公开(公告)号：US20230373889A1

公开(公告)日：2023-11-23

申请号：US18031542

申请日：2021-10-08

申请人： Resonac Corporation

发明人： Atsushi SUZUKI

IPC分类号： C07C17/42

CPC分类号： C07C17/42

摘要： Provided is a method for storing a fluoro-2-butene by which isomerization reaction is unlikely to proceed during storage. A fluoro-2-butene represented by general formula C4HxFy where x is 0 or more and 7 or less, y is 1 or more and 8 or less, and x+y is 8 contains or does not contain hydrogen fluoride as an impurity. The fluoro-2-butene is stored in a container in which the concentration of hydrogen fluoride is 100 ppm by volume or less in a gas phase portion when the fluoro-2-butene contains hydrogen fluoride.

公开(公告)号：US20220396537A1

公开(公告)日：2022-12-15

申请号：US17774053

申请日：2020-11-05

申请人： Honeywell International Inc.

发明人： Haluk Kopkalli ,  Daniel C. Merkel ,  Hang T. Pham

IPC分类号： C07C17/383 ,  C07C17/42 ,  C07C21/18 ,  C07C21/04 ,  B01J23/644

摘要： Heterogenous azeotrope or azeotrope-like compositions comprising 2-chloro-3,3,3-trifluoropropene (HFCO-1233xf) and water which may include from about 0.09 wt. % to about 92.69 wt. % 2-chloro-3,3,3-trifluoropropene (HFCO-1233xf) and from about 7.31 wt. % to about 99.91 wt. % water and having a boiling point between about 12.0° C. and about 13.6° C. at a pressure of between about 12.5 psia and about 16.5 psia. The azeotrope or azeotrope-like compositions may be used to separate impurities, including water, from 2-chloro-3,3,3-trifluoropropene (HFCO-1233xf).

公开(公告)号：US20200055804A1

公开(公告)日：2020-02-20

申请号：US16346739

申请日：2017-11-02

申请人： Honeywell International Inc.

发明人： Haiyou Wang ,  Hsueh Sung Tung ,  Willie Josue Perez ,  Yian Zhai ,  Ralph John Borowski ,  Fang Huang Tu ,  Lucas Peter Labuda ,  John L. Welch

IPC分类号： C07C17/395 ,  C07C17/42

摘要： The invention relates to a process for reducing the concentration of a fluorinated alkyne impurity, such as 3,3,3-trifluoropropyne (TFPY), in 2,3,3,3-tetrafluoropropene (HFO-1234yf) which comprises contacting such a mixture with a caustic material, such as sodium hydroxide (NaOH), under conditions effective to reduce the concentration of the fluorinated alkyne impurity, including in some practices reducing the concentration by at least about 50%.

公开(公告)号：US10131597B2

公开(公告)日：2018-11-20

申请号：US14355894

申请日：2012-11-02

申请人： HONEYWELL INTERNATIONAL INC.

发明人： Haiyou Wang ,  Hsueh Sung Tung ,  Selma Bektesevic ,  Daniel C. Merkel ,  Haluk Kopkalli ,  Yuon Chiu

IPC分类号： C07C17/20 ,  B01J23/26 ,  C07C17/087 ,  C07C17/25 ,  C07C17/42 ,  B01J21/04 ,  B01J23/34 ,  B01J23/745 ,  B01J23/75 ,  B01J23/755 ,  B01J27/10 ,  B01J27/12 ,  B01J27/138

摘要： The present invention relates, in part, to the discovery that, during the fluorination of certain fluoroolefin starting reagents, oligomerization/polymerization of such reagents reduces the conversion process and leads to increased catalyst deactivation. The present invention also illustrates that vaporizing such starting reagents in the presence of one or more organic co-feed reduces such oligomerization/polymerization and improves catalytic stability.

公开(公告)号：US20180148395A1

公开(公告)日：2018-05-31

申请号：US15878794

申请日：2018-01-24

申请人： ARKEMA FRANCE

发明人： Wissam RACHED ,  Sophie GUERIN ,  Pascale KINDLER

IPC分类号： C07C17/42 ,  F01K25/10 ,  C09K5/04 ,  C07C21/18

CPC分类号： C07C17/42 ,  C09K5/044 ,  C09K2205/12 ,  F01K25/10 ,  C07C21/18

摘要： The use of a C3 to C6 alkene compound including a sole double bond, for limiting or preventing the isomerization of trans-1-chloro-3,3,3-trifluoropropene to cis-1-chloro-3,3,3-trifluoropropene. Also, a composition including 1-chloro-3,3,3-trifluoropropene and a C3 to C6 alkene compound including a sole double bond, and also to various uses of this composition, such as a process for heating or cooling a fluid.

公开(公告)号：US09908828B2

公开(公告)日：2018-03-06

申请号：US15073108

申请日：2016-03-17

申请人： ARKEMA FRANCE

发明人： Wissam Rached ,  Sophie Guerin ,  Pascale Kindler

IPC分类号： C09K5/04 ,  C07C17/42 ,  F01K25/10

CPC分类号： C07C17/42 ,  C09K5/044 ,  C09K2205/12 ,  F01K25/10 ,  C07C21/18

摘要： The use of a C3 to C6 alkene compound including a sole double bond, for limiting or preventing, for example, the isomerization of trans-1-chloro-3,3,3-trifluoropropene to cis-1-chloro-3,3,3-trifluoropropene. Also, a composition including 1-chloro-3,3,3-trifluoropropene and a C3 to C6 alkene compound including a sole double bond, and also to various uses of this composition.

公开(公告)号：US20180044268A1

公开(公告)日：2018-02-15

申请号：US15553592

申请日：2016-02-23

申请人： DAIKIN INDUSTRIES, LTD.

