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公开(公告)号：US08920929B2
公开(公告)日：2014-12-30
申请号：US13514173
申请日：2009-12-18
申请人： Given Jing Chen , Wilson Xiao Wei Yan , Bin Li , Lan Lu , Weiming Wayne Ma , Lotus Hua Huang , David Hong Fei Guo
发明人： Given Jing Chen , Wilson Xiao Wei Yan , Bin Li , Lan Lu , Weiming Wayne Ma , Lotus Hua Huang , David Hong Fei Guo
IPC分类号： B32B27/40 , B32B27/32 , C08K5/523 , C08K3/22 , C09D153/00
CPC分类号： C08L75/04 , C08K3/22 , C08K5/5205 , C08K5/523 , C08L53/00 , C08L63/00 , C08L2205/03 , Y10T428/31605 , Y10T428/31609 , Y10T428/31678 , Y10T428/31692
摘要： The present disclosure provides a flexible, halogen-free, flame retardant composition. The composition includes from about 25 wt % to about 95 wt % of a thermoplastic polyurethane (TPU); from about 5 wt % to about 50 wt % of an olefin block copolymer (OBC); and from about 30 wt % to about 70 wt % of a flame retardant. The flame retardant is selected from resorcinol bis(diphenyl 5 phosphate) (RDP), bis diphenyl phosphate (BDP), bisphenol-A bis(diphenyl phosphate) (BPADP), aluminum trihydrate (ATH), a nitrogen/phosphorus-based halogen-free flame retardant, epoxidized novolac resin, and combinations thereof. The composition requires no compatibilizer for the TPU and OBC. The composition finds application in wire and cable structures.
摘要翻译： 本公开提供了柔性的无卤阻燃组合物。 该组合物包含约25wt％至约95wt％的热塑性聚氨酯（TPU）; 约5重量％至约50重量％的烯烃嵌段共聚物（OBC）; 和约30重量％至约70重量％的阻燃剂。 阻燃剂选自间苯二酚双（二苯基磷酸二苯酯）（RDP），二苯基磷酸酯（BDP），双酚A双（磷酸二苯酯）（BPADP），三水合铝（ATH），氮/磷类卤素 - 游离阻燃剂，环氧化酚醛清漆树脂及其组合。 组合物不需要TPU和OBC的增容剂。 该组合物可应用于电线电缆结构中。
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公开(公告)号：US20120244365A1
公开(公告)日：2012-09-27
申请号：US13514173
申请日：2009-12-18
申请人： Given Jing Chen , Wilson Xiao Wei Yan , Bin Li , Lan Lu , Weiming Wayne Ma , Lotus Hua Huang , David Hong Fei Guo
发明人： Given Jing Chen , Wilson Xiao Wei Yan , Bin Li , Lan Lu , Weiming Wayne Ma , Lotus Hua Huang , David Hong Fei Guo
IPC分类号： C09D153/00 , C08K3/22 , C08K5/523 , B32B15/08 , C09D163/04
CPC分类号： C08L75/04 , C08K3/22 , C08K5/5205 , C08K5/523 , C08L53/00 , C08L63/00 , C08L2205/03 , Y10T428/31605 , Y10T428/31609 , Y10T428/31678 , Y10T428/31692
摘要： The present disclosure provides a flexible, halogen-free, flame retardant composition. The composition includes from about 25 wt % to about 95 wt % of a thermoplastic polyurethane (TPU); from about 5 wt % to about 50 wt % of an olefin block copolymer (OBC); and from about 30 wt % to about 70 wt % of a flame retardant. The flame retardant is selected from resorcinol bis(diphenyl 5 phosphate) (RDP), bis diphenyl phosphate (BDP), bisphenol-A bis(diphenyl phosphate) (BPADP), aluminum trihydrate (ATH), a nitrogen/phosphorus-based halogen-free flame retardant, epoxidized novolac resin, and combinations thereof. The composition requires no compatibilizer for the TPU and OBC. The composition finds application in wire and cable structures.
