公开(公告)号：US4161594A

公开(公告)日：1979-07-17

申请号：US541911

申请日：1975-01-17

申请人： Hans Batzer ,  Jurgen Habermeier ,  Daniel Porret

发明人： Hans Batzer ,  Jurgen Habermeier ,  Daniel Porret

IPC分类号： C07D233/72 ,  C07D239/22 ,  C07D239/54 ,  C07D239/62 ,  C08G59/10 ,  C08G59/26 ,  C08G59/38

CPC分类号： C07D239/22 ,  C07D233/72 ,  C07D239/54 ,  C07D239/62 ,  C08G59/10 ,  C08G59/26 ,  C08G59/38

摘要： New dialcohols of mononuclear, five-membered or six-membered, unsubstituted or substituted N-heterocyclic compounds which contain two NH-groups in the molecule, by reaction of mononuclear, five-membered or six-membered, unsubstituted or substituted N-heterocyclic compounds, for example hydantoin, barbituric acid, uracil, dihydrouracil, parabanic acid and the corresponding derivatives, with ethylene oxide or propylene oxide to give dialcohols. These diols are useful as intermediates for the preparation of polymers, such as polyesters or polyurethanes, or of epoxy resins.

摘要翻译： 通过单核，五元或六元未取代或取代的N-杂环化合物的反应，分子中含有两个NH-基团的单核，五元或六元未取代或取代的N-杂环化合物的新二醇 ，例如乙内酰脲，巴比妥酸，尿嘧啶，二氢尿嘧啶，对an酸及其衍生物与环氧乙烷或环氧丙烷反应，得到二醇。 这些二醇可用作制备聚合物如聚酯或聚氨酯或环氧树脂的中间体。

公开(公告)号：US4007199A

公开(公告)日：1977-02-08

申请号：US593916

申请日：1975-07-07

申请人： Jurgen Habermeier ,  Hans Batzer ,  Daniel Porret

发明人： Jurgen Habermeier ,  Hans Batzer ,  Daniel Porret

IPC分类号： C08G59/32 ,  C07D49/32

CPC分类号： C08G59/3245

摘要： The polyglycidyl compounds according to the invention can be manufactured by reacting epihalogenohydrin with compounds of the formula IV ##STR1## or the formula V ##STR2## in which 1.) n denotes 2, 3 or 4, 2.) A represents a 2-valent, 3-valent or 4-valent organic radical which either contains a N-heterocyclic or cycloaliphatic ring or 2 N-heterocyclic rings or 2 phenylene rings, 3.) either B denotes the --CH.sub.2.O.CO-- radical and m denotes the number 1, or B denotes the radical ##STR3## and m denotes 0, and 4.) R.sup.1 represents a divalent radical, which contains at least one hydrantoin ring or uracil ring. During the reaction hydrogen halide splits off. From curable mixtures containing polyglycidyl compounds according to the invention and a curing agent such as hexahydrophthalic anhydride or phthalic anhydride are obtained products with good mechanical and electrical properties.

摘要翻译： 根据本发明的多缩水甘油化合物可以通过使表卤代醇与式IV（IV）或式V（VI）的化合物反应制备，其中1.）n表示2,3或4,2。 ）A表示2-价，3价或4价有机基团，其含有N-杂环或脂环族环或2个N-杂环或2个亚苯基环。3）B表示-CH 2 O. CO-基，m表示数1，或B表示基团，且m表示0和4.）R1表示含有至少一个环氨基环或尿嘧啶环的二价基团。 反应期间卤化氢分解。 由含有本发明的聚缩水甘油基化合物和固化剂如六氢邻苯二甲酸酐或邻苯二甲酸酐的可固化混合物得到具有良好机械和电学性能的产品。

公开(公告)号：US3956309A

公开(公告)日：1976-05-11

申请号：US591678

申请日：1975-06-30

申请人： Jurgen Habermeier ,  Hans Batzer ,  Daniel Porret

发明人： Jurgen Habermeier ,  Hans Batzer ,  Daniel Porret

IPC分类号： C08G59/32 ,  C07D233/72

CPC分类号： C08G59/3245

摘要： The polyglycidyl compounds according to the invention can be manufactured by reacting epihalogenohydrin with compounds of the formula IV ##EQU1## OR THE FORMULA V ##EQU2## in which (1.) n denotes 2, 3 or 4, (2.) A represents a 2-valent, 3-valent or 4-valent organic radical which either contains a N-heterocyclic or cycloaliphatic ring or 2 N-heterocyclic rings or 2 phenylene rings, (3.) either B deontes the --CH.sub.2.O.CO--radical and m denotes the number 1, or B denotes the radical ##EQU3## and m denotes 0, and 4.) R.sup.1 represents a divalent radical, which contains at least one hydrantoin ring or uracil ring. During the reaction hydrogen halide splits off. From curable mixtures containing polyglycidyl compounds according to the invention and a curing agent such as hexahydrophthalic anhydride or phthalic anhydride are obtained products with good mechanical and electrical properties.

