，其中Y是氧或硫，其盐或官能衍生物，其中X是 氯或溴，n为1或2，在0.2-5％的存在下或在0.01至0.2重量％的存在下。1.含有至少一种三价或多价的硝酸或磷酸盐的化合物 氮在1至4之间，至少在磷酸盐的情况下 有机碳有机物多达20个碳原子，两个这样的价格可选地形成双重键，或2.单独或有机有机或无机全酰胺或三价或三价硼，其中N原子任选 被具有至多20个碳原子的脂族基团取代，并且其有机基团含有至多20个碳原子，如果需要，在惰性溶剂存在下。

    Process for the manufacture of 2-chloroethane-phosphonic acid
    8.
    发明授权
    Process for the manufacture of 2-chloroethane-phosphonic acid 失效
    2-氯乙烷 - 膦酸的制备方法

    公开(公告)号：US4018819A

    公开(公告)日：1977-04-19

    申请号：US605868

    申请日：1975-08-19

    申请人： Karl Rehn ,  Otto Schaffner ,  Gerhard Stahler

    发明人： Karl Rehn ,  Otto Schaffner ,  Gerhard Stahler

    IPC分类号： C07F9/38

    CPC分类号： C07F9/3808

    摘要： An improved process for the manufacture of 2-chloroethane phosphonic acid in which 2-chloroethane phosphonic acid bis(2-chloroethyl)-ester is heated with excess hydrogen chloride in the presence of 0.1 to 31% by weight of water at temperatures above 100.degree. C under pressure, the 1,2-dichloroethane formed during the reaction is continuously or discontinuously distilled off and the decrease in pressure is compensated by adding gaseous hydrogen chloride.

    摘要翻译： 一种制备2-氯乙烷膦酸的改进方法，其中2-氯乙烷膦酸双（2-氯乙基）酯与过量的氯化氢在高于100℃的温度下在0.1至31重量％的水存在下加热 在反应过程中形成的1,2-二氯乙烷连续或不连续地蒸馏出来，并通过加入氯化氢气来补偿压力的降低。

    Mono- and dithiophosphonic acid esters and their use as pesticides
    9.
    发明授权
    Mono- and dithiophosphonic acid esters and their use as pesticides 失效
    单 - 和二硫代膦酸酯及其作为农药的用途

    公开(公告)号：US4002743A

    公开(公告)日：1977-01-11

    申请号：US559643

    申请日：1975-03-18

    申请人： Gerhard Stahler ,  Ludwig Emmel ,  Werner Bonin

    发明人： Gerhard Stahler ,  Ludwig Emmel ,  Werner Bonin

    IPC分类号： A01N57/16 ,  A01N57/24 ,  A01N57/34 ,  C07F9/653 ,  C07D263/56

    CPC分类号： C07F9/65324 ,  A01N57/24

    摘要： Mono- and dithiophosphonic acid esters of the formula ##STR1## in which R is optionally substituted alkyl, cycloalkyl, cycloalkenyl, or optionally substituted phenyl, R' is optionally substituted alkyl, alkenyl, or cycloalkyl, R" and R'" which are identical or different, are hydrogen, halogen, methyl, methoxy, nitro or trifluoromethyl, and X is oxygen or sulfur, are useful insecticides and acaricides.

    摘要翻译： R 1为任选取代的烷基，环烷基，环烯基或任选取代的苯基，R'为任选取代的烷基，烯基或环烷基，R“和R”'的单 - 和二硫代膦酸酯为式 它们是相同或不同的，是氢，卤素，甲基，甲氧基，硝基或三氟甲基，X是氧或硫，是有用的杀虫剂和杀螨剂。