发明人： Daisuke KARUBE ,  Satoshi OHISHI ,  Michiaki OKADA

IPC分类号： C07C17/25 ,  C07C17/16 ,  C07C17/42 ,  C09K5/04

CPC分类号： C07C17/25 ,  C07B61/00 ,  C07C17/16 ,  C07C17/42 ,  C07C19/10 ,  C07C21/18 ,  C09K5/04

摘要： The present invention provides a method for producing 1233yd that enables high conversion of the starting compound and high selectivity of 1233yd.The present invention provide a method for producing 1-chloro-2,3,3-trifluoropropene (1233yd), comprising the step of dehydrofluorinating 3-chloro-1,1,2,2-tetrafluoropropane (244ca).

公开(公告)号：US09573867B2

公开(公告)日：2017-02-21

申请号：US14986750

申请日：2016-01-04

申请人： HONEYWELL INTERNATIONAL INC.

发明人： Daniel C. Merkel ,  Hsueh S. Tung

IPC分类号： C07C17/25 ,  C07C19/08 ,  C07C17/087 ,  C07C17/20 ,  C07C17/42 ,  C07C21/18 ,  C07C17/06

CPC分类号： C07C17/206 ,  C07C17/06 ,  C07C17/087 ,  C07C17/20 ,  C07C17/25 ,  C07C17/42 ,  C07C21/18

摘要： The present invention relates to an improved method for manufacturing 2-chloro-3,3,3-trifluoropropene, (HCFC-1233xf) by reacting 1,1,2,3-tetrachloropropene, 1,1,1,2,3-pentachloropropane, and/or 2,3,3,3-tetrachloropropene with hydrogen fluoride, in a vapor phase reaction vessel in the presence of a vapor phase fluorination catalyst and stabilizer. HCFC-1233xf is an intermediate in the production of 2,3,3,3-tetrafluoropropene (HFO-1234yf) which is a refrigerant with low global warming potential.

摘要翻译： 本发明涉及一种用于制备2-氯-3,3,3-三氟丙烯（HCFC-1233xf）的改进方法，其通过使1,1,2,3-四氯丙烯，1,1,1,2,3-五氯丙烷 ，和/或2,3,3,3-四氯丙烯与氟化氢在气相反应容器中在气相氟化催化剂和稳定剂存在下反应。 HCFC-1233xf是生产2,3,3,3-四氟丙烯（HFO-1234yf）的中间体，它是具有低全球变暖潜能的制冷剂。

公开(公告)号：US09120716B2

公开(公告)日：2015-09-01

申请号：US13879435

申请日：2010-10-22

申请人： Laurent Wendlinger ,  Philippe Bonnet ,  Anne Pigamo ,  Nicolas Doucet

发明人： Laurent Wendlinger ,  Philippe Bonnet ,  Anne Pigamo ,  Nicolas Doucet

IPC分类号： C07C17/25 ,  C07C17/383 ,  C07C17/20 ,  C07C17/42 ,  C07C21/18

CPC分类号： C07C17/25 ,  C07C17/206 ,  C07C17/383 ,  C07C17/42 ,  C07C21/18

摘要： The present invention provides a process for preparing 2,3,3,3-tetrafluoropropene, comprising the following steps: (a) catalytic reaction of 1,1,1,2,3-pentachloropropane and/or 1,1,2,2,3-pentachloropropane with HF into product 2-chloro-3,3,3-trifluoropropene; (b) catalytic reaction of the thus-obtained 2-chloro-3,3,3-trifluoropropene into 2,3,3,3-tetrafluoropropene.

摘要翻译： 本发明提供一种制备2,3,3,3-四氟丙烯的方法，包括以下步骤：（a）1,1,1,2,3-五氯丙烷和/或1,1,2,2 与HF的3-五氯丙烷反应制成2-氯-3,3,3-三氟丙烯; （b）将由此得到的2-氯-3,3,3-三氟丙烯催化反应成2,3,3,3-四氟丙烯。

公开(公告)号：US09090531B2

公开(公告)日：2015-07-28

申请号：US13804738

申请日：2013-03-14

申请人： Honeywell International Inc.

发明人： Haiyou Wang ,  Huseh Sung Tung ,  Selma Bektesevic

IPC分类号： C07C17/25 ,  C07C17/38 ,  C07C17/383 ,  C07C17/42 ,  C07C21/04 ,  C07C17/278 ,  C07C17/386

CPC分类号： C07C17/42 ,  C07C17/25 ,  C07C17/278 ,  C07C17/38 ,  C07C17/386 ,  C07C21/04

摘要： This invention is directed to a method for mitigating HCl generation during 1230xa purification, which comprises the steps of; (a) adding a chelating agent into 1230xa crude, and (b) conducting the 1230xa purification in the presence of said chelating agent at a quantity sufficient to reduce or prevent 1230xa decomposition. Examples of chelating agent include tributyl phosphate (TBP), tripropyl phosphate (TPP), and triethyl phosphate (TEP). The concentration of chelating agent in 1230xa crude can range from 0.001 to 20 wt %, preferably from 0.01 to 10 wt %, and more preferably from 0.1 to 5 wt %.

摘要翻译： 本发明涉及一种减轻1230xa纯化期间HCl产生的方法，其包括以下步骤： （a）向1230xa粗品中加入螯合剂，和（b）在所述螯合剂存在下，以足以减少或防止1230×分解的量进行1230xa纯化。 螯合剂的实例包括磷酸三丁酯（TBP），磷酸三丙基酯（TPP）和磷酸三乙酯（TEP）。 1230xa原料中螯合剂的浓度可以为0.001〜20重量％，优选为0.01〜10重量％，更优选为0.1〜5重量％。