公开(公告)号：US5360857A

公开(公告)日：1994-11-01

申请号：US32692

申请日：1993-03-17

申请人： Hajime Kitamura ,  Susumu Ueno ,  Mikio Watanabe ,  Masahiro Usuki ,  Toshihiko Nakano

发明人： Hajime Kitamura ,  Susumu Ueno ,  Mikio Watanabe ,  Masahiro Usuki ,  Toshihiko Nakano

IPC分类号： C08F2/00 ,  C08K5/07

CPC分类号： C08F2/004

摘要： A polymer scale preventive agent for use in polymerization of vinyl chloride monomer or a monomer mixture containing vinyl chloride monomer as a major component, comprising:(A) a naphthoquinone natural dye and(B) a polyvinyl alcohol with a saponification degree of at least 50 mol %. The polymer scale preventive agent is formed as coating on the inner wall, etc. of a polymerization vessel. Deposition of polymer scale can be always effectively prevented. Polymers with a high whiteness can be produced, and products formed from the polymer have only a small number of fish eyes.

摘要翻译： 一种用于聚合氯乙烯单体或含有氯乙烯单体作为主要成分的单体混合物的聚合物防垢剂，包括：（A）萘醌天然染料和（B）皂化度至少为50的聚乙烯醇 mol％。 聚合物垢防止剂形成为聚合容器的内壁等上的涂层。 总能有效防止聚合物垢的沉积。 可以生产高白度的聚合物，由聚合物形成的产品只有少量的鱼眼。

公开(公告)号：US5430113A

公开(公告)日：1995-07-04

申请号：US261300

申请日：1994-06-16

申请人： Masahiro Usuki ,  Hajime Kitamura ,  Susumu Ueno ,  Mikio Watanabe ,  Masayoshi Yono

发明人： Masahiro Usuki ,  Hajime Kitamura ,  Susumu Ueno ,  Mikio Watanabe ,  Masayoshi Yono

IPC分类号： C08F2/00

CPC分类号： C08F2/004

摘要： A process to prevent scale adhesion on reactor surfaces when polymerizing vinyl monomers. Coating of internal reactor surfaces with a combination of an amino containing aromatic compound, and an alkali metal or ammonium salt of polyvinylsulfuric acid results in the scale prevention. This combination is applied to reactor surfaces via its mixture with a solvent and is subsequently dried to form the coating.

摘要翻译： 一种在聚合乙烯基单体时防止反应器表面附着垢的方法。 用含氨基的芳族化合物和聚乙烯基硫酸的碱金属盐或铵盐的组合涂覆内部反应器表面导致防垢。 这种组合通过其与溶剂的混合物施加到反应器表面，随后干燥以形成涂层。

公开(公告)号：US5354817A

公开(公告)日：1994-10-11

申请号：US870953

申请日：1992-04-20

申请人： Masahiro Usuki ,  Hajime Kitamura ,  Susumu Ueno ,  Mikio Watanabe ,  Richard W. Armentrout ,  Thomas J. Pollock

发明人： Masahiro Usuki ,  Hajime Kitamura ,  Susumu Ueno ,  Mikio Watanabe ,  Richard W. Armentrout ,  Thomas J. Pollock

IPC分类号： C08F2/00

CPC分类号： C08F2/004

摘要： A polymer scale preventive agent for use in polymerization of a haloethylene or a monomer mixture containing the same, comprising:(A) an aromatic compound having at least one group selected from the class consisting of primary, secondary and tertiary amino groups, quaternary ammonium groups and the azo group and/or a dye having at least one group selected from said class, and(B) an alkali metal or ammonium salt of a polyvinylsulfonic acid, and(C) a naphthoquinone natural dye; a polymerization vessel having a coating comprising said scale preventive agnet. A process of preparing a haloethylene polymer using the vessel can produce a polymer of high quality without polymer scale deposition.

摘要翻译： 一种用于聚合卤代乙烯或含有它们的单体混合物的聚合物防垢剂，其包含：（A）具有至少一个选自伯，仲和叔氨基的基团的芳族化合物，季铵基 和偶氮基和/或具有选自所述类别的至少一个基团的染料和（B）聚乙烯基磺酸的碱金属盐或铵盐，和（C）萘醌天然染料; 一种聚合容器，其具有包含防垢剂防腐剂的涂层。 使用该容器制备卤代乙烯聚合物的方法可以生产高质量的聚合物，而没有聚合物垢沉积。

公开(公告)号：US5241022A

公开(公告)日：1993-08-31

申请号：US824086

申请日：1992-01-22

申请人： Mikio Watanabe ,  Hajime Kitamura ,  Susumu Ueno ,  Masahiro Usuki ,  Masayoshi Yono

