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公开(公告)号：US3937691A
公开(公告)日：1976-02-10
申请号：US365218
申请日：1973-05-30
CPC分类号： C08F10/00 , Y10S526/906
摘要： A process for the manufacture of poly(.alpha.-olefins) by polymerization of .alpha.-olefins using a catalyst system comprising (1) a titanium-containing component of (1.1) a substance of the formula TiCl.sub.3 . 1/3 AlCl.sub.3 and (1.2) an organic electron donor containing phosphorus atoms and/or nitrogen atoms, ground together with said substance (1.1), and (2) an aluminum-containing component of a substance of formula Al(C.sub.n H.sub.2 ..sub.n.sub.+1).sub.3 or Al(C.sub.n H.sub.2..sub.n.sub.+1).sub.2 Cl, where n is an integer of from 2 to 6. The characteristic feature is that the catalyst system used is one in which the component (1.1) has been ground with component (1.2) without the use of auxiliaries or additives in a vibratory ball mill using specific steel balls and a specific grinding acceleration over a specific period of time at a temperature which is just below that at which the particles in the ground material begin to agglomerate. The advantage of this process is that the efficiency of the catalyst system is very high and/or poly(.alpha.-olefins) are obtained which have a particularly large fraction which is insoluble in boiling n-heptane.
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公开(公告)号：US4296222A
公开(公告)日：1981-10-20
申请号：US780764
申请日：1977-03-24
申请人： Gerhard Staiger , Klaus Bronstert
发明人： Gerhard Staiger , Klaus Bronstert
CPC分类号： C08F10/00 , Y10S526/906
摘要： A process for the manufacture of poly-.alpha.-olefins by polymerizing .alpha.-olefins by means of a catalyst system comprising (1) a titanium-containing component obtained from (1.1) a compound of the formula TiCl.sub.3.1/3AlCl.sub.3 and (1.2) an organic electron donor, containing phosphorus, nitrogen and/or oxygen atoms, which has been milled with the compound of the formula TiCl.sub.3.1/3AlCl.sub.3 (1.1), in order to form a complex compound, the milling being carried out without assistants or additives in a vibratory ball mill under specific acceleration conditions and at a temperature which is from 4.degree. to 10.degree. C. below the temperature at which the particles of the material being ground begin to agglomerate, and (2) an aluminum-containing component, in which process the titanium-containing component (1) of the catalyst system used is one which has been treated, after milling and before polymerization, with (i) titanium tetrachloride and (ii) an ether and/or an ester.
摘要翻译： 一种通过催化剂体系聚合α-烯烃制备聚-α-烯烃的方法，包括（1）由（1.1）式TiCl3.1 / 3AlCl3化合物和（1.2）得到的含钛组分， 为了形成配位化合物，已经用式TiCl 3·1 / 3AlCl 3（1.1）的化合物研磨了含有磷，氮和/或氧原子的有机电子给体，所述研磨是在没有助剂的情况下进行的， 在特定的加速条件下和低于待研磨材料的颗粒开始凝聚的温度下4℃至10℃的温度下的振动球磨机中的添加剂，和（2）含铝组分， 在该方法中，使用的催化剂体系的含钛组分（1）是在碾磨后和聚合前用（i）四氯化钛和（ii）醚和/或酯进行处理的催化剂体系的含钛组分（1）。
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公开(公告)号：US4282341A
公开(公告)日：1981-08-04
申请号：US74758
申请日：1979-09-12
申请人： Peter Klaerner , Gerhard Staiger , Klaus Bronstert
发明人： Peter Klaerner , Gerhard Staiger , Klaus Bronstert
CPC分类号： C08F10/00
摘要： A process for the manufacture of homopolymers and copolymers of .alpha.-monoolefins by polymerizing the monomer or monomers at relatively low temperatures under relatively low pressures by means of a Ziegler-Natta catalyst comprising (I) a titanium chloride component and (II) an aluminumalkyl component, wherein the titanium chloride component (I) employed is obtained by exposing a conventional catalyst component consisting, or substantially consisting, of titanium trichloride or titanium tetrachloride, to a carbon dioxide atmosphere under specific conditions. Catalysts obtained from titanium chloride components (I) which have been treated in this way exhibit a relatively long induction period.
