公开(公告)号：US20240376028A1

公开(公告)日：2024-11-14

申请号：US18658300

申请日：2024-05-08

Applicant: Honeywell International Inc.

Inventor： Haiyou Wang ,  Alexey Kruglov ,  Yian Zhai ,  Dimitrios Papanastasiou ,  Sudharsanam Ramanathan ,  Christophe Roger ,  Hsien-cheng YU ,  Akbar Mahdavi-Shakib

IPC: C07C17/23 ,  C07C17/25

Abstract: Production of HFO-1132 and, in particular, HFO-1132E, may be produced from 1,1,2-trichloro-1,2,2-trifluoroethane (CFC-113). In a first step, 1,1,2-trifluoroethane (HFC-143) is produced by hydrogenating 1,1,2-trichloro-1,2,2-trifluoroethane (CFC-113) by reaction with hydrogen in the presence of a catalyst to produce 1,1,2-trifluoroethane (HFC-143). The 1,1,2-trifluoroethane (HFC-143) may then be dehydrofluorinated in the presence of a catalyst to produce trans-1,2-difluoroethylene (HFO-1132E) and/or cis-1,2-difluoroethylene (HFO-1132Z). The cis-1,2-difluoroethylene (HFO-1132Z) may then be isomerized to produce trans-1,2-difluoroethylene (HFO-1132E).

公开(公告)号：US10913697B2

公开(公告)日：2021-02-09

申请号：US16346739

申请日：2017-11-02

Applicant: Honeywell International Inc.

Inventor： Haiyou Wang ,  Hsueh Sung Tung ,  Willie Josue Perez ,  Yian Zhai ,  Ralph John Borowski ,  Fang Huang Tu ,  Lucas Peter Labuda ,  John L. Welch

IPC: C07C17/00 ,  C07C17/395 ,  C07C17/42 ,  C07C21/18

Abstract: The invention relates to a process for reducing the concentration of a fluorinated alkyne impurity, such as 3,3,3-trifluoropropyne (TFPY), in 2,3,3,3-tetrafluoropropene (HFO-1234yf) which comprises contacting such a mixture with a caustic material, such as sodium hydroxide (NaOH), under conditions effective to reduce the concentration of the fluorinated alkyne impurity, including in some practices reducing the concentration by at least about 50%.

公开(公告)号：US10071940B2

公开(公告)日：2018-09-11

申请号：US15709931

申请日：2017-09-20

Applicant: Honeywell International Inc.

Inventor： Rajiv Banavali ,  Haridasan K. Nair ,  Yian Zhai

IPC: C07C17/361

CPC classification number: C07C17/361 ,  Y02P20/582 ,  C07C21/18

Abstract: Disclosed is a process for the formation of a mixture of the compounds 2,3,3,3-tetrafluoropropene (HFO-1234yf) and vinylidene fluoride, comprising pyrolyzing 1,1,2-trifluoro-2-trifluoro-methyl-cyclobutane under conditions effective to produce a reaction product comprising HFO-1234yf and vinylidene fluoride in a 1234yf:vinylidene fluoride molar ratio of from about 0.5 to about 1.2.

公开(公告)号：US09029617B2

公开(公告)日：2015-05-12

申请号：US14330744

申请日：2014-07-14

Applicant: Honeywell International Inc.

Inventor： Haridasan K. Nair ,  David Nalewajek ,  Andrew Joseph Poss ,  Yian Zhai

IPC: C07C17/25 ,  C07C17/04 ,  C07C17/10 ,  C07C17/156 ,  C07C17/354

CPC classification number: C07C17/25 ,  C07C17/04 ,  C07C17/10 ,  C07C17/156 ,  C07C17/354 ,  Y02P20/582 ,  C07C21/18 ,  C07C19/16 ,  C07C19/08 ,  C07C19/10

Abstract: The present invention provides routes for making 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd) from commercially available raw materials. More specifically, this invention provides several routes for forming HCFO-1233zd from 3,3,3-trifluoropropene (FC-1234zf).

Abstract translation: 本发明提供从市售原料制备1-氯-3,3,3-三氟丙烯（HCFO-1233zd）的途径。 更具体地，本发明提供了用于从3,3,3-三氟丙烯（FC-1234zf）形成HCFO-1233zd的若干途径。

公开(公告)号：US20130150632A1

公开(公告)日：2013-06-13

申请号：US13674145

申请日：2012-11-12

Applicant: Honeywell International Inc.

Inventor： Yian Zhai ,  Andrew Joseph Poss ,  Michael Van Der Puy ,  Rajiv Ratna Singh

IPC: C07C17/23 ,  C07C17/358

CPC classification number: C07C17/23 ,  C07B2200/09 ,  C07C17/358 ,  C07C21/18

Abstract: Disclosed is a process for the preparation of cis-1-chloro-3,3,3-trifluoropropene (cis-1233zd) comprising the steps of (a) providing CF3CHClCHCl2 (233da), and (b) treating the 233da with a dechlorinating agent to produce a mixture of compounds including cis-1-chloro-3,3,3-trifluoropropene, preferably wherein the amount of the cis-isomer generated in the reaction is not less than 30%.