发明人： Mikio Watanabe ,  Hajime Kitamura ,  Susumu Ueno ,  Masahiro Usuki ,  Masayoshi Yono

IPC分类号： C08F2/00

CPC分类号： C08F2/004

摘要： The present invention relates to a coating solution for preventing adhesion of polymer scale and a method for preventing scale adhesion during preparation of polymers which can provide polymers having high quality without coloring thereof while preventing adhesion of polymer scale to a polymerizer when a monomer having an ethylenically unsaturated double bond is polymerized. A coating solution for preventing adhesion of polymer scale which comprises anaphthoquinone natural dyestuffs, anthraquinone natural dyestuffs, tannin natural dyestuffs, xanthone natural dyestuffs, flavonoid natural dyestuffs, or/and benzoquinone natural dyestuffs and a polyvinyl alcohol having a degree of saponification of not less than 70 mole % was applied on at least a part of a polymerizer which comes in contact with a monomer having an ethylenically unsaturated double bond and was dried to give a coating film during polymerization thereof.

公开(公告)号：US5432241A

公开(公告)日：1995-07-11

申请号：US261296

申请日：1994-06-16

申请人： Masahiro Usuki ,  Mikio Watanabe ,  Susumu Ueno

发明人： Masahiro Usuki ,  Mikio Watanabe ,  Susumu Ueno

IPC分类号： C08F2/00

CPC分类号： C08F2/004

摘要： A process to prevent scale adhesion on rector surfaces when polymerizing vinyl esters, vinyl esthers, carboxylic acids, styrene or diene monomers. Coating of internal reactor surfaces with a combination of an amino containing aromatic compound, and an alkali metal or ammonium salt of polyvinylsulfuric acid results in the scale prevention. This combination is applied to reactor surfaces via its mixture with a solvent and is subsequently dried to form the coating.

摘要翻译： 当乙烯基酯，乙烯基酯，羧酸，苯乙烯或二烯单体聚合时，防止水份附着在反应器表面上的方法。 用含氨基的芳族化合物和聚乙烯基硫酸的碱金属盐或铵盐的组合涂覆内部反应器表面导致防垢。 这种组合通过其与溶剂的混合物施加到反应器表面，随后干燥以形成涂层。

公开(公告)号：US5292834A

公开(公告)日：1994-03-08

申请号：US727901

申请日：1991-07-10

申请人： Mikio Watanabe ,  Masahiro Usuki ,  Susumu Ueno

发明人： Mikio Watanabe ,  Masahiro Usuki ,  Susumu Ueno

IPC分类号： C08F2/00

CPC分类号： C08F2/004

摘要： A method of preventing polymer scale deposition in a polymerization vessel in polymerization of a particular monomer having an ethylenic double bond having a high dissolving power against the conventional scale preventive coatings, wherein said polymerization is carried out in a polymerization vessel of which the inner wall has been previously coated with a first coating liquid comprising:(A) a water-soluble anionic dye, and(B) a metal salt, to form a first coating, and the first coating thus formed has been then coated with a second coating liquid comprising:(C) an alkaline earth metal compound, and at least one member selected from the group consisting of:(D) a water-soluble anionic dye and(E) an inorganic colloid,to form a second coating. Polymer scale deposition can be effectively prevented.

摘要翻译： 一种防止聚合容器在聚合反应器中聚合具有对常规防垢涂料具有高溶解力的烯属双键的聚合物的方法，其中所述聚合在内壁具有的聚合容器中进行 预先涂覆有第一涂布液体，其包含：（A）水溶性阴离子染料和（B）金属盐，以形成第一涂层，然后用如此形成的第一涂层涂覆第二涂布液，所述第二涂布液包含 （C）碱土金属化合物和选自（D）水溶性阴离子染料和（E）无机胶体）中的至少一种，以形成第二涂层。 可以有效地防止聚合物垢沉积。

公开(公告)号：US5262497A

公开(公告)日：1993-11-16

申请号：US894646

申请日：1992-06-05

申请人： Mikio Watanabe ,  Masahiro Usuki ,  Susumu Ueno

发明人： Mikio Watanabe ,  Masahiro Usuki ,  Susumu Ueno

IPC分类号： C08F2/00 ,  C08F14/06 ,  C08F20/0644

CPC分类号： C08F2/004

摘要： Polymer scale deposition from a polymerization medium in which a monomer having an ethylenic double bond is polymerized, is prevented by conducting the polymerization in a polymerization vessel having a coating by applying a liquid comprising (A) an organic compound containing at least one member selected from the group consisting of a sulfonic acid group and a carboxylic acid group and having a molecular weight of 1000 or less and (B) a water-insoluble compound having an absorption band in the visible light range of 540 to 750 nm, the compounds (A) and (B) having been dissolved or dispersed in (C) an ester-based organic solvent, and having a pH of 3 or less; to the inner wall surfaces of said polymerization vessel. Polymer scale can be effectively prevented and polymeric products are barely colored.