摘要翻译： 通过齐格勒 - 纳塔催化剂在相对低的压力下在相对较低的温度下聚合单体或单体，制备α-单烯烃的均聚物和共聚物的方法，该齐格勒 - 纳塔催化剂包含（I）氯化钛组分和（II） 其中使用的氯化钛组分（I）通过将由三氯化钛或四氯化钛组成或基本上由氯化钛或四氯化钛组成的常规催化剂组分暴露于特定条件下的二氧化碳气氛中而获得。 以这种方式处理的氯化钛组分（I）获得的催化剂表现出较长的诱导期。
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公开(公告)号：US4208497A
公开(公告)日：1980-06-17
申请号：US883218
申请日：1978-03-03
申请人： Klaus Bronstert , Peter Klaerner , Gerhard Staiger
发明人： Klaus Bronstert , Peter Klaerner , Gerhard Staiger
CPC分类号： C08F10/00
摘要： A process for the manufacture of homopolymers and copolymers of .alpha.-monoolefins by polymerizing the monomer or monomers at relatively low temperatures under relatively low pressures by means of a Ziegler-Natta catalyst comprising (I) a titanium trichloride component and (II) an aluminum-alkyl component, wherein the titanium trichloride component (I) employed is obtained by exposing a conventional catalyst component consisting, or substantially consisting, of titanium trichloride, to a carbon monoxide atmosphere under specific conditions. Catalysts obtained from titanium trichloride components (I) which have been treated in this way exhibit a relatively long induction period.
摘要翻译： 通过齐格勒 - 纳塔催化剂在相对较低的温度下在相对较低的温度下聚合单体或单体来制备α-单烯烃的均聚物和共聚物的方法，该齐格勒 - 纳塔催化剂包含（I）三氯化钛组分和（II） 烷基组分，其中所用的三氯化钛组分（I）通过将由三氯化钛组成或基本上由三氯化钛组成的常规催化剂组分暴露于特定条件下的一氧化碳气氛下获得。 以这种方式处理的三氯化钛组分（I）获得的催化剂表现出较长的诱导期。
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公开(公告)号：US4189557A
公开(公告)日：1980-02-19
申请号：US901195
申请日：1978-04-28
申请人： Peter Klaerner , Klaus Bronstert , Gerhard Staiger
发明人： Peter Klaerner , Klaus Bronstert , Gerhard Staiger
CPC分类号： C08F10/00 , Y10S526/903 , Y10S526/906 , Y10S526/907
摘要： A process for the manufacture of homopolymers and copolymers of .alpha.-monoolefins by polymerizing the monomer or monomers by means of a Ziegler-Natta catalyst comprising (I) a titanium trichloride component and (II) an aluminum-alkyl component, wherein the titanium trichloride component (I) employed is obtained by (1) in a first stage moistening a suitable conventional catalyst component, consisting entirely or substantially of titanium trichloride, with a hydrocarbon mixture comprising a liquid alkane hydrocarbon and a liquid benzene hydrocarbon and (2) in a second stage drying the catalyst component, moistened with the hydrocarbon mixture, under an inert gas, with constant mechanical mixing, within a certain period, at a temperature which is from 5.degree. to 50.degree. C. above the boiling point of the highest-boiling hydrocarbon present in the hydrocarbon mixture which has been used to moisten the component. Homopolymers and copolymers having particularly advantageous morphological properties can be manufactured by the process of the invention.