摘要翻译： 本公开提供了柔性的无卤阻燃组合物。 该组合物包含约25wt％至约95wt％的热塑性聚氨酯（TPU）; 约5重量％至约50重量％的烯烃嵌段共聚物（OBC）; 和约30重量％至约70重量％的阻燃剂。 阻燃剂选自间苯二酚双（二苯基磷酸二苯酯）（RDP），二苯基磷酸酯（BDP），双酚A双（磷酸二苯酯）（BPADP），三水合铝（ATH），氮/磷类卤素 - 游离阻燃剂，环氧化酚醛清漆树脂及其组合。 组合物不需要TPU和OBC的增容剂。 该组合物可应用于电线电缆结构中。
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3.发明申请公开(公告)号：US20120244305A1
公开(公告)日：2012-09-27
申请号：US13513893
申请日：2009-12-18
申请人： Given Jing Chen , Wilson Xiao Wei Yan , Lan Lu , Bin Li , David Hong Fei Guo , Lotus Hua Huang
发明人： Given Jing Chen , Wilson Xiao Wei Yan , Lan Lu , Bin Li , David Hong Fei Guo , Lotus Hua Huang
CPC分类号： H01B3/302 , C08K5/5205 , C08K5/523 , C08K2003/2227 , H01B3/441 , H01B7/295 , Y10T428/139 , C08L75/08 , C08L63/04 , C08L51/06 , C08L53/00
摘要： A halogen-free, flame retardant composition comprises thermoplastic polyurethane, olefin block copolymer, carbonyl-containing olefin polymer compatibilizer, and flame retardant package comprising bisphenol-A bis(diphenyl phosphate) and/or resorcinol bis(diphenyl phosphate), a nitrogen/phosphorus based, halogen-free flame retardant, and epoxidized novolac. The composition that will not only be processed easily to make a wire or cable sheath but also pass both the VW-1 flame retardancy test and the UL1581 heat deformation test at 150° C. exhibits good tensile and flexibility properties.
摘要翻译： 无卤阻燃组合物包含热塑性聚氨酯，烯烃嵌段共聚物，含羰基的烯烃聚合物增容剂和包含双酚-A双（二苯基磷酸酯）和/或间苯二酚双（二苯基磷酸酯），氮/磷 无卤阻燃剂和环氧化酚醛清漆。 不仅容易制造电线或电缆护套，而且通过VW-1阻燃试验和UL1581热变形试验在150℃下的组合物表现出良好的拉伸和柔软性。
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4.发明授权公开(公告)号：US08455576B2
公开(公告)日：2013-06-04
申请号：US13513893
申请日：2009-12-18
申请人： Given Jing Chen , Wilson Xiao Wei Yan , Lan Lu , Bin Li , David Hong Fei Guo , Lotus Hua Huang
发明人： Given Jing Chen , Wilson Xiao Wei Yan , Lan Lu , Bin Li , David Hong Fei Guo , Lotus Hua Huang
IPC分类号： C08K5/523
CPC分类号： H01B3/302 , C08K5/5205 , C08K5/523 , C08K2003/2227 , H01B3/441 , H01B7/295 , Y10T428/139 , C08L75/08 , C08L63/04 , C08L51/06 , C08L53/00
摘要： A halogen-free, flame retardant composition comprises thermoplastic polyurethane, olefin block copolymer, carbonyl-containing olefin polymer compatibilizer, and flame retardant package comprising bisphenol-A bis(diphenyl phosphate) and/or resorcinol bis(diphenyl phosphate), a nitrogen/phosphorus based, halogen-free flame retardant, and epoxidized novolac. The composition that will not only be processed easily to make a wire or cable sheath but also pass both the VW-1 flame retardancy test and the UL1581 heat deformation test at 150° C. exhibits good tensile and flexibility properties.