摘要翻译： 通过在包含（A）含有至少一种选自以下的物质的有机化合物的液体中进行聚合，可以防止在具有烯属双键的单体聚合的聚合介质中进行聚合， 由磺酸基和羧酸基组成的组，分子量为1000以下，（B）在54​​0〜750nm的可见光范围具有吸收带的水不溶性化合物，化合物（A ）和（B）已经溶解或分散在（C）酯类有机溶剂中，并且pH为3以下; 到所述聚合容器的内壁表面。 可以有效地防止聚合物垢，聚合物几乎不着色。

公开(公告)号：US5244986A

公开(公告)日：1993-09-14

申请号：US941767

申请日：1992-09-04

申请人： Mikio Watanabe ,  Masahiro Usuki ,  Susumu Ueno

发明人： Mikio Watanabe ,  Masahiro Usuki ,  Susumu Ueno

IPC分类号： C08F2/00

CPC分类号： C08F2/004

摘要： A method of preventing polymer scale deposition in a polymerization vessel in polymerization of a particular monomer having an ethylenic double bond having a high dissolving power against the conventional scale preventive coatings, wherein said polymerization is carried out in a polymerization vessel of which the inner wall has been previously coated with a first coating solution comprising:(A) a water-soluble anionic dye, and(B) at least one member selected from the group consisting of inorganic colloids and cationic dyes, to form a first coating, and the first coating thus formed has been then coated with a second coating solution comprising:(C) an alkaline earth metal compound, and at least one member selected from the group consisting of:(D) a water-soluble anionic dye and(E) an inorganic colloid, to form a second coating. The polymerization vessel having the double coating as prepared above is also disclosed. Polymer scale deposition can be effectively prevented.

摘要翻译： 一种防止聚合容器在聚合反应器中聚合具有对常规防垢涂料具有高溶解力的烯属双键的聚合物的方法，其中所述聚合在内壁具有的聚合容器中进行 预先涂覆有第一涂布溶液，其包含：（A）水溶性阴离子染料和（B）至少一种选自无机胶体和阳离子染料的成分，以形成第一涂层，并且第一涂层 这样形成的涂层已经涂覆有第二涂层溶液，其包括：（C）碱土金属化合物和至少一种选自以下的组分：（D）水溶性阴离子染料和（E）无机胶体 ，以形成第二涂层。 还公开了具有如上制备的双层涂层的聚合容器。 可以有效地防止聚合物垢沉积。

公开(公告)号：US5147455A

公开(公告)日：1992-09-15

申请号：US705644

申请日：1991-05-24

申请人： Mikio Watanabe ,  Masahiro Usuki ,  Susumu Ueno

发明人： Mikio Watanabe ,  Masahiro Usuki ,  Susumu Ueno

IPC分类号： C08F2/00 ,  C08F2/44

CPC分类号： C08F2/004

摘要： A method of preventing polymer scale deposition during polymerization of a monomer having an ethylenically double bond in a polymerization vessel, comprising the step of carrying out said polymerization in a polymerization vessel of which the inner wall surface has a coating comprising a water-soluble polysaccharide; and a polymer scale preventive agent comprising polysaccharide. By use of the method or agent, deposition of polymer scale can be effectively prevented; in addition, polymers with a high whiteness can be prepared. Moreover, the scale preventive agent used has no poisonousness or the like and is highly safe.

摘要翻译： 在聚合容器中具有烯键式双键的单体聚合期间防止聚合物垢沉积的方法，包括在其内壁表面具有包含水溶性多糖的涂层的聚合容器中进行所述聚合的步骤; 以及包含多糖的聚合物垢预防剂。 通过使用该方法或试剂，可以有效地防止聚合物垢的沉积; 此外，可以制备具有高白度的聚合物。 此外，所使用的防垢剂没有毒性等，并且是高度安全的。

公开(公告)号：US5142003A

公开(公告)日：1992-08-25

申请号：US717567

申请日：1991-06-19

申请人： Masahiro Usuki ,  Mikio Watanabe ,  Susumu Ueno

发明人： Masahiro Usuki ,  Mikio Watanabe ,  Susumu Ueno

IPC分类号： C08F2/00

CPC分类号： C08F2/004

摘要： Scale deposits during polymerization of monomers containing ethylene-type double bonds are prevented by coating the reactor walls and parts with cationic dyes oxidized with hydrogen peroxide.