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公开(公告)号：US5124297A
公开(公告)日：1992-06-23
申请号：US624210
申请日：1990-12-07
CPC分类号： C08F10/00
摘要： A catalyst or catalyst component for the polymerization of copolymerization of alpha-olefins, which is formed by a process comprising forming a solution of a magnesium-containing species in a liquid comprising at least one alcohol.
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公开(公告)号：US4988656A
公开(公告)日：1991-01-29
申请号：US351408
申请日：1989-05-12
申请人： Gregory G. Arzoumanidis , Nicholas M. Karayannis , Habet M. Khelghatian , Sam S. Lee , Bryce V. Johnson
发明人： Gregory G. Arzoumanidis , Nicholas M. Karayannis , Habet M. Khelghatian , Sam S. Lee , Bryce V. Johnson
IPC分类号： C08F10/00
CPC分类号： C08F10/00 , Y10S526/904
摘要： A solid hydrocarbon-insoluble, alpha-olefin polymerization catalyst component with superior activity, stereospecificity and morphology characteristics comprises the product formed by (A) forming a solution of a magnesium-containing species from a magnesium carbonte or a magnesium carboxylate; (B) precipitating solid particles from such magnesium-containing solution by treatment with a transition metal halide and an organosilane; (C) reprecipitating such solid particles from a mixture containing a cyclic ether; and (D) treating the reprecipitated particles with a transition metal compound and an electron donor.
摘要翻译： 具有优异活性，立体定向性和形态特征的固体烃不溶性α-烯烃聚合催化剂组分包括通过（A）由镁碳酸镁或羧酸镁形成含镁物质的溶液形成的产物; （B）用过渡金属卤化物和有机硅烷处理从这种含镁溶液中沉淀固体颗粒; （C）从含有环醚的混合物中再沉淀这样的固体颗粒; 和（D）用过渡金属化合物和电子给体处理再沉淀的颗粒。
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公开(公告)号：US4946816A
公开(公告)日：1990-08-07
申请号：US395990
申请日：1989-08-21
申请人： Steven A. Cohen , Gregory G. Arzoumanidis , Nicholas M. Karayannis , Habet M. Khelghatian , Sam S. Lee
发明人： Steven A. Cohen , Gregory G. Arzoumanidis , Nicholas M. Karayannis , Habet M. Khelghatian , Sam S. Lee
CPC分类号： C08F10/00 , Y10S526/903
摘要： In a solid hydrocarbon-insoluble, alpha-olefin polymerization catalyst component with superior activity, stereospecificity and morphology characteristics comprising the product formed by (A) forming a solution of a magnesium-containing species from a magnesium alkyl (or hydrocarbyl) carbonate or a magnesium carboxylate; (B) precipitating solid particles from such magnesium-containing toluene-based solvent by treatment with a transition metal halide and an organosilane; (C) reprecipitating such solid particles from a mixture containing a cyclic either; and (D) treating the reprecipitated particles with a transition metal compound and an electron donor, the morphology of such component is modified by incorporating a morphology-affecting amount of C.sub.8 -C.sub.10 aromatics within the toluene-based solvent in Step B, Step A, in Step C prior to addition of ether, or combinations thereof.