摘要翻译： 通过包含（I）三氯化钛组分和（II）铝 - 烷基组分的齐格勒 - 纳塔催化剂聚合单体或单体来制造α-单烯烃的均聚物和共聚物的方法，其中三氯化钛组分 （I）通过（1）在第一阶段中润湿合适的常规催化剂组分（其完全或基本上由三氯化钛组成）与包含液体烷烃和液体苯烃的烃混合物和（2）在第二阶段 在一定时间内，在高沸点烃的沸点以上5℃至50℃的温度下，在惰性气体下，以不断的机械混合的状态下，将烃类混合物润湿的催化剂组分进行阶段干燥 存在于用于润湿组分的烃混合物中。 可以通过本发明的方法制造具有特别有利的形态特征的均聚物和共聚物。
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6.发明授权Telechelics containing ethanolamine or oligoether-ol-amine end groups and process for the preparation thereof 失效含有乙醇胺或低聚醚 - 醇 - 胺端基的电视电影及其制备方法
公开(公告)号：US5753777A
公开(公告)日：1998-05-19
申请号：US553664
申请日：1995-11-17
申请人： Klaus Bronstert , Konrad Knoll
发明人： Klaus Bronstert , Konrad Knoll
IPC分类号： C08F8/30 , C08C19/44 , C08F4/48 , C08F36/00 , C08F36/02 , C08F36/04 , C08G18/69 , C08F136/06 , C08F8/32 , C08F136/08
CPC分类号： C08G18/696 , C08C19/44 , C08F36/04
摘要： A polydiene which is obtainable by anionic polymerization of a diene using a bifunctional Li initiator followed by polymer-like reaction and which contains at least one ethanolamine or oligoetherolamine terminal group of the general structure I ##STR1## in which R.sup.1 denotes alkyl or aryl, Ar denotes aryl, R.sup.2 denotes alkyl or hydrogen, and R.sup.3 denotes aryl, alkyl, or hydrogen and X can assume a value from 1 to 10, and the hydrogenation products thereof.
摘要翻译： PCT No.PCT / EP94 / 01802 Sec。 371日期：1995年11月17日 102（e）1995年11月17日日期PCT PCT 1994年6月3日PCT公布。 第WO94 / 29354号公报 日期：1994年12月22日A聚二烯，其可以通过使用双官能的Li引发剂进行二聚体的阴离子聚合，然后进行聚合物样反应并含有至少一种通式II的乙醇胺或低聚乙酰胺末端基，Ar表示芳基，R2表示 烷基或氢，R3表示芳基，烷基或氢，X可以为1至10的值，并且其氢化产物。
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7.发明授权Living polymers, the preparation thereof and the use thereof for preparing telechelic polymers 失效活性聚合物，其制备方法及其制备远电子聚合物的用途
公开(公告)号：US5321093A
公开(公告)日：1994-06-14
申请号：US764870
申请日：1991-09-24
申请人： Klaus Bronstert , Konrad Knoll , Erich Haedicke
发明人： Klaus Bronstert , Konrad Knoll , Erich Haedicke
IPC分类号： C08C19/44 , C08F4/48 , C08F36/04 , C08F297/04 , C08F297/94
CPC分类号： C08F297/042 , C08C19/44 , C08F36/04
摘要： A process for preparing bifunctional living polymers which are able to forth bifunctional telechelic polymers or block copolymers with at least 3 blocks of conjugated dienes and/or vinylaromatics with molecular weights of from 1,500 to 500,000, by bifunctional initiators whose anionic centers are aliphatic carbon atoms which are substituted by lithium and an aliphatic hydrocarbon radical as well as by either 2 aryl radicals or by one aryl radical and one hydrogen radical, where one of the aryl radicals can also be part of the two anionic centers, in a first stage being reacted in the presence of not more than 2.5 moles of an aliphatic ether or a tertiary amine per mole of lithium and not less than 2 mol/l of a conjugated diene at from -40.degree. to +35.degree. C. with not less than two moles of diene, resulting in the formation of low molecular weight diene oligomers which in turn act as bifunctional initiators, and using the latter in a second reaction stage in a conventional manner at above 40.degree. C., with or without the addition of other monomers, to obtain polymers of the required molecular weight.
