摘要:
Novel water-soluble, reactive xanthene dystuffs of the
IN WHICH R1 and R2, being identical or different, each represent hydrogen, chlorine, bromine, lower alkyl or lower alkoxy, X represents oxygen, sulfur or
AND M REPRESENTS A NUMBER FROM 1 TO 3, SAID DYSTUFFS BEING HIGHLY SUITABLE FOR THE DYEING OR PRINTING OF LEATHER, WOOL, SILK, POLYAMIDE OR POLYURETHANE FIBRES, ESPECIALLY OF CELLULOSE FIBRES, THE DYEINGS OR PRINTS OBTAINED ON CELLULOSE FIBRES WITH THE SAID DYESTUFFS BEING IN PART DISTINGUISHED BY HIGH BRILLIANCY AND GOOD FASTNESS PROPERTIES, PARTICULARLY BY GOOD FASTNESS TO WET PROCESSING.
摘要:
Water-soluble reactive azo dyestuffs of the formula (1)
WHEREIN R represents a hydrogen atom or a lower alkyl radical a cyclohexyl radical or a phenyl radical, Q represents a hydrogen atom or a hydroxyl group and Z stands for one of the groupings (2a), (2b) or (2c) -CH2-CH2-OSO3H(2a) -CH CH2(2b) -CH2-CH2OH(2c) AND N STANDS FOR THE INTEGER 1 OR 2, WHICH ARE VERY SUITABLE FOR DYEING AND PRINTING MATERIALS MADE OF NATURAL CELLULOSE FIBERS, PARTICULARLY COTTON, REGENERATED CELLULOSE FIBERS, LINEN, SILK, POLYAMIDE AND POLYURETHANE FIBERS, ESPECIALLY WOOL, PREFERABLY UTILIZED ACCORDING TO THE TECHNICALLY USUAL DYEING AND PRINTING PROCESSES FOR REACTIVE DYESTUFFS. They posses an excellent affinity towards wool fibers and they are dyed from an acid, weakly acid or neutral dyeing bath at 70*C to 120*C. They are distinguished by a very good color build-up, a good levelness of the dyeings, very good fastnesses to processing and very good fastnesses to use, also on chlorinated wool. A particular characteristic of these dyestuffs is the very good suitability for the preparation of combination dyeings in mixtures with other dyestuffs on account of the fact that the rate of absorption from the dyeing bath on the wool fiber can be controlled by the pH value of the dyebath.
摘要:
Process for dyeing or printing nitrogen containing native or synthetic fibrous materials, such as wool, silk or fibres of polyamide, which comprises the dyeing or printing of the said fibrous materials with a water-soluble dyestuff of the formula
IN WHICH F represents the rest of a monoazo- or 1-amino-4phenyl-amino-anthraquinone-2-sulfonic acid dyestuff, Y represents a direct linkage or one of the groups
OR
Z represents a hydrogen atom or an alkali metal atom or the ammonium group, and n represents the integer 1, 2 or 3, at a temperature between about 20* and about 115* C and at a pH-value between about 4.0 and about 7.5, the dyeings and prints so prepared being distinguished by very good fastness to processing and fastness to wear, such as fastness to wet and fastness to light.
IN WHICH X REPRESENTS A DIRECT LINKAGE,-CH2-, -CH2CH2-,-NH-OR-N(LOWER ALKYL)-, THE BENZENE NUCLEUS IS UNSUBSTITUTED OR SUBSTITUTED BY HYDROGEN, METHYL, LOWER ALKOXY, CARBOXYL, CHLORINE OR BROMINE, AND N STANDS FOR 0 OR 1, THE SAID DYESTUFFS BEING SUITABLE FOR THE DYEING OR PRINTING OF LEATHER OR OF FIBROUS MATERIALS CONSISTING OF WOOL, SILK, LINEAR POLYMIDES, NATIVE OR REGENERATED CELLULOSE FIBRES, THE DYEINGS OR PRINTS OBTAINED ON SAID MATERIALS BEING DISTINGUISHED BY VERY GOOD FASTNESS PROPERTIES TO WETTING AND TO LIGHT.
R REPRESENT HYDROGEN OR LOWER ALKYL, M AND A REPRESENT INTEGERS FROM 0 TO 2, THE SUM OF M AND N BEING AT LEAST 1 AND AT MOST 2, A REPRESENTS THE RADICAL OF A DIZZO COMPONENT FO THE BENZENE AND NAPHTHALENE SERIES, AND K REPRESENTS THE RADICAL OF A COUPLING COMPONENT OF THE MAPHTHALENE, PYRAZOLONE AND ACEO-ACETYLARYLANIDE SERIES, AND THE 1:1 COPPER COMPLEX COMPOUND OR THE 1:2-COBALT-OR 1:2-CHROMIUM COMPLEX COMPOUNDS THEREOF, SAID DYESTUFFS BEING SUITABLE FOR THE DYEING OR PRINTING OF FIBROUS MATERIALS OF NATIVE OR REGENERATED CELLULOSE, WOOL, SILK, POLYAMIDES OR POLYARETHANES, THE DYEINGS AND PRINTS OBTAINED ON CELLULOSE FIBROUS MATERIALS BEING OF INTENSE REDBROWN, DARK BROWN, OLIVE, GREY (BLACK) OR NAVY BLUE SHADES AND BEING DISTINGUISHED BY A VERY GOOD FASTNESS TO LIGHT AND TO WET PROCESSING.