摘要翻译： 在具有优异活性，立体定向性和形态特征的固体烃不溶性α-烯烃聚合催化剂组分中，包括通过（A）由碳酸烷基（或烃基）或镁的镁形成镁的物质溶液形成的产物 羧酸酯; （B）用过渡金属卤化物和有机硅烷处理从这种含镁甲苯系溶剂中析出固体颗粒; （C）从含有环状的混合物中再沉淀此类固体颗粒; 和（D）用过渡金属化合物和电子给体处理再沉淀的颗粒，通过在步骤B，步骤A中在甲苯系溶剂中引入形态影响量的C 8 -C 10芳族化合物来修饰这些组分的形态， 在步骤C中加入醚之前，或其组合。
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公开(公告)号：US4866022A
公开(公告)日：1989-09-12
申请号：US186359
申请日：1988-04-25
申请人： Gregory G. Arzoumanidis , Nicholas M. Karayannis , Habet M. Khelghatian , Sam S. Lee , Bryce V. Johnson
发明人： Gregory G. Arzoumanidis , Nicholas M. Karayannis , Habet M. Khelghatian , Sam S. Lee , Bryce V. Johnson
CPC分类号： C08F10/00
摘要： A solid hydrocarbon-insoluble, alpha-olefin polymerization catalyst component with superior activity, stereospecificity and morphology characteristics comprises the product formed by (A) forming a solution of a magnesium-containing species from a magnesium carbonate or a magnesium carboxylate; (B) precipitating solid particles from such magnesium-containing solution by treatment with a transition metal halide and an organosilane; (C) reprecipitating such solid particles from a mixture containing a cyclic ether; and (D) treating the reprecipitated particles with a transition metal compound and an electron donor.
摘要翻译： 具有优异活性，立体定向性和形态特征的固体烃不溶性α-烯烃聚合催化剂组分包括由（A）形成镁酸盐或羧酸镁的含镁物质溶液形成的产物; （B）用过渡金属卤化物和有机硅烷处理从这种含镁溶液中沉淀固体颗粒; （C）从含有环醚的混合物中再沉淀这样的固体颗粒; 和（D）用过渡金属化合物和电子给体处理再沉淀的颗粒。
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5.发明授权Activation of complexed reduced titanium halide olefin polymerization catalyst with haloalkylchlorosilanes 失效用卤代烷基氯硅烷活化复合的还原卤化钛烯烃聚合催化剂
公开(公告)号：US4422956A
公开(公告)日：1983-12-27
申请号：US378405
申请日：1982-05-14
CPC分类号： C08F10/00
摘要： A titanium-containing olefin polymerization catalyst component comprises a titanium-containing component formed by reducing titanium tetrachloride with an organoaluminum compound, optionally contacting the resulting reduced solid with a pretreatment amount of alpha-olefin monomer under polymerization conditions, and reacting the resulting product with a Lewis base complexing agent and a haloalkylchlorosilane.
摘要翻译： 含钛烯烃聚合催化剂组分包括通过用有机铝化合物还原四氯化钛形成的含钛组分，任选地在聚合条件下使所得还原固体与预处理量的α-烯烃单体接触，并将所得产物与 路易斯碱络合剂和卤代烷基氯硅烷。
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公开(公告)号：US5013702A
公开(公告)日：1991-05-07
申请号：US434915
申请日：1989-11-09
申请人： Gregory G. Arzoumanidis , Nicholas M. Karayannis , Habet M. Khelghatian , Sam S. Lee , Bryce V. Johnson
发明人： Gregory G. Arzoumanidis , Nicholas M. Karayannis , Habet M. Khelghatian , Sam S. Lee , Bryce V. Johnson
CPC分类号： C08F10/00
摘要： A solid hydrocarbon-insoluble, alpha-olefin polymerization catalyst component with superior activity, stereospecificity and morphology characteristics comprises the product formed by (A) forming a solution of a magnesium-containing species from a magnesium carbonate or a magnesium carboxylate; (B) precipitating solid particles from such magnesium-containing solution by treatment with a transition metal halide and an organosilane; (C) reprecipitating such solid particles from a mixture containing a cyclic ether; and (D) treating the reprecipitated particles with a transition metal compound and an electron donor.
摘要翻译： 具有优异活性，立体定向性和形态特征的固体烃不溶性α-烯烃聚合催化剂组分包括由（A）形成镁酸盐或羧酸镁的含镁物质溶液形成的产物; （B）用过渡金属卤化物和有机硅烷处理从这种含镁溶液中沉淀固体颗粒; （C）从含有环醚的混合物中再沉淀这样的固体颗粒; 和（D）用过渡金属化合物和电子给体处理再沉淀的颗粒。
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公开(公告)号：US4657883A
公开(公告)日：1987-04-14
申请号：US784934
申请日：1985-10-07
CPC分类号： C08F10/00
摘要： An olefin polymerization catalyst component comprises an organoaluminum-reduced titanium trihalide on which a pretreatment amount of olefin polymer has been placed complexed with an alkyl aliphatic carboxylic acid ester containing 7 to 22 carbon atoms having a structure:R--CO.sub.2 R'wherein R' is an alkyl group containing 3 to about 8 carbon atoms and R is an alkyl group containing 3 to 17 carbon atoms, and treated with a Lewis acid, a chlorocarbon or an haloalkylchlorosilane.