Abstract translation: 公开了制备顺式-1-氯-3,3,3-三氟丙烯（顺式-1233zd）的方法，包括以下步骤：（a）提供CF 3 CHClCHCl 2（233da），和（b）用脱氯剂处理233da 以产生包括顺式-1-氯-3,3,3-三氟丙烯的化合物的混合物，优选其中在反应中产生的顺式异构体的量不小于30％。

公开(公告)号：US20240279520A1

公开(公告)日：2024-08-22

申请号：US18379954

申请日：2023-10-13

Applicant: Honeywell International Inc.

Inventor： Yian Zhai ,  Sudharsanam Ramanathan ,  Pramod K.W. Harikumar Warrier ,  Alexey Kruglov ,  Dimitrios Papanastasiou ,  Christophe Roger

IPC: C09K5/04

CPC classification number: C09K5/041 ,  C09K2205/112

Abstract: The fluoroether 3-(difluoromethoxy)-1,1,1,2,2-pentafluoropropane (“HFE-347mcf”) may be used as a refrigerant and/or heat transfer composition, such as in single phase and two phase cooling systems, and a method of heating and/or cooling an electronic component or device includes providing a heat transfer fluid comprising at least about 10% by weight of 3-(difluoromethoxy)-1,1,1,2,2-pentafluoropropane, and transferring heat between the electronic component and the heat transfer fluid. The fluoroether 3-(difluoromethoxy)-1,1,1,2,2-pentafluoropropane may be synthesized by reacting 2,2,3,3,3-pentafluoro-1-propanol with chlorodifluoromethane (R-22).

公开(公告)号：US09856193B2

公开(公告)日：2018-01-02

申请号：US15582981

申请日：2017-05-01

Applicant: Honeywell International Inc.

Inventor： Haridasan K. Nair ,  Rajiv Banavali ,  Yian Zhai ,  Glenn Matthies

IPC: C07C17/275

CPC classification number: C07C17/275 ,  C07C2601/04 ,  C07C23/06

Abstract: The production of 1,1,2-trifluoro-2-(trifluoromethyl)cyclobutane (TFMCB). More specifically, the present invention relates to a process for making 1,1,2-trifluoro-2-(trifluoromethyl)cyclobutane via a continuous catalytic reaction from commercially available raw materials ethylene and hexafluoropropene.

公开(公告)号：US09790151B2

公开(公告)日：2017-10-17

申请号：US15345695

申请日：2016-11-08

Applicant: Honeywell International Inc.

Inventor： Rajiv Banavali ,  Haridasan K. Nair ,  Yian Zhai

IPC: C07C17/361

CPC classification number: C07C17/361 ,  Y02P20/582 ,  C07C21/18

Abstract: Disclosed is a process for the formation of a mixture of the compounds 2,3,3,3-tetrafluoropropene (1234yf) and vinylidene fluoride, comprising pyrolyzing 1,1,2-trifluoro-2-trifluoro-methyl-cyclobutane under conditions effective to produce a reaction product comprising 1234yf and vinylidene fluoride in a 1234yf:vinylidene fluoride molar ratio of from about 0.5 to about 1.2.

公开(公告)号：US20130150634A1

公开(公告)日：2013-06-13

申请号：US13674160

申请日：2012-11-12

Applicant: Honeywell International Inc.

Inventor： Yian Zhai ,  Andrew Joseph Poss ,  Rajiv Ratna Singh

IPC: C07C17/20 ,  C07C17/013

CPC classification number: C07C17/206 ,  C07C17/013 ,  C07C17/04 ,  C07C17/20 ,  C07C17/208 ,  C07C19/01 ,  C07C19/10

Abstract: Disclosed is a process for making the compound 1,1,2-trichloro-3,3,3-trifluoro-propane (233da) by the catalytic fluorination of 1,1,1,2,3,3-hexachloropropane. 233da is a starting material used in the production cis-1-chloro-3,3,3-trifluoropropene (cis-1233zd).

Abstract translation: 公开了通过1,1,1,2,3,3-六氯丙烷的催化氟化制备化合物1,1,2-三氯-3,3,3-三氟丙烷（233da）的方法。 233da是用于生产顺式-1-氯-3,3,3-三氟丙烯（顺式-1233zd）的原料。

公开(公告)号：US20130150633A1

公开(公告)日：2013-06-13

申请号：US13674177

申请日：2012-11-12

Applicant: Honeywell International Inc.

Inventor： Yian Zhai ,  Andrew Joseph Poss ,  Rajiv Ratna Singh

IPC: C07C17/10

CPC classification number: C07C17/10 ,  C07C17/087 ,  C07C21/18

Abstract: Disclosed is a process for making cis-1-chloro-3,3,3-trifluoropropene comprising reacting 3,3,3-trifluoropropyne with HCl in a reaction vessel at a yield of at least about 80%.

Abstract translation: 公开了一种制备顺式-1-氯-3,3,3-三氟丙烯的方法，包括使反应容器中的3,3,3-三氟丙炔与HCl在至少约80％的收率下反应。