摘要翻译： 无卤阻燃组合物包含热塑性聚氨酯，烯烃嵌段共聚物，含羰基的烯烃聚合物增容剂和包含双酚-A双（二苯基磷酸酯）和/或间苯二酚双（二苯基磷酸酯），氮/磷 无卤阻燃剂和环氧化酚醛清漆。 不仅容易制造电线或电缆护套，而且通过VW-1阻燃试验和UL1581热变形试验在150℃下的组合物表现出良好的拉伸和柔软性。
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5.发明申请Thermoplastic Polymer Blends Comprising Crosslinked Polar Olefin Polymers in a Thermoplastic Polyurethane Matrix 审中-公开热塑性聚氨酯基质中包含交联极性烯烃聚合物的热塑性聚合物共混物公开(公告)号：US20120238664A1
公开(公告)日：2012-09-20
申请号：US13512718
申请日：2009-12-11
申请人： Wilson Xiao Wei Yan , Given Jing Chen , Tong Wu , Lotus Hua Huang , David Hong Fei Guo , Jeffrey M. Cogen , Will Wei Chao Gu
发明人： Wilson Xiao Wei Yan , Given Jing Chen , Tong Wu , Lotus Hua Huang , David Hong Fei Guo , Jeffrey M. Cogen , Will Wei Chao Gu
CPC分类号： C08L75/04 , C08K3/22 , C08K5/523 , C08K5/54 , C08L23/02 , C08L23/0853 , C08L31/04 , C08L63/04 , C08L2201/02 , C08L2666/20 , C08L2666/22 , C08L2666/04
摘要： Polymer blends comprising a first phase comprising a thermoplastic polyurethane matrix and a second phase comprising a crosslinked polar olefin polymer are provided. The first phase is a continuous phase and the second phase can be co-continuous with the first phase, or dispersed as a non-continuous phase in the first phase. The first phase further comprises a metal hydroxide flame retardant and an organic flame retardant. The second phase further includes a metal hydroxide which is coupled to the olefin polymer via a silane coupling agent.
摘要翻译： 提供包含包含热塑性聚氨酯基质的第一相和包含交联的极性烯烃聚合物的第二相的聚合物共混物。 第一相是连续相，第二相可以与第一相共同连续，或者在第一相中作为非连续相分散。 第一阶段还包括金属氢氧化物阻燃剂和有机阻燃剂。 第二相还包括通过硅烷偶联剂与烯烃聚合物偶联的金属氢氧化物。
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6.发明授权Halogen-free, flame retardant composition comprising crosslinked silane-g-EVA 有权包含交联硅烷-g-EVA的无卤阻燃组合物公开(公告)号：US09318240B2
公开(公告)日：2016-04-19
申请号：US13695862
申请日：2010-05-24
摘要： Halogen-free, flame retardant compositions comprising in weight percent based on the weight of the composition: A. 20 to 60% TPU/Si-g-EVA polymer blend in which the Si-g-EVA is crosslinked, B. 1 to 25% organic phosphate ester, C. 30 to 60% metal hydrate, and D. 0.1 to 10% epoxidized novolac. Optionally, the compositions further comprise in weight percent based on the weight of the composition, one or more of: E. 0.01 to 0.5% anti-dripping agent, F. 0.1 to 2% additive; and G. 0.1 to 5% filler.
摘要翻译： 基于组合物重量的无卤素阻燃组合物，其重量百分数：A.其中Si-g-EVA交联的20-60％TPU / Si-g-EVA聚合物共混物，B 1至25 ％有机磷酸酯，C.30-60％金属水合物，D.D.1至10％环氧化酚醛清漆。 任选地，组合物还包含基于组合物重量的重量百分比，一种或多种：E.0.01至0.5％的抗滴落剂，F. 0.1至2％的添加剂; 和G. 0.1至5％填料。
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7.发明申请Halogen-Free, Flame Retardant Composition Comprising Crosslinked Silane-g-EVA 有权包含交联硅烷-g-EVA的无卤素，阻燃组合物公开(公告)号：US20130059943A1
公开(公告)日：2013-03-07
申请号：US13695862
申请日：2010-05-24
IPC分类号： C09K21/14
摘要： Halogen-free, flame retardant compositions comprising in weight percent based on the weight of the composition: A. 20 to 60% TPU/Si-g-EVA polymer blend in which the Si-g-EVA is crosslinked, B. 1 to 25% organic phosphate ester, C. 30 to 60% metal hydrate, and D. 0.1 to 10% epoxidized novolac. Optionally, the compositions further comprise in weight percent based on the weight of the composition, one or more of: E. 0.01 to 0.5% anti-dripping agent, F. 0.1 to 2% additive; and G. 0.1 to 5% filler.
摘要翻译： 基于组合物重量的无卤素阻燃组合物，其重量百分数：A.其中Si-g-EVA交联的20-60％TPU / Si-g-EVA聚合物共混物，B 1至25 ％有机磷酸酯，C.30-60％金属水合物，D.D.1至10％环氧化酚醛清漆。 任选地，组合物还包含基于组合物重量的重量百分比，一种或多种：E.0.01至0.5％的防滴剂，F.0.1至2％的添加剂; 和G. 0.1至5％填料。
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