摘要翻译： 制备双官能活性聚合物的方法，其能够通过双官能引发剂（其阴离子中心是脂族碳原子）与分子量为1,500至500,000的至少3个共轭二烯和/或乙烯基芳香族嵌段的双官能遥爪聚合物或嵌段共聚物 被锂和脂族烃基以及2个芳基或一个芳基和一个氢基取代，其中一个芳基也可以是两个阴离子中心的一部分，在第一阶段中被反应 在-40℃至+ 35℃下每摩尔锂和不小于2mol / l共轭二烯的摩尔数不超过2.5摩尔的脂族醚或叔胺的存在，不少于2摩尔的 二烯，导致形成低分子量二烯低聚物，其又作为双官能引发剂，并在上述常规方式的第二反应阶段中使用后者 40℃，加入或不加入其它单体，得到所需分子量的聚合物。
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公开(公告)号：US5122573A
公开(公告)日：1992-06-16
申请号：US696914
申请日：1991-05-08
申请人： Konrad Knoll , Klaus Bronstert , Dietmar Bender
发明人： Konrad Knoll , Klaus Bronstert , Dietmar Bender
IPC分类号： C08F8/20
CPC分类号： C08F8/20
摘要： A process for the preparation of polymers of isobutene having tertiary chloride groups by reaction of appropriate polymers which have been prepared by cationic polymerization of isobutene with hydrogen chloride.
摘要翻译： 通过异丁烯的阳离子聚合制备的合适的聚合物与氯化氢的反应制备具有三氯化钛基团的异丁烯的聚合物的方法。
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公开(公告)号：US4835221A
公开(公告)日：1989-05-30
申请号：US920078
申请日：1986-10-17
CPC分类号： C08C19/44
摘要： Polymers and copolymers of conjugated dienes and aromatic vinyl compound which have a carboxyl end group and are present as salts, the salts containing metal cations or metal cation complexes which are bivalent or polyvallent and also a process for preparing such salts of polymers which contain carboxyl end groups and their use for modifying thermoplastic materials or as vulcanizable materials.
摘要翻译： 具有羧基端基并以盐形式存在的共轭二烯和芳族乙烯基化合物的聚合物和共聚物，含有二价或多元醇的金属阳离子或金属阳离子络合物的盐，以及含有羧基末端的聚合物盐的制备方法 基团及其用于改性热塑性材料或作为可硫化材料的用途。
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公开(公告)号：US4822945A
公开(公告)日：1989-04-18
申请号：US128342
申请日：1987-12-03
IPC分类号： C07C2/30 , C08F110/14 , C10M107/10 , C07C2/02
CPC分类号： C10M107/10 , C07C2/30 , C08F110/14 , C07C2531/02 , C07C2531/14 , C10M2205/028 , C10N2220/02
摘要： Decene oligomers useful with or without hydrogenation as basis for synthetic lubricating oils are prepared by oligomerizing decene-1 in the presence of an alkylaluminum chloride catalyst and an alkyl halide cocatalyst, in a first reaction stage the decene-1 being mixed with the catalyst at from 0 to +25.degree. C. and being kept in contact therewith within the same temperature range for not less than 15 minutes and in a second reaction stage the cocatalyst being added at from 0 to +35.degree. C. in the course of a period of from 15 to 180 minutes.
摘要翻译： 通过在烷基氯化铝催化剂和烷基卤助催化剂存在下使癸烯-1低聚而制备用于合成润滑油或不加氢的癸烯低聚物，在第一反应阶段中，癸烯-1与催化剂在 0至+25℃，并在相同温度范围内保持接触不少于15分钟，而在第二反应阶段，助催化剂在0至+35℃的加入过程中 从15到180分钟。
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