摘要翻译： 烯烃聚合催化剂组分包含有机铝还原的三卤化钛，其上预处理量的烯烃聚合物与含有7-22个碳原子的烷基脂族羧酸酯配合，其结构为：R-CO 2 R'，其中R'为 含有3〜8个碳原子的烷基，R为含有3〜17个碳原子的烷基，用路易斯酸，氯碳化合物或卤代烷基氯硅烷处理。
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公开(公告)号：US4612299A
公开(公告)日：1986-09-16
申请号：US741858
申请日：1985-06-06
CPC分类号： C08F10/00 , Y10S526/904
摘要： Composition comprising a transition metal component and magnesium carboxylate prepared by reacting a solution of hydrocarbyl magnesium compound with carbon dioxide to precipitate a magnesium carboxylate and reacting magnesium carboxylate with transition metal component.
摘要翻译： 含有过渡金属组分和羧酸镁的组合物，其通过使烃基镁化合物的溶液与二氧化碳反应而沉淀羧酸镁并使羧酸镁与过渡金属组分反应制备。
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9.发明授权
公开(公告)号：US4579836A
公开(公告)日：1986-04-01
申请号：US736941
申请日：1985-05-22
CPC分类号： C08F10/00 , Y10S526/904
摘要： An exhaustively prepolymerized supported olefin polymerization catalyst component comprises solid, hydrocarbon-insoluble, magnesium-containing, titanium-containing catalyst particles which have been contacted with an olefin monomer and an organo-aluminum co-catalyst under exhaustive prepolymerization conditions at an Al/Ti atomic ratio such that the weight of prepolymer formed is less than 10 times the weight of such catalyst particles and the resulting prepolymerized catalyst particles essentially are inactive to further polymerization.
摘要翻译： 全部预聚的负载型烯烃聚合催化剂组分包括固体，烃不溶性，含镁，含钛的催化剂颗粒，其在Al / Ti原子的完全预聚合条件下已经与烯烃单体和有机铝助催化剂接触 比例使得形成的预聚物的重量小于这种催化剂颗粒的重量的10倍，并且所得预聚催化剂颗粒基本上对于进一步聚合是无活性的。
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公开(公告)号：US4540679A
公开(公告)日：1985-09-10
申请号：US592910
申请日：1984-03-23
CPC分类号： C08F10/00 , Y10S526/904
摘要： Composition comprising a transition metal component and magnesium hydrocarbyl carbonate. Composition can be prepared by reacting suspension of magnesium alcoholate with carbon dioxide to form a magnesium hydrocarbyl carbonate and reacting magnesium hydrocarbyl carbonate with transition metal component. When the suspending liquid comprises an alcohol, the magnesium hydrocarbyl carbonate dissolves and is subsequently precipitated with an antisolvent comprising metal alkyl or transition metal halide. When the suspending liquid is substantially free of alcohol, the magnesium hydrocarbyl carbonate suspension is reacted with metal alkyl and transition metal compound.
摘要翻译： 包含过渡金属组分和碳酸镁烷基酯的组合物。 组合物可以通过使醇镁化物的悬浮液与二氧化碳反应形成碳酸镁烷基酯并使碳酸镁与过渡金属组分反应来制备。 当悬浮液体包含醇时，烃基碳酸镁溶解并随后用包含金属烷基或过渡金属卤化物的反溶剂沉淀。 当悬浮液基本上不含醇时，碳酸镁烷基酯悬浮液与金属烷基和过渡金属化合物反应。
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