摘要翻译： 根据本发明的多缩水甘油化合物可以通过使表卤代醇与式IVA-CH2-CH-CH2-R1H（IV）| OHn或式V CH2CH2角度HR1-CHC（H）的化合物反应来制备， mB-CHCH-R 1 H（V）||| CHCH 2 CH 2 CH|| HO角度OH CH 2 CH 2其中（1）n表示2,3或4，（2）A表示2价，3价或 含有N-杂环或脂环族环或2个N-杂环或2个亚苯基环的4价有机基团，（3）B是-CH 2 O.CO-基团，m表示数字1，或 B表示自由基CH 2 - O角度CH-CH 2 -O，m表示0和4.）R 1表示含有至少一个环氨基环或尿嘧啶环的二价基团。 反应期间卤化氢分解。 由含有本发明的聚缩水甘油基化合物和固化剂如六氢邻苯二甲酸酐或邻苯二甲酸酐的可固化混合物得到具有良好机械和电学性能的产品。

公开(公告)号：US4227005A

公开(公告)日：1980-10-07

申请号：US956523

申请日：1978-10-31

申请人： Hans Batzer ,  Jurgen Habermeier ,  Daniel Porret

发明人： Hans Batzer ,  Jurgen Habermeier ,  Daniel Porret

IPC分类号： C07D233/72 ,  C07D239/22 ,  C07D239/54 ,  C07D239/62 ,  C08G59/10 ,  C08G59/26 ,  C08G59/38 ,  C07D233/74

CPC分类号： C07D239/22 ,  C07D233/72 ,  C07D239/54 ,  C07D239/62 ,  C08G59/10 ,  C08G59/26 ,  C08G59/38 ,  Y10S525/908

摘要： New dialcohols of mononuclear, five-membered or six-membered, unsubstituted or substituted N-heterocyclic compounds which contain two NH-groups in the molecule, by reaction of mononuclear, five-membered or six-membered, unsubstituted or substituted N-heterocyclic compounds, for example hydantoin, barbituric acid, uracil, dihydrouracil, parabanic acid and the corresponding derivatives, with ethylene oxide or propylene oxide to give dialcohols. These diols are useful as intermediates for the preparation of polymers, such as polyesters or polyurethanes, or of epoxy resins.

公开(公告)号：US4052366A

公开(公告)日：1977-10-04

申请号：US582041

申请日：1975-05-29

申请人： Jurgen Habermeier ,  Hans Batzer ,  Daniel Porret

发明人： Jurgen Habermeier ,  Hans Batzer ,  Daniel Porret

IPC分类号： C07D233/72 ,  C08G59/32 ,  C08G59/04 ,  C08G59/26

CPC分类号： C07D233/72 ,  C08G59/3245

摘要： The polyglycidyl compounds according to the invention can be manufactured by reacting epihalogenohydrin with compounds of the formula IV ##STR1## or the formula V ##STR2## in which (1) n denotes 2, 3 or 4, (2) A represents a 2-valent, 3-valent or 4-valent organic radical which either contains a N-heterocyclic or cycloaliphatic ring or 2 N-heterocyclic rings or 2 phenylene rings, (3) either D denotes the --CH.sub.2.O.CO-- radical and m denotes the number 1, or D denotes the radical ##STR3## and m denotes O, and (4) R.sup.1 represents a divalent radical, which contains at least one hydantoin ring or uracil ring. During the reaction hydrogen halide splits off. From curable mixtures containing polyglycidyl compounds according to the invention and a curing agent such as hexahydrophthalic anhydride or phthalic anhydride are obtained products with good mechanical and electrical properties.

公开(公告)号：US3998837A

公开(公告)日：1976-12-21

申请号：US590550

申请日：1975-06-26

申请人： Jurgen Habermeier ,  Hans Batzer ,  Daniel Porret

发明人： Jurgen Habermeier ,  Hans Batzer ,  Daniel Porret

IPC分类号： C08G59/32 ,  C07D405/14

CPC分类号： C08G59/3245

摘要： The polyglycidyl compounds according to the invention can be manufactured by reacting epihalogenohydrin with compounds of the formula IV ##STR1## or the formula V ##STR2## in which (1) n denotes 2, 3 or 4, (2) A represents a 2-valent, 3-valent or 4-valent organic radical which either contains a N-heterocyclic or cycloaliphatic ring or 2 N-heterocyclic rings or 2 phenylene rings, (3) either B denotes the --CH.sub.2.O.CO-- radical and m denotes the number 1, or B denotes the radical ##STR3## and m denotes O, and (4) R.sup.1 represents a divalent radical, which contains at least one hydrantoin ring or uracil ring. During the reaction hydrogen halide splits off. From curable mixtures containing polyglycidyl compounds according to the invention and a curing agent such as hexahydrophthalic anhydride or phthalic anhydride are obtained products with good mechanical and electrical properties.

