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公开(公告)号:US20230180598A1
公开(公告)日:2023-06-08
申请号:US17925619
申请日:2021-06-16
Applicant: HODOGAYA CHEMICAL CO., LTD. , SFC CO., LTD.
Inventor: Yuta HIRAYAMA , Takeshi YAMAMOTO , Kouki KASE , Kazuyuki SURUGA , Shuichi HAYASHI , Soon-Wook CHA , Sung-Hoon JOO , Byung-Sun YANG , Ji-Hwan KIM
CPC classification number: H10K85/633 , H10K85/658 , C09K11/06 , H10K50/156
Abstract: An objective of the present invention is to provide a material for organic EL devices offering excellent hole injectability and transportability, electron blockability, stability in a thin-film state, and durability, and also to provide an organic EL device having high efficiency, low driving voltage and long lifetime by employing, in combination, the aforementioned material and various materials for organic EL devices offering excellent hole/electron injectability and transportability, electron blockability, stability in a thin-film state, and durability, in a manner that the properties of each of the materials can be brought out effectively. The present invention relates to an organic EL device containing a specific arylamine compound as a material constituting a second hole transport layer, wherein the difference between the HOMO level of the second hole transport layer and the HOMO level of a first hole transport layer is 0.15 eV or less.
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公开(公告)号:US20210210693A1
公开(公告)日:2021-07-08
申请号:US17057040
申请日:2019-06-20
Applicant: HODOGAYA CHEMICAL CO., LTD.
Inventor: Takuya UEHARA , Kouki KASE , Kyung-Hwa PARK , Yuta HIRAYAMA
IPC: H01L51/00 , C07C211/54 , C07C211/61 , C07C211/58
Abstract: An object of the present invention is to provide an organic compound that has excellent properties, with excellent hole injection and transport performance, electron blocking capability, and high stability in a thin film state, and furthermore to provide a highly efficient and highly durable organic EL device by using this compound. The present invention relates to a compound having a triarylamine structure and being represented by the structural formula (A-1) below, where A, B, and C may be the same or different, and each represent a group represented by the structural formula (B-1) below, a substituted or unsubstituted aromatic hydrocarbon group, a substituted or unsubstituted aromatic heterocyclic group, or a substituted or unsubstituted fused polycyclic aromatic group, where at least one of A, B, and C is not the group represented by the structural formula (B-1) below. (For the symbols and the like in the formulae, see the descriptions in the specification.)
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公开(公告)号:US20200035927A1
公开(公告)日:2020-01-30
申请号:US16522107
申请日:2019-07-25
Applicant: HODOGAYA CHEMICAL CO., LTD.
Inventor: Kouki KASE , Si-In KIM , Yuta HIRAYAMA
IPC: H01L51/00 , C07D491/147 , C09K11/06
Abstract: A compound has an azaindeno phenanthrene ring structure, the compound being represented by the following general formula (A-1).
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公开(公告)号:US20240352009A1
公开(公告)日:2024-10-24
申请号:US18694173
申请日:2022-10-26
Applicant: HODOGAYA CHEMICAL CO., LTD.
Inventor: Kouki KASE , Byung-Sun YANG , Moon-Chan HWANG , Junichi IZUMIDA , Yuta HIRAYAMA , Shuichi HAYASHI
IPC: C07D417/10 , C07D413/10 , C07D413/14 , C07D417/14 , C07D487/04 , H10K85/60
CPC classification number: C07D417/10 , C07D413/10 , C07D413/14 , C07D417/14 , C07D487/04 , H10K85/615 , H10K85/631 , H10K85/654 , H10K85/6572 , H10K85/6574 , H10K85/6576
Abstract: In order to prevent deterioration inside an organic EL element and significantly improve the light extraction efficiency, an object of the present invention is to provide a compound that absorbs light rays with wavelengths of 400 to 410 nm of sunlight, thereby preventing them from affecting a material inside the element, and has a high refractive index in a wavelength range of 450 to 750 nm. The present invention provides an amine compound having a specific benzazole ring structure having a high refractive index. An organic EL element having excellent light emission efficiency is obtained by using the compound of the present invention as a material constituting a capping layer.
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公开(公告)号:US20240260457A1
公开(公告)日:2024-08-01
申请号:US18618748
申请日:2024-03-27
Applicant: HODOGAYA CHEMICAL CO., LTD.
Inventor: Kouki KASE , Takeshi YAMAMOTO , Shunji MOCHIZUKI , Shuichi HAYASHI
CPC classification number: H10K85/654 , H10K85/631 , H10K50/15 , H10K50/16 , H10K50/171
Abstract: The present invention relates to an organic EL device having at least an anodic electrode, a hole transport layer, a light emitting layer, an electron transport layer, a cathodic electrode, and a capping layer in this order, in which the capping layer contains an amine compound having a benzazole ring structure represented by the following general formula (A-1).
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公开(公告)号:US20230112128A1
公开(公告)日:2023-04-13
申请号:US17788976
申请日:2021-01-20
Applicant: HODOGAYA CHEMICAL CO., LTD.