公开(公告)号：US4001236A

公开(公告)日：1977-01-04

申请号：US588528

申请日：1975-06-19

申请人： Jurgen Habermeier ,  Hans Batzer ,  Daniel Porret

发明人： Jurgen Habermeier ,  Hans Batzer ,  Daniel Porret

IPC分类号： C08G59/32 ,  C07D49/32 ,  C07D51/20 ,  C07D51/30

CPC分类号： C08G59/3245

摘要： The polyglycidyl compounds according to the invention can be manufactured by reacting epihalogenohydrin with compounds of the formula IV ##STR1## or the formula V ##STR2## in which 1.) n denotes 2, 3 or 4, 2.) A represents a 2-valent, 3-valent or 4-valent organic radical which either contains a N-heterocyclic or cycloaliphatic ring or 2 N-heterocyclic rings or 2 phenylene rings, 3.) either B denotes the --CH.sub.2.O.CO-- radical and m denotes the number 1, or B denotes the radical ##STR3## and m denotes 0, and 4.) R.sup.1 represents a divalent radical, which contains at least one hydrantoin ring or uracil ring. During the reaction hydrogen halide splits off. From curable mixtures containing polyglycidyl compounds according to the invention and a curing agent such as hexahydrophthalic anhydride or phthalic anhydride are obtained products with good mechanical and electrical properties.

公开(公告)号：US4011235A

公开(公告)日：1977-03-08

申请号：US593801

申请日：1975-07-07

申请人： Jurgen Habermeier ,  Hans Batzer ,  Daniel Porret

发明人： Jurgen Habermeier ,  Hans Batzer ,  Daniel Porret

IPC分类号： C08G59/32 ,  C07D233/72

CPC分类号： C08G59/3245

摘要： The polyglycidyl compounds according to the invention can be manufactured by reacting epihalogenohydrin with compounds of the formula IV ##STR1## or the formula V ##STR2## in which 1. N DENOTES 2, 3 OR 4,2. A represents a 2-valent, 3-valent or 4-valent organic radical which either contains a N-heterocyclic or cycloaliphatic ring or 2 N-heterocyclic rings or 2-phenylene rings,3. either B denotes the --CH.sub.2.O.CO-- radical and m denotes the number 1, or B denotes the radical ##STR3## and m denotes O, and 4. R.sup.1 represents a divalent radical, which contains at least one hydrantoin ring or uracil ring.During the reaction hydrogen halide splits off. From curable mixtures containing polyglycidyl compounds according to the invention and a curing agent such as hexahydrophthalic anhydride or phthalic anhydride are obtained products with good mechanical and electrical properties.

公开(公告)号：US3994864A

公开(公告)日：1976-11-30

申请号：US552489

申请日：1975-02-24

申请人： Lothar Buxbaum ,  Jurgen Habermeier ,  Hans Batzer

发明人： Lothar Buxbaum ,  Jurgen Habermeier ,  Hans Batzer

IPC分类号： C07D233/72 ,  C08G63/00 ,  C08G63/685 ,  C08G63/68

CPC分类号： C08G63/6856

摘要： Linear polyesters based on terephthalic acid and/or isophthalic acid and containing di-(hydroxyalkyl) compounds of oligomeric N,N-heterocyclic compounds as the diol component, have higher glass transition temperatures compared with poly-(alkylene) terephthalates. The new polyesters are thermoplastic materials suitable for the manufacture, by customary moulding processes, of mouldings having a higher heat distortion point.

摘要翻译： 基于对苯二甲酸和/或间苯二甲酸并含有低聚N，N-杂环化合物作为二醇组分的二（羟基烷基）化合物的线性聚酯与聚（亚烷基）对苯二甲酸酯相比具有更高的玻璃化转变温度。 新的聚酯是热塑性材料，适用于通过常规成型工艺制造具有较高热变形点的模制品。

公开(公告)号：US3997511A

公开(公告)日：1976-12-14

申请号：US521128

申请日：1974-11-05

申请人： Hans Batzer ,  Jurgen Habermeier

发明人： Hans Batzer ,  Jurgen Habermeier

IPC分类号： C07D235/26 ,  C08G63/00 ,  C08G63/685 ,  C08G63/68

CPC分类号： C08G63/6858 ,  Y10S260/24

摘要： Unsaturated, linear polyesters having flame-retarding properties are obtained by polycondensing unsaturated dicarboxylic acids, optionally mixed with aromatic dicarboxylic acids and aliphatic diols, with brominated and/or chlorinated 1,3-di-(hydroxyalkyl)-benzimidazolone compounds. The new, unsaturated polyesters can be polymerized easily, also when mixed with other polymerizable monomers, and give moulding materials having flame-retarding properties.

摘要翻译： 通过将任选与芳族二羧酸和脂族二醇混合的不饱和二羧酸与溴化和/或氯化的1,3-二（羟烷基） - 苯并咪唑酮化合物缩聚得到具有阻燃性能的不饱和直链聚酯。 当与其它可聚合单体混合时，新的不饱和聚酯可以容易地聚合，并得到具有阻燃性的成型材料。