Inventor: Kouki KASE , Takeshi YAMAMOTO , Jae-Geon LIM , Junichi IZUMIDA , Shuichi HAYASHI , Norimasa YOKOYAMA
IPC: C07C211/54 , H01L51/00 , H01L51/50
Abstract: An objective of the invention is to provide, as a material for highly efficient, highly durable organic EL devices, an organic EL device material having excellent hole injectability and transportability, electron blockability, high stability in a thin-film state, and excellent durability, and also to provide a highly efficient, highly durable organic EL device by using this compound. The present invention concerns an arylamine compound represented by general formula (1). (In the formula, Ar1, Ar2, Ar3, and Ar4 each represent a substituted or unsubstituted aromatic hydrocarbon group, etc.; L1 and L2 each represent a divalent substituted or unsubstituted aromatic hydrocarbon group, etc.; R1 to R7 each represent a hydrogen atom, a deuterium atom, etc.; and m and n may be the same or different from one another, and each represent an integer from 0 to 2, wherein L1 represents a single bond when m is 0, and L2 represents a single bond when n is 0.)
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公开(公告)号:US20230101400A1
公开(公告)日:2023-03-30
申请号:US17792001
申请日:2021-01-21
Applicant: HODOGAYA CHEMICAL CO., LTD. , SFC CO., LTD.
Inventor: Junichi IZUMIDA , Takeshi YAMAMOTO , Kouki KASE , Kazuyuki SURUGA , Shuichi HAYASHI , Soon-Wook CHA , Sung-Hoon JOO , Byung-Sun YANG , Ji-Hwan KIM
Abstract: An organic electroluminescent element including an anode and a cathode and including, between the anode and the cathode, at least a first hole transport layer, a second hole transport layer, a blue-light-emitting layer, and an electron transport layer disposed in this order from the anode side, in which at least one of the layers disposed between the first hole transport layer and the electron transport layer includes an arylamine compound represented by general formula (1).
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公开(公告)号:US20180351101A1
公开(公告)日:2018-12-06
申请号:US15776582
申请日:2016-11-16
Applicant: HODOGAYA CHEMICAL CO., LTD.
Inventor: Kazuyuki SURUGA , Kouki KASE , Junichi IZUMIDA , Syunji MOCHIDUKI
IPC: H01L51/00 , C07C211/58 , C09K11/02
CPC classification number: C09K11/06 , C07C211/58 , C07D307/91 , H01L51/50
Abstract: The present invention provides an organic EL device having at least an anode, a hole-transporting layer, a luminous layer, an electron-transporting layer and a cathode arranged in this order, wherein the hole-transporting layer contains an arylamine compound represented by the following general formula (1). The organic EL device of the present invention has a high efficiency, drives on a low voltage, and features a specifically long life.
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公开(公告)号:US20250109145A1
公开(公告)日:2025-04-03
申请号:US18684337
申请日:2022-08-18
Applicant: HODOGAYA CHEMICAL CO., LTD.
Inventor: Eriko CHIBA , Kouki KASE , Takeshi YAMAMOTO , Yuta HIRAYAMA , Shuichi HAYASHI
IPC: C07D519/00 , H10K50/844 , H10K85/60
Abstract: An object of the present invention is to provide a compound not affecting a material inside a device by absorbing light at a wavelength of 400 nm to 410 nm of sunlight, and having a high refractive index at a wavelength in range of 450 nm to 750 nm in order to prevent deterioration inside the device of an organic EL device and greatly improve light extraction efficiency.
The present invention was achieved by focusing on the fact that arylamine-based materials have excellent thin film stability and durability and planning a diamine compound having a specific benzazole ring structure with a high refractive index, using the compound as materials constituting a capping layer, and an organic EL device having excellent luminous efficiency was obtained.-
公开(公告)号:US20240360358A1
公开(公告)日:2024-10-31
申请号:US18681888
申请日:2022-09-20
Applicant: HODOGAYA CHEMICAL CO., LTD.
Inventor: Kouki KASE , Eriko CHIBA , Byung-Sun YANG , Moon-Chan HWANG , Yuta HIRAYAMA , Shuichi HAYASHI
CPC classification number: C09K11/06 , H10K50/11 , H10K85/6572 , C09K2211/1029
Abstract: It is an object of the present invention to provide a compound that has a high refractive index and a low extinction coefficient in a wavelength range of 450 to 750 nm, which is favorably used as a material for a capping layer of an organic EL element. Also, it is another object of the present invention to provide an organic EL element whose light extraction efficiency has been improved by using the compound. The present invention is directed to a compound represented by a general formula (1) or (2) below:
where A represents a substituted or unsubstituted aromatic hydrocarbon group or the like, B and C are optionally the same or different, and represent an unsubstituted naphthyl group, an unsubstituted quinolyl group, or the like, and each L is optionally the same or different, and represents a single bond, a substituted or unsubstituted divalent aromatic hydrocarbon group